现代地质 ›› 2023, Vol. 37 ›› Issue (06): 1482-1494.DOI: 10.19657/j.geoscience.1000-8527.2023.016
宋彦博1(), 王建平1(
), 沈存利2, 车东1, 杨文华2, 郭海蛟2
收稿日期:
2022-11-03
修回日期:
2023-02-20
出版日期:
2023-12-10
发布日期:
2024-01-24
通讯作者:
王建平,男,教授,1972年出生,矿物学、岩石学、矿床学专业,主要从事矿床学的教学与科研工作。Email:jpwang@cugb.edu.cn。
作者简介:
宋彦博,男,硕士研究生,1998年出生,矿物学、岩石学、矿床学专业,主要从事矿床学与矿床地球化学研究。Email:1339168830@qq.com。
基金资助:
SONG Yanbo1(), WANG Jianping1(
), SHEN Cunli2, CHE Dong1, YANG Wenhua2, GUO Haijiao2
Received:
2022-11-03
Revised:
2023-02-20
Online:
2023-12-10
Published:
2024-01-24
摘要:
扎拉格阿木铜矿床位于锡林浩特古老地块东北部边缘,是内蒙古自治区也是大兴安岭中南段西坡富Zn-Pb-Ag成矿带新近发现的一处与花岗斑岩相关的中等规模热液型铜矿床,研究其成岩成矿机制能为区域找铜提供理论基础,并拓宽勘查方向。为查明花岗斑岩形成时代、岩浆源区特征及其与矿化之间的关系,本文对该岩体进行了岩相学、全岩元素组成、锆石U-Pb年代学和全岩Sr-Nd同位素组成研究。结果表明,岩体具高SiO2和Al2O3含量、低MgO含量,轻稀土元素富集、重稀土元素亏损,弱Eu负异常,亏损Ta、Nb、Ti和P等高场强元素,富集Rb、K、La和Th等大离子亲石元素。这些特征表明其属高钾钙碱性I型花岗岩。εNd(t)值为较小的正值,变化范围为2.1~3.3,对应的Nd同位素模式年龄TDM值在980~740 Ma之间,显示花岗斑岩岩浆的形成与壳幔物质的混合有关。岩浆锆石U-Pb年龄为(254.51±2.13) Ma,指示成岩及与其相关的成矿作用发生于晚二叠世。综合分析认为,扎拉格阿木铜矿床形成于晚二叠世岛弧构造环境,可能与贺根山洋盆俯冲作用有关。
中图分类号:
宋彦博, 王建平, 沈存利, 车东, 杨文华, 郭海蛟. 内蒙古扎拉格阿木铜矿床成矿岩体地质地球化学及其成矿学意义[J]. 现代地质, 2023, 37(06): 1482-1494.
SONG Yanbo, WANG Jianping, SHEN Cunli, CHE Dong, YANG Wenhua, GUO Haijiao. Geological and Geochemical Characteristics of Ore-forming Granite Porphyry and Its Metallogenic Significance in the Zhalageamu Copper Deposit, Inner Mongolia[J]. Geoscience, 2023, 37(06): 1482-1494.
图1 扎拉格阿木铜矿床大地构造位置(a)和兴蒙造山带锡林浩特及额尔古纳地块铜、锡、钼、钨多金属矿床分布(b)(据文献 [2-3,13]修编)
Fig.1 Tectonic map of the Zhalageamu copper deposit (a) and geological map, showing the distribution of Cu,Zn,Mo and W polymetallic ore deposits in the Xilinhot and Erguna blocks of the Khingan metallogenic belt (b)(modified after references [2-3,13])
图2 扎拉格阿木铜矿床地质图(a)和15号勘探线钻孔剖面图(b)(据文献 [8]修编) 1.第四系沉积物;2.中二叠统哲斯组含碳质变质砂岩;3.中二叠统哲斯组褐灰色变质砂岩;4.中二叠统哲斯组砾岩和含砾砂岩;5.中二叠统哲斯组似千枚状板岩;6.中二叠统哲斯组紫灰色变质砂岩;7.中二叠统花岗闪长岩;8.橄榄玄武岩;9.花岗岩脉;10.闪长玢岩脉;11.断层;12.勘探线与钻孔编号;13.矿体;14.糜棱岩带
Fig.2 Geological map (a) and borehole profile along exploration line 15 (b) of the Zhalageamu copper deposit (after reference [8])
图3 扎拉格阿木铜矿床矿石手标本和显微照片 (a)块状构造(采自ZK1508下部);(b) 脉状构造(采自ZK704中下部);(c) 角砾状构造(采自ZK1505中部);(d) 自形-半自形粒状结构;(e) 乳滴结构;(f) 包含结构;Apy.毒砂;Ccp.黄铜矿;Sp.闪锌矿;Qtz.石英
Fig.3 Field photographs and microphotographs of the ore from the Zhalageamu copper deposit
图4 扎拉格阿木铜矿床花岗斑岩手标本和显微照片 Bt.黑云母;Ccp.黄铜矿;Kp.钾长石;Qtz.石英;Ser.绢云母
Fig.4 Field photographs and microphotographs (crossedpolar) of the granite porphyry from the Zhalageamu copper deposit
样品号 | SiO2 | TiO2 | Al2O3 | TFe2O3 | MgO | CaO | Na2O | K2O | P2O5 | 烧失量 | 总量 |
---|---|---|---|---|---|---|---|---|---|---|---|
ZLG-6-1 | 71.30 | 0.43 | 13.36 | 2.89 | 1.44 | 1.37 | 4.24 | 2.48 | 0.12 | 1.52 | 99.14 |
ZLG-6-2 | 69.83 | 0.41 | 14.55 | 3.14 | 1.42 | 1.54 | 4.11 | 2.23 | 0.11 | 2.05 | 99.18 |
ZLG-6-3 | 68.51 | 0.43 | 14.48 | 4.22 | 1.52 | 1.32 | 4.24 | 2.53 | 0.11 | 1.85 | 99.20 |
ZLG-26-1 | 75.36 | 0.38 | 11.92 | 0.84 | 1.21 | 0.48 | 2.61 | 5.82 | 0.07 | 0.69 | 99.15 |
ZLG-26-2 | 75.41 | 0.29 | 11.94 | 0.59 | 0.54 | 1.69 | 3.78 | 3.57 | 0.06 | 1.21 | 99.08 |
ZLG-64 | 74.34 | 0.14 | 11.87 | 3.02 | 0.45 | 0.39 | 5.61 | 1.76 | 0.03 | 1.41 | 99.02 |
ZLG-65 | 72.26 | 0.24 | 13.53 | 1.72 | 0.71 | 0.91 | 3.53 | 5.01 | 0.05 | 1.23 | 99.19 |
ZLG-66 | 72.87 | 0.36 | 12.67 | 2.44 | 0.95 | 0.93 | 3.15 | 4.25 | 0.09 | 1.43 | 99.16 |
样品号 | Mg# | Sc | Ti | Cr | Co | Ni | Rb | Sr | Y | Zr | Nb |
ZLG-6-1 | 49.9 | 6.033 | 2571 | 33.77 | 5.046 | 9.91 | 133.2 | 238.1 | 11.098 | 163.15 | 4.77 |
ZLG-6-2 | 47.4 | 6.278 | 2570 | 31.96 | 4.626 | 7.07 | 123.8 | 216.8 | 11.178 | 141.26 | 4.99 |
ZLG-6-3 | 41.9 | 6.929 | 2654 | 35.15 | 5.109 | 7.47 | 157.8 | 258.1 | 10.635 | 135.28 | 5.08 |
ZLG-26-1 | 70.4 | 5.513 | 2310 | 34.71 | 1.899 | 10.49 | 328.8 | 48.9 | 5.946 | 122.04 | 5.98 |
样品号 | Mg# | Sc | Ti | Cr | Co | Ni | Rb | Sr | Y | Zr | Nb |
ZLG-26-2 | 64.6 | 4.224 | 1750 | 22.69 | 2.448 | 15.37 | 204.3 | 62.4 | 10.583 | 100.56 | 4.52 |
ZLG-64 | 23.2 | 3.557 | 881 | 3.41 | 9.403 | 8.46 | 105.6 | 78.3 | 29.971 | 77.34 | 4.39 |
ZLG-65 | 45.2 | 4.865 | 1487 | 7.19 | 1.342 | 5.34 | 210.4 | 84.2 | 26.323 | 118.63 | 6.39 |
ZLG-66 | 43.7 | 5.85 | 2156 | 12.99 | 3.632 | 7.93 | 243.2 | 96.4 | 19.516 | 123.91 | 6.96 |
样品号 | Ba | La | Ce | Pr | Nd | Sm | Eu | Gd | Tb | Dy | Ho |
ZLG-6-1 | 346.2 | 15.69 | 32.193 | 3.572 | 13.957 | 2.665 | 0.676 | 2.329 | 0.341 | 2.113 | 0.392 |
ZLG-6-2 | 355.2 | 17.34 | 35.721 | 3.994 | 15.679 | 2.995 | 0.747 | 2.558 | 0.357 | 2.134 | 0.389 |
ZLG-6-3 | 364.6 | 14.39 | 29.064 | 3.281 | 13.062 | 2.535 | 0.722 | 2.289 | 0.331 | 2.023 | 0.373 |
ZLG-26-1 | 467.1 | 3.73 | 8.978 | 1.134 | 5.041 | 1.198 | 0.367 | 1.173 | 0.177 | 1.113 | 0.218 |
ZLG-26-2 | 242.8 | 5.72 | 12.953 | 1.596 | 6.903 | 1.593 | 0.425 | 1.597 | 0.256 | 1.671 | 0.337 |
ZLG-64 | 175.3 | 24.26 | 49.308 | 5.718 | 23.646 | 5.273 | 0.963 | 5.538 | 0.876 | 5.672 | 1.081 |
ZLG-65 | 334.2 | 23.06 | 49.061 | 5.427 | 20.475 | 4.178 | 0.506 | 3.973 | 0.659 | 4.428 | 0.885 |
ZLG-66 | 377.6 | 19.68 | 40.887 | 4.568 | 17.564 | 3.612 | 0.602 | 3.539 | 0.563 | 3.604 | 0.684 |
样品号 | Er | Tm | Yb | Hf | Lu | Ta | Pb | Th | U | Hf | Lu |
ZLG-6-1 | 1.173 | 0.153 | 1.053 | 3.739 | 0.146 | 0.28 | 15.164 | 6.791 | 4.632 | 3.739 | 0.146 |
ZLG-6-2 | 1.162 | 0.155 | 1.049 | 3.475 | 0.147 | 0.287 | 13.692 | 7.123 | 2.454 | 3.475 | 0.147 |
ZLG-6-3 | 1.122 | 0.146 | 1.006 | 3.331 | 0.142 | 0.445 | 8.591 | 6.748 | 2.348 | 3.331 | 0.141 |
ZLG-26-1 | 0.711 | 0.105 | 0.837 | 2.904 | 0.136 | 0.372 | 13.444 | 6.015 | 1.591 | 2.904 | 0.136 |
ZLG-26-2 | 1.074 | 0.154 | 1.124 | 2.367 | 0.171 | 0.424 | 10.339 | 4.694 | 1.355 | 2.367 | 0.173 |
ZLG-64 | 3.275 | 0.442 | 3.027 | 2.112 | 0.406 | 0.671 | 7.493 | 10.155 | 3.199 | 2.112 | 0.406 |
ZLG-65 | 2.813 | 0.404 | 2.845 | 3.331 | 0.399 | 0.618 | 22.799 | 17.691 | 5.064 | 3.331 | 0.399 |
ZLG-66 | 2.071 | 0.284 | 1.936 | 3.234 | 0.275 | 0.418 | 12.531 | 13.287 | 3.192 | 3.234 | 0.275 |
表1 扎拉格阿木铜矿床花岗斑岩全岩主量元素(%)、稀土元素和微量元素(10-6)分析结果
Table 1 Major element (%), REE and trace element (10-6) compositions of the granite porphyry from the Zha-lageamu copper deposit
样品号 | SiO2 | TiO2 | Al2O3 | TFe2O3 | MgO | CaO | Na2O | K2O | P2O5 | 烧失量 | 总量 |
---|---|---|---|---|---|---|---|---|---|---|---|
ZLG-6-1 | 71.30 | 0.43 | 13.36 | 2.89 | 1.44 | 1.37 | 4.24 | 2.48 | 0.12 | 1.52 | 99.14 |
ZLG-6-2 | 69.83 | 0.41 | 14.55 | 3.14 | 1.42 | 1.54 | 4.11 | 2.23 | 0.11 | 2.05 | 99.18 |
ZLG-6-3 | 68.51 | 0.43 | 14.48 | 4.22 | 1.52 | 1.32 | 4.24 | 2.53 | 0.11 | 1.85 | 99.20 |
ZLG-26-1 | 75.36 | 0.38 | 11.92 | 0.84 | 1.21 | 0.48 | 2.61 | 5.82 | 0.07 | 0.69 | 99.15 |
ZLG-26-2 | 75.41 | 0.29 | 11.94 | 0.59 | 0.54 | 1.69 | 3.78 | 3.57 | 0.06 | 1.21 | 99.08 |
ZLG-64 | 74.34 | 0.14 | 11.87 | 3.02 | 0.45 | 0.39 | 5.61 | 1.76 | 0.03 | 1.41 | 99.02 |
ZLG-65 | 72.26 | 0.24 | 13.53 | 1.72 | 0.71 | 0.91 | 3.53 | 5.01 | 0.05 | 1.23 | 99.19 |
ZLG-66 | 72.87 | 0.36 | 12.67 | 2.44 | 0.95 | 0.93 | 3.15 | 4.25 | 0.09 | 1.43 | 99.16 |
样品号 | Mg# | Sc | Ti | Cr | Co | Ni | Rb | Sr | Y | Zr | Nb |
ZLG-6-1 | 49.9 | 6.033 | 2571 | 33.77 | 5.046 | 9.91 | 133.2 | 238.1 | 11.098 | 163.15 | 4.77 |
ZLG-6-2 | 47.4 | 6.278 | 2570 | 31.96 | 4.626 | 7.07 | 123.8 | 216.8 | 11.178 | 141.26 | 4.99 |
ZLG-6-3 | 41.9 | 6.929 | 2654 | 35.15 | 5.109 | 7.47 | 157.8 | 258.1 | 10.635 | 135.28 | 5.08 |
ZLG-26-1 | 70.4 | 5.513 | 2310 | 34.71 | 1.899 | 10.49 | 328.8 | 48.9 | 5.946 | 122.04 | 5.98 |
样品号 | Mg# | Sc | Ti | Cr | Co | Ni | Rb | Sr | Y | Zr | Nb |
ZLG-26-2 | 64.6 | 4.224 | 1750 | 22.69 | 2.448 | 15.37 | 204.3 | 62.4 | 10.583 | 100.56 | 4.52 |
ZLG-64 | 23.2 | 3.557 | 881 | 3.41 | 9.403 | 8.46 | 105.6 | 78.3 | 29.971 | 77.34 | 4.39 |
ZLG-65 | 45.2 | 4.865 | 1487 | 7.19 | 1.342 | 5.34 | 210.4 | 84.2 | 26.323 | 118.63 | 6.39 |
ZLG-66 | 43.7 | 5.85 | 2156 | 12.99 | 3.632 | 7.93 | 243.2 | 96.4 | 19.516 | 123.91 | 6.96 |
样品号 | Ba | La | Ce | Pr | Nd | Sm | Eu | Gd | Tb | Dy | Ho |
ZLG-6-1 | 346.2 | 15.69 | 32.193 | 3.572 | 13.957 | 2.665 | 0.676 | 2.329 | 0.341 | 2.113 | 0.392 |
ZLG-6-2 | 355.2 | 17.34 | 35.721 | 3.994 | 15.679 | 2.995 | 0.747 | 2.558 | 0.357 | 2.134 | 0.389 |
ZLG-6-3 | 364.6 | 14.39 | 29.064 | 3.281 | 13.062 | 2.535 | 0.722 | 2.289 | 0.331 | 2.023 | 0.373 |
ZLG-26-1 | 467.1 | 3.73 | 8.978 | 1.134 | 5.041 | 1.198 | 0.367 | 1.173 | 0.177 | 1.113 | 0.218 |
ZLG-26-2 | 242.8 | 5.72 | 12.953 | 1.596 | 6.903 | 1.593 | 0.425 | 1.597 | 0.256 | 1.671 | 0.337 |
ZLG-64 | 175.3 | 24.26 | 49.308 | 5.718 | 23.646 | 5.273 | 0.963 | 5.538 | 0.876 | 5.672 | 1.081 |
ZLG-65 | 334.2 | 23.06 | 49.061 | 5.427 | 20.475 | 4.178 | 0.506 | 3.973 | 0.659 | 4.428 | 0.885 |
ZLG-66 | 377.6 | 19.68 | 40.887 | 4.568 | 17.564 | 3.612 | 0.602 | 3.539 | 0.563 | 3.604 | 0.684 |
样品号 | Er | Tm | Yb | Hf | Lu | Ta | Pb | Th | U | Hf | Lu |
ZLG-6-1 | 1.173 | 0.153 | 1.053 | 3.739 | 0.146 | 0.28 | 15.164 | 6.791 | 4.632 | 3.739 | 0.146 |
ZLG-6-2 | 1.162 | 0.155 | 1.049 | 3.475 | 0.147 | 0.287 | 13.692 | 7.123 | 2.454 | 3.475 | 0.147 |
ZLG-6-3 | 1.122 | 0.146 | 1.006 | 3.331 | 0.142 | 0.445 | 8.591 | 6.748 | 2.348 | 3.331 | 0.141 |
ZLG-26-1 | 0.711 | 0.105 | 0.837 | 2.904 | 0.136 | 0.372 | 13.444 | 6.015 | 1.591 | 2.904 | 0.136 |
ZLG-26-2 | 1.074 | 0.154 | 1.124 | 2.367 | 0.171 | 0.424 | 10.339 | 4.694 | 1.355 | 2.367 | 0.173 |
ZLG-64 | 3.275 | 0.442 | 3.027 | 2.112 | 0.406 | 0.671 | 7.493 | 10.155 | 3.199 | 2.112 | 0.406 |
ZLG-65 | 2.813 | 0.404 | 2.845 | 3.331 | 0.399 | 0.618 | 22.799 | 17.691 | 5.064 | 3.331 | 0.399 |
ZLG-66 | 2.071 | 0.284 | 1.936 | 3.234 | 0.275 | 0.418 | 12.531 | 13.287 | 3.192 | 3.234 | 0.275 |
图5 扎拉格阿木铜矿床花岗斑岩K2O-SiO2图解(a)与A/NK-A/CNK图解(b)(底图据文献 [18-19])
Fig.5 Diagrams of K2O-SiO2 (a) and A/NK-A/CNK (b) for the granite porphyry from the Zhalageamu copper deposit (after references [18-19])
图6 扎拉格阿木铜矿床花岗斑岩哈克图解 (a)Al2O3-SiO2协变图;(b) TFe2O3-SiO2协变图;(c) MgO-SiO2协变图;(d) TiO2-SiO2协变图;(e) Na2O-SiO2协变图;(f) CaO-SiO2协变图
Fig.6 Harker diagrams for the granite porphyry from the Zhalageamu copper deposit
图7 扎拉格阿木铜矿床花岗斑岩稀土元素球粒陨石标准化配分曲线(a)和微量元素原始地幔标准化蛛网图(b)(球粒陨石标准值和原始地幔标准化值据文献 [19])
Fig.7 Chondrite-normalized REE patterns (a) and primitive mantle-normalized multi-elements spidergram (b) of the granite porphyry from the Zhalageamu copper deposit (chondrite- and primitive mantle-normalizing values from reference [19])
图8 扎拉格阿木铜矿床花岗斑岩典型锆石测点CL图像(标示年龄为锆石206Pb/238U年龄)
Fig.8 Zircon cathodoluminescence (CL) images of the granite porphyry from the Zhalageamu copper deposit (the zircon 206Pb/238U are indicated)
样品编号 | 元素含量 (10-6) | 232Th/ 238U | 同位素比值 | 年龄 (Ma) | 谐和度 (%) | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
206Pb | 238U | 232Th | 207Pb/206Pb ±1σ | 207Pb/235U ±1σ | 206Pb/238U ±1σ | 207Pb/206Pb ±1σ | 207Pb/235U ±1σ | 206Pb/238U ±1σ | ||||||
ZLG-22-4 | 2.0817 | 484.09 | 214.53 | 0.44 | 0.0531± 0.0036 | 0.2956± 0.0181 | 0.0402± 0.0008 | 331.54± 153.6830 | 262.94± 14.2592 | 254.46± 4.8230 | 96 | |||
ZLG-22-6 | 0.0917 | 332.75 | 171.95 | 0.52 | 0.0544± 0.0074 | 0.2949± 0.0354 | 0.0395± 0.0011 | 387.09± 307.3680 | 262.43± 27.0588 | 250.11± 7.0920 | 95 | |||
ZLG-22-7 | 0.7494 | 458.93 | 233.51 | 0.51 | 0.0529± 0.0032 | 0.2932± 0.0165 | 0.0399± 0.0006 | 324.13± 132.3900 | 261.07± 12.6790 | 252.22± 3.9420 | 96 | |||
ZLG-22-8 | 1.1862 | 407.11 | 244.18 | 0.60 | 0.0503± 0.0042 | 0.2909± 0.0241 | 0.0411± 0.0008 | 209.33± 4.6300 | 259.31± 18.8419 | 259.78± 5.1700 | 99 | |||
ZLG-22-9 | 0.5036 | 448.42 | 199.59 | 0.45 | 0.0518± 0.0029 | 0.2883± 0.0165 | 0.0401± 0.0007 | 279.69± 160.1650 | 257.28± 12.2389 | 253.47± 4.1580 | 98 | |||
ZLG-22-11 | 0.0917 | 351.28 | 243.92 | 0.69 | 0.0538± 0.0050 | 0.2936± 0.0257 | 0.0398± 0.0010 | 361.17± 213.8630 | 261.46± 19.3354 | 251.86± 6.4871 | 96 | |||
ZLG-22-12 | 1.1402 | 335.09 | 146.00 | 0.44 | 0.0522± 0.0040 | 0.2907± 0.0224 | 0.0403± 0.0008 | 294.51± 175.9030 | 259.16± 17.5984 | 254.79± 5.1493 | 98 | |||
ZLG-22-13 | 0.7494 | 416.34 | 222.29 | 0.53 | 0.0530± 0.0033 | 0.2912± 0.0175 | 0.0396± 0.0007 | 327.84± 136.0930 | 259.55± 13.5015 | 250.43± 4.2806 | 96 | |||
ZLG-22-14 | 0.5042 | 351.60 | 185.95 | 0.53 | 0.0528± 0.0035 | 0.2877± 0.0177 | 0.0400± 0.0008 | 320.43± 151.8330 | 256.78± 13.4575 | 253.29± 4.7386 | 98 | |||
ZLG-22-16 | 0.3047 | 247.92 | 97.98 | 0.40 | 0.0548± 0.0051 | 0.2973± 0.0268 | 0.0396± 0.0008 | 466.71± 211.0800 | 264.31± 20.6215 | 250.41± 4.7054 | 94 | |||
ZLG-22-17 | 2.1587 | 461.24 | 327.07 | 0.71 | 0.0538± 0.0034 | 0.2954± 0.0181 | 0.0396± 0.0007 | 364.87± 144.4280 | 262.81± 14.0484 | 250.68± 4.2119 | 95 | |||
ZLG-22-20 | 2.4374 | 227.64 | 102.24 | 0.45 | 0.0547± 0.0067 | 0.2916± 0.0303 | 0.0401± 0.0010 | 466.71± 275.8900 | 259.82± 23.4196 | 253.60± 6.3016 | 97 | |||
ZLG-22-22 | 0.6650 | 346.50 | 178.91 | 0.52 | 0.0506± 0.0045 | 0.2891± 0.0262 | 0.0408± 0.0009 | 220.44± 196.2750 | 257.88± 20.1280 | 258.22± 5.7015 | 99 | |||
ZLG-22-23 | 0.2382 | 379.90 | 132.01 | 0.35 | 0.0524± 0.0045 | 0.2805± 0.0211 | 0.0400± 0.0010 | 305.62± 202.7530 | 251.13± 16.3184 | 253.34± 6.2258 | 99 | |||
ZLG-22-25 | 0.6496 | 362.72 | 146.31 | 0.40 | 0.0539± 0.0044 | 0.2887± 0.0215 | 0.0399± 0.0009 | 368.57± 183.3100 | 257.58± 16.2335 | 252.39± 5.5236 | 97 | |||
ZLG-22-26 | 1.5691 | 376.49 | 212.50 | 0.56 | 0.0507± 0.0046 | 0.2911± 0.0251 | 0.0413± 0.0008 | 227.85± 16.6650 | 259.49± 19.3279 | 261.40± 4.9738 | 99 | |||
ZLG-22-27 | 1.9669 | 414.77 | 176.72 | 0.43 | 0.0521± 0.0034 | 0.2937± 0.0195 | 0.0410± 0.0008 | 300.06± 115.7280 | 261.48± 14.8045 | 259.13± 4.9481 | 99 |
表2 扎拉格阿木铜矿床花岗斑岩锆石U-Pb同位素 LA-ICP-MS 定年结果
Table 2 Results of LA-ICP-MS zircon U-Pb dating for the granite porphyry from the Zhalageamu copper deposit
样品编号 | 元素含量 (10-6) | 232Th/ 238U | 同位素比值 | 年龄 (Ma) | 谐和度 (%) | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
206Pb | 238U | 232Th | 207Pb/206Pb ±1σ | 207Pb/235U ±1σ | 206Pb/238U ±1σ | 207Pb/206Pb ±1σ | 207Pb/235U ±1σ | 206Pb/238U ±1σ | ||||||
ZLG-22-4 | 2.0817 | 484.09 | 214.53 | 0.44 | 0.0531± 0.0036 | 0.2956± 0.0181 | 0.0402± 0.0008 | 331.54± 153.6830 | 262.94± 14.2592 | 254.46± 4.8230 | 96 | |||
ZLG-22-6 | 0.0917 | 332.75 | 171.95 | 0.52 | 0.0544± 0.0074 | 0.2949± 0.0354 | 0.0395± 0.0011 | 387.09± 307.3680 | 262.43± 27.0588 | 250.11± 7.0920 | 95 | |||
ZLG-22-7 | 0.7494 | 458.93 | 233.51 | 0.51 | 0.0529± 0.0032 | 0.2932± 0.0165 | 0.0399± 0.0006 | 324.13± 132.3900 | 261.07± 12.6790 | 252.22± 3.9420 | 96 | |||
ZLG-22-8 | 1.1862 | 407.11 | 244.18 | 0.60 | 0.0503± 0.0042 | 0.2909± 0.0241 | 0.0411± 0.0008 | 209.33± 4.6300 | 259.31± 18.8419 | 259.78± 5.1700 | 99 | |||
ZLG-22-9 | 0.5036 | 448.42 | 199.59 | 0.45 | 0.0518± 0.0029 | 0.2883± 0.0165 | 0.0401± 0.0007 | 279.69± 160.1650 | 257.28± 12.2389 | 253.47± 4.1580 | 98 | |||
ZLG-22-11 | 0.0917 | 351.28 | 243.92 | 0.69 | 0.0538± 0.0050 | 0.2936± 0.0257 | 0.0398± 0.0010 | 361.17± 213.8630 | 261.46± 19.3354 | 251.86± 6.4871 | 96 | |||
ZLG-22-12 | 1.1402 | 335.09 | 146.00 | 0.44 | 0.0522± 0.0040 | 0.2907± 0.0224 | 0.0403± 0.0008 | 294.51± 175.9030 | 259.16± 17.5984 | 254.79± 5.1493 | 98 | |||
ZLG-22-13 | 0.7494 | 416.34 | 222.29 | 0.53 | 0.0530± 0.0033 | 0.2912± 0.0175 | 0.0396± 0.0007 | 327.84± 136.0930 | 259.55± 13.5015 | 250.43± 4.2806 | 96 | |||
ZLG-22-14 | 0.5042 | 351.60 | 185.95 | 0.53 | 0.0528± 0.0035 | 0.2877± 0.0177 | 0.0400± 0.0008 | 320.43± 151.8330 | 256.78± 13.4575 | 253.29± 4.7386 | 98 | |||
ZLG-22-16 | 0.3047 | 247.92 | 97.98 | 0.40 | 0.0548± 0.0051 | 0.2973± 0.0268 | 0.0396± 0.0008 | 466.71± 211.0800 | 264.31± 20.6215 | 250.41± 4.7054 | 94 | |||
ZLG-22-17 | 2.1587 | 461.24 | 327.07 | 0.71 | 0.0538± 0.0034 | 0.2954± 0.0181 | 0.0396± 0.0007 | 364.87± 144.4280 | 262.81± 14.0484 | 250.68± 4.2119 | 95 | |||
ZLG-22-20 | 2.4374 | 227.64 | 102.24 | 0.45 | 0.0547± 0.0067 | 0.2916± 0.0303 | 0.0401± 0.0010 | 466.71± 275.8900 | 259.82± 23.4196 | 253.60± 6.3016 | 97 | |||
ZLG-22-22 | 0.6650 | 346.50 | 178.91 | 0.52 | 0.0506± 0.0045 | 0.2891± 0.0262 | 0.0408± 0.0009 | 220.44± 196.2750 | 257.88± 20.1280 | 258.22± 5.7015 | 99 | |||
ZLG-22-23 | 0.2382 | 379.90 | 132.01 | 0.35 | 0.0524± 0.0045 | 0.2805± 0.0211 | 0.0400± 0.0010 | 305.62± 202.7530 | 251.13± 16.3184 | 253.34± 6.2258 | 99 | |||
ZLG-22-25 | 0.6496 | 362.72 | 146.31 | 0.40 | 0.0539± 0.0044 | 0.2887± 0.0215 | 0.0399± 0.0009 | 368.57± 183.3100 | 257.58± 16.2335 | 252.39± 5.5236 | 97 | |||
ZLG-22-26 | 1.5691 | 376.49 | 212.50 | 0.56 | 0.0507± 0.0046 | 0.2911± 0.0251 | 0.0413± 0.0008 | 227.85± 16.6650 | 259.49± 19.3279 | 261.40± 4.9738 | 99 | |||
ZLG-22-27 | 1.9669 | 414.77 | 176.72 | 0.43 | 0.0521± 0.0034 | 0.2937± 0.0195 | 0.0410± 0.0008 | 300.06± 115.7280 | 261.48± 14.8045 | 259.13± 4.9481 | 99 |
图9 扎拉格阿木铜矿床花岗斑岩锆石U-Pb谐和年龄图(a)与206Pb/238U加权平均年龄图(b)
Fig.9 Zircon U-Pb concordia (a) and weighted average age (b) diagrams of the granite porphyry from the Zha-lageamu copper deposit
样品号 | T (Ma) | Rb (10-6) | Sr (10-6) | 87Rb/ 86Sr | 87Sr/ 86Sr | (87Sr/ 86Sr)i | Sm (10-6) | Nd (10-6) | 147Sm/ 144Nd | 143Nd/ 144Nd | (143Nd/ 144Nd)i | εNd(t) | TDM (Ga) |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
ZLG-6-1 | 255 | 133.216 | 238.080 | 1.667 | 0.708 | 0.702 | 2.664 | 13.951 | 0.115 | 0.51264 | 0.51241 | 3.3 | 0.74 |
ZLG-6-2 | 255 | 204.320 | 62.400 | 9.760 | 0.706 | 0.670 | 1.592 | 6.902 | 0.139 | 0.51268 | 0.51248 | 2.5 | 0.98 |
ZLG-6-3 | 255 | 157.760 | 258.080 | 1.822 | 0.708 | 0.701 | 2.534 | 13.062 | 0.117 | 0.51267 | 0.51244 | 3.2 | 0.77 |
ZLG-26-1 | 255 | 328.800 | 48.880 | 20.052 | 0.745 | 0.672 | 1.198 | 5.040 | 0.143 | 0.51267 | 0.51248 | -0.6 | 1.37 |
ZLG-26-2 | 255 | 123.840 | 216.800 | 1.702 | 0.707 | 0.701 | 2.994 | 15.673 | 0.115 | 0.51265 | 0.51246 | 3.0 | 0.76 |
ZLG-64 | 255 | 105.616 | 78.304 | 4.020 | 0.705 | 0.691 | 5.273 | 23.640 | 0.134 | 0.51266 | 0.51247 | 2.1 | 0.98 |
ZLG-65 | 255 | 210.450 | 84.244 | 7.446 | 0.707 | 0.680 | 4.178 | 20.474 | 0.123 | 0.51252 | 0.51228 | 3.3 | 0.78 |
表3 扎拉格阿木铜矿床花岗斑岩全岩Sr-Nd同位素组成
Table 3 Sr-Nd isotopic compositions for the granite porphyry from the Zhalageamu copper deposit
样品号 | T (Ma) | Rb (10-6) | Sr (10-6) | 87Rb/ 86Sr | 87Sr/ 86Sr | (87Sr/ 86Sr)i | Sm (10-6) | Nd (10-6) | 147Sm/ 144Nd | 143Nd/ 144Nd | (143Nd/ 144Nd)i | εNd(t) | TDM (Ga) |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
ZLG-6-1 | 255 | 133.216 | 238.080 | 1.667 | 0.708 | 0.702 | 2.664 | 13.951 | 0.115 | 0.51264 | 0.51241 | 3.3 | 0.74 |
ZLG-6-2 | 255 | 204.320 | 62.400 | 9.760 | 0.706 | 0.670 | 1.592 | 6.902 | 0.139 | 0.51268 | 0.51248 | 2.5 | 0.98 |
ZLG-6-3 | 255 | 157.760 | 258.080 | 1.822 | 0.708 | 0.701 | 2.534 | 13.062 | 0.117 | 0.51267 | 0.51244 | 3.2 | 0.77 |
ZLG-26-1 | 255 | 328.800 | 48.880 | 20.052 | 0.745 | 0.672 | 1.198 | 5.040 | 0.143 | 0.51267 | 0.51248 | -0.6 | 1.37 |
ZLG-26-2 | 255 | 123.840 | 216.800 | 1.702 | 0.707 | 0.701 | 2.994 | 15.673 | 0.115 | 0.51265 | 0.51246 | 3.0 | 0.76 |
ZLG-64 | 255 | 105.616 | 78.304 | 4.020 | 0.705 | 0.691 | 5.273 | 23.640 | 0.134 | 0.51266 | 0.51247 | 2.1 | 0.98 |
ZLG-65 | 255 | 210.450 | 84.244 | 7.446 | 0.707 | 0.680 | 4.178 | 20.474 | 0.123 | 0.51252 | 0.51228 | 3.3 | 0.78 |
图10 扎拉格阿木铜矿床花岗斑岩成因类型判别图解 (a)花岗岩Zr-SiO2判别图解(底图据文献 [21,24-25]);(b) I型花岗岩P2O5-SiO2图解(底图据文献 [27])
Fig.10 Granite discrimination diagrams for the granite porphyry from the Zhalageamu copper deposit
图11 扎拉格阿木铜矿床花岗斑岩εNd(t)值与侵位时代的关系(底图据文献 [24]) CHUR.球粒陨石均一储存库;DM.亏损地幔
Fig.11 Plot of εNd(t) vs. intrusive age of the granite porphyry from the Zhalageamu copper deposit(basemap after reference [24])
图12 扎拉格阿木铜矿床花岗斑岩微量元素构造环境判别图解(底图据文献 [39]) (a) Nb-Y构造判别图解;(b) Ta-Yb构造判别图解;(c) Rb/30-Hf-3Ta构造判别图解;(d) TiO2-Zr构造判别图解
Fig.12 Trace element tectonic discrimination diagrams for the granite porphyry from the Zhalageamu copper deposit(basemap after reference [39])
图13 扎拉格阿木铜矿床成岩成矿模式图(底图据文献 [40]) (a) 扎拉格阿木地区晚二叠世构造演化;(b) 来自交代板片的岩浆在下地壳经历了MASH(熔融、同化、均一和存储)过程,形成高分异和相对低密度岩浆,向上运移定位并成矿;(c) 含矿热液运移并沉淀成矿于花岗闪长岩体与上覆地层的接触带及裂隙中
Fig.13 Magmatic and metallogenic models of the Zhalageamu copper deposit (basemap after reference [40])
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