地下水硝酸盐污染源解析及氮同位素分馏效应研究进展

doi:10.19657/j.geoscience.1000-8527.2021.176

现代地质 ›› 2022, Vol. 36 ›› Issue (02): 563-573.DOI: 10.19657/j.geoscience.1000-8527.2021.176

地下水硝酸盐污染源解析及氮同位素分馏效应研究进展

于璐¹^,²(), 郑天元¹^,³, 郑西来¹^,³()

1. 中国海洋大学环境科学与工程学院,山东青岛 266100
2. 青岛大学威海创新研究院生态环境研发中心,山东威海 264200
3. 中国海洋大学海洋环境与生态教育部重点实验室,山东青岛 266100

收稿日期:2021-09-30 修回日期:2022-03-03 出版日期:2022-04-10 发布日期:2022-06-01
通讯作者: 郑西来
作者简介:郑西来,男,教授,1959年出生,环境工程专业,主要从事水文地质及环境污染与防治研究。Email: zhxilai@ouc.edu.cn。
于璐,女,博士,1987年出生,环境规划与管理专业,主要从事地下水污染与防治研究。Email: yulu1229@qq.com。
基金资助:
国家自然科学基金重点项目(41731280);国家自然科学基金-山东联合基金项目(U1806210);国家自然科学基金面上项目(51978348)

Review of Nitrate Source Apportionment and Nitrogen Isotope Fractionation in Groundwater

YU Lu¹^,²(), ZHENG Tianyuan¹^,³, ZHENG Xilai¹^,³()

1. College of Environmental Science and Engineering, Ocean University of China, Qingdao, Shandong 266100, China
2. Ecological Environment Research and Development Center, Weihai Innovation Institute, Qingdao University, Weihai, Shandong 264200, China
3. Key Lab of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao, Shandong 266100, China

Received:2021-09-30 Revised:2022-03-03 Online:2022-04-10 Published:2022-06-01
Contact: ZHENG Xilai

摘要/Abstract

摘要：

地下水硝酸盐污染已成为世界范围内最严重的环境地质问题之一。全面并准确识别硝酸盐污染源,对地下水的有效管理及污染防治具有重要的指导意义。从地下水硝酸盐来源、同位素检测方法、污染源同位素特征、定量解析模型构建、硝酸盐主要转化过程及同位素分馏效应等方面进行总结,比较不同解析方法在硝酸盐溯源中的应用与发展,建议采用多学科、多方法相结合的方式,提高对硝酸盐污染源的全面理解。同位素富集系数是定量解析硝酸盐污染源的重要参数,在源解析过程中探讨硝酸盐转化及同位素分馏机制,能够更好地诠释地下水硝酸盐来源和迁移转化过程,提高源解析的准确性,为地下水硝酸盐污染的准确溯源与有效防治提供参考。

关键词: 硝酸盐, 源解析, 氮循环, 同位素, 同位素分馏

Abstract:

Groundwater nitrate (N $O 3 -$ ) pollution has become one of the world’s most serious geoenvironmental problems. Comprehensive and accurate identification of N $O 3 -$ sources has important guiding significance for effective groundwater management and pollution prevention. In this study, we reviewed the N $O 3 -$ sources in groundwater, isotope measurement methods, isotope features of pollution sources, quantitative analytical model, N $O 3 -$ transformation process and isotope fractionation. By comparing the development and application of various N $O 3 -$ source apportionment methods, we invoked that comprehensive and multidisciplinary understanding of N $O 3 -$ sources is needed. Isotope enrichment factor is an important parameter to quantify the contribution of N $O 3 -$ sources. The study of isotopic fractionation effect can better interpret the N $O 3 -$ sources and transformation process in the groundwater, and provide reference for accurate tracing and effective prevention of groundwater N $O 3 -$ pollution.

Key words: nitrate, source apportionment, nitrogen cycle, isotope, fractionation

中图分类号:

P641.3

于璐, 郑天元, 郑西来. 地下水硝酸盐污染源解析及氮同位素分馏效应研究进展[J]. 现代地质, 2022, 36(02): 563-573.

YU Lu, ZHENG Tianyuan, ZHENG Xilai. Review of Nitrate Source Apportionment and Nitrogen Isotope Fractionation in Groundwater[J]. Geoscience, 2022, 36(02): 563-573.

图/表 3

图1 不同污染源氮、氧稳定同位素范围[53⇓⇓⇓⇓-58]

Fig.1 Nitrogen and oxygen isotope compositions of various pollution sources [53⇓⇓⇓⇓-58]

图2 不同污染源氮转化过程及其同位素富集系数[62]

Fig.2 Nitrogen isotope enrichment factor in nitrogen transformation processes of various pollution sources[62]

图3 氮循环主要过程的氮同位素富集系数[57]

Fig.3 Nitrogen isotope enrichment factor of the major nitrogen cycle processes [57]

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地下水硝酸盐污染源解析及氮同位素分馏效应研究进展

Review of Nitrate Source Apportionment and Nitrogen Isotope Fractionation in Groundwater

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