吉林“磐龙玉”的地球化学特征及颜色成因探讨

doi:10.19657/j.geoscience.1000-8527.2025.005

摘要/Abstract

摘要：

“磐龙玉”是一种产于吉林省磐石市小红石砬子铅锌矿矿床的矿化蚀变带围岩中的石英质玉石,主要由石英和绢云母组成,多呈黄绿色。本文基于野外调查,采用常规宝石学测试、X射线粉晶衍射、红外光谱、激光拉曼光谱、紫外-可见光反射光谱、电子探针、全岩主量元素分析、全岩稀土与微量元素分析及锆石U-Pb定年等多种方法,对“磐龙玉”的宝石学特征、光谱学特征和地球化学特征进行系统研究,探讨其颜色形成机理、成矿时代及矿床成因机制。结果表明,“磐龙玉”原岩主要为流纹质凝灰岩,经硅化、绢云母化等蚀变作用使其颜色、粒度发生显著变化而达到玉石的标准。其绿色色调的致色离子为Fe²⁺,Fe²⁺的类质同象混入使得绢云母呈绿色,绢云母含量与“磐龙玉”绿色呈正相关;而Fe³⁺的存在则使其呈现黄色(针铁矿)和红色(赤铁矿)色调。“磐龙玉”形成于中-低温变质环境,锆石U-Pb定年结果(228.1±0.7) Ma表明其形成与该区中生代晚三叠世的酸性岩浆侵入活动关系密切,其成矿过程主要发生在气水热液期,可划分为硅化、绢云母化和碳酸盐化三个阶段。

关键词: “磐龙玉”, 石英质玉石, 光谱分析, 岩石地球化学, 锆石U-Pb定年

Abstract:

“Panlong Jade”, a type of quartzite jade, is derived from the mineralized rocks surrounding the Xiaohongshilazi lead-zinc deposit in Panshi City, Jilin Province. Mostly yellow-green, it is primarily composed of quartz and sericite minerals. Based on field investigations, this study systematically examines the gemological, spectroscopic and geochemical characteristics of “Panlong Jade” using conventional gemological testing, X-ray powder diffraction, infrared spectroscopy, laser Raman spectroscopy, whole rock geochemical principal component analysis, electron probe, ultraviolet-visible reflection spectroscopy, whole-rock rare earth and trace element analysis and zircon U-Pb dating, while exploring the color formation mechanism, age and ore genesis of “Panlong Jade”. The results indicate that the protolith of “Panlong Jade” is mainly rhyolite tuff, and its color and particle size change due to alteration processes such as silicification and sericitization to meet jade standards. The green coloration is due to the presence of Fe²⁺, which is isomorphic substituted in sericite, giving it a green hue. There is a positive correlation between the sericite content and the green color of “Panlong Jade”. On the other hand, the presence of Fe³⁺ imparts yellow (goethite) and red (hematite) hues. “Panlong Jade” formed in a medium to low-temperature metamorphic environment. Zircon U-Pb dating results (228.1±0.7) Ma suggest that the formation of “Panlong Jade” is closely related to acidic magmatic intrusion activity during the Late Triassic period of the Mesozoic era. The mineralization process of “Panlong Jade” can be divided into three main stages: silicification, sericitization, and carbonation.

Key words: “Panlong Jade”, quartzite jade, spectroscopic analysis, rock geochemistry, zircon U-Pb dating

中图分类号:

杨宇婷, 白峰, 温宇航, 张启东, 张道元, 王雯. 吉林“磐龙玉”的地球化学特征及颜色成因探讨[J]. 现代地质, 2025, 39(01): 167-182.

YANG Yuting, BAI Feng, WEN Yuhang, ZHANG Qidong, ZHANG Daoyuan, WANG Wen. Geochemical Characteristics and Color Formation Mechanisms of “Panlong Jade” from Jilin Province[J]. Geoscience, 2025, 39(01): 167-182.

图/表 22

图1 中国东北地区大地构造简图(a)(底图据文献[8]修改)和“磐龙玉”矿区地质图(b)(底图据文献[3]修改)

Fig. 1 Regional tectonic framework of Northeast China (a) (modified after reference[8]) and geological map of the “PanlongJade” deposit (b) (modified after reference[3])

图2 “磐龙玉”矿体 (a)流纹构造;(b)脉状矿体

Fig. 2 “Panlong Jade” orebody

图3 “磐龙玉”手标本照片

Fig.3 Photos of “Panlong Jade” hand specimens

图4 “磐龙玉”镜下特征 (a)(b)斑状变晶结构;(c)(d)石英、方解石脉;(e)(f)钠长石双晶;(g)(h)浑圆石英颗粒及石英、方解石脉;Ab. 钠长石;Cal. 方解石;Py. 黄铁矿;Qtz. 石英;Ser. 绢云母

Fig.4 Features of “Panlong Jade” under polarization microscope

图5 “磐龙玉”样品的XRD衍射图 (a)黄色系列;(b)绿黄色系列;(c)黄绿色系列;(d)绿色系列

Fig. 5 XRD diffraction pattern of “Panlong Jade” samples

图6 “磐龙玉”样品红外光谱反射图 (a)黄色系列;(b)绿黄色系列;(c)黄绿色系列;(d)绿色系列

Fig. 6 Infrared spectral reflectance of “Panlong Jade” samples

表1 绿色系列“磐龙玉”的部分红外特征峰(cm-1)

Table 1 Partial infrared reflectance spectral characteristic peaks of the green series “Panlong Jade”(cm-1)

编号	$ν S i (A l I V) - O$ 伸缩振动(Ms)	Si(Al)-O 伸缩振动(Ab)	Si-Si伸缩振动(Ab)	Si-Al(Si) 伸缩振动(Ab)		O-Si(Al)-O 弯曲振动(Ab)		Si-O-Si弯曲振动(Ab)
L01	1039	1010	761	742	721	649	594	420
L02	1041	-	761	742	723	648	592	430
L03	1041	-	-	740	721	656	590	422
L04	1035	-	761	742	719	648	-	418
L05	1041	-	-	-	721	651	595	-
L06	1041	1008	761	742	721	653	594	420
L07	1045	-	-	-	721	649	590	418
L08	1039	-	-	-	-	-	-	-
L09	1041	-	760	742	721	649	590	420

表1 绿色系列“磐龙玉”的部分红外特征峰(cm-1)

Table 1 Partial infrared reflectance spectral characteristic peaks of the green series “Panlong Jade”(cm-1)

编号	$ν S i (A l I V) - O$ 伸缩振动(Ms)	Si(Al)-O 伸缩振动(Ab)	Si-Si伸缩振动(Ab)	Si-Al(Si) 伸缩振动(Ab)		O-Si(Al)-O 弯曲振动(Ab)		Si-O-Si弯曲振动(Ab)
L01	1039	1010	761	742	721	649	594	420
L02	1041	-	761	742	723	648	592	430
L03	1041	-	-	740	721	656	590	422
L04	1035	-	761	742	719	648	-	418
L05	1041	-	-	-	721	651	595	-
L06	1041	1008	761	742	721	653	594	420
L07	1045	-	-	-	721	649	590	418
L08	1039	-	-	-	-	-	-	-
L09	1041	-	760	742	721	649	590	420

图7 “磐龙玉”样品拉曼光谱图 (a)黄色系列;(b)绿黄色系列;(c)黄绿色系列;(d)绿色系列

Fig. 7 Raman spectra of “Panlong Jade” samples

图8 “磐龙玉”紫外-可见光反射光谱及其一阶导数图谱

Fig. 8 Ultraviolet-visible reflection spectrum and its first derivative spectrum of “Panlong Jade” samples

表2 “磐龙玉”样品绢云母化学成分(%)

Table 2 Chemical composition of sericite from “Panlong Jade” samples (%)

编号	SiO₂	TiO₂	Al₂O₃	^TFeO	MnO	MgO	CaO	NaO	K₂O	Cr₂O₃	Total	Si
LH07-1	50.17	0.09	34.15	1.19	0.04	0.43	0.14	0.30	9.90	0.05	96.46	3.26
LH07-2	49.01	0.11	33.68	1.14	0.06	0.38	0.12	0.31	9.97	0.42	95.20	3.25
LH07-2	49.40	0.11	34.58	1.32	-	0.36	0.02	0.37	10.15	0.04	96.35	3.22
LH08-2	50.16	0.03	34.21	1.28	0.06	0.43	0.06	0.39	9.69	-	96.31	3.26
LH08-3	50.49	0.11	33.84	1.15	0.02	0.44	0.03	0.29	9.48	0.07	95.92	3.29
L10-1	49.38	0.02	34.57	0.76	-	0.53	0.09	0.29	10.30	0.32	96.26	3.23
L10-2	49.78	0.09	34.59	1.34	0.04	0.31	0.01	0.36	9.96	-	96.48	3.24
L11-1	50.05	0.08	34.10	1.18	-	0.40	0.07	0.25	9.43	0.38	95.94	3.27
L11-2	49.25	0.19	34.69	1.10	0.07	0.50	0.15	0.31	9.99	0.04	96.29	3.21
L11-3	48.16	0.27	34.14	1.19	0.10	0.69	0.11	0.29	10.58	0.09	95.62	3.18
编号	^ⅣAl	^ⅥAl	Al^T	Ti	Fe	Mn	Mg	Ca	Na	K	Total	OH^-
LH07-1	0.74	1.88	2.62	-	0.06	-	0.04	0.01	0.04	0.82	6.86	2.00
LH07-2	0.75	1.87	2.63	0.01	0.06	-	0.04	0.01	0.04	0.84	6.88	2.00
LH07-2	0.78	1.88	2.66	0.01	0.07	-	0.04	-	0.05	0.84	6.89	2.00
LH08-2	0.74	1.88	2.62	-	0.07	-	0.04	-	0.05	0.80	6.85	2.00
LH08-3	0.71	1.88	2.60	0.01	0.06	-	0.04	-	0.04	0.79	6.82	2.00
L10-1	0.77	1.89	2.66	-	0.04	-	0.05	0.01	0.04	0.86	6.89	2.00
L10-2	0.76	1.89	2.65	-	0.07	-	0.03	-	0.05	0.83	6.87	2.00
L11-1	0.73	1.89	2.62	-	0.06	-	0.04	-	0.03	0.79	6.82	2.00
L11-2	0.79	1.88	2.67	0.01	0.06	-	0.05	0.01	0.04	0.83	6.88	2.00
L11-3	0.82	1.85	2.66	0.01	0.07	0.01	0.07	0.01	0.04	0.89	6.94	2.00

图9 “磐龙玉”样品绢云母(Fe+Mg+Mn) -(Total Al)图解[22]

Fig.9 (Fe+Mg+Mn) vs. (Total Al) diagram for sericite from “Panlong Jade” samples[22]

表3 不同颜色“磐龙玉”主量元素结果(%)

Table 3 Results of main elements in different colors of “Panlong Jade” (%)

样品	SiO₂	TiO₂	Al₂O₃	Fe₂O₃	MnO	MgO	CaO	Na₂O	K₂O	P₂O₅	FeO	LOI	总量
H02	76.18	0.07	12.17	0.11	0.04	0.28	1.52	0.19	3.23	0.01	0.43	4.22	98.45
H04	81.00	0.07	10.94	0.14	0.03	0.21	0.09	0.13	3.01	0.02	0.43	2.22	98.28
LH03	78.02	0.08	12.38	0.16	0.03	0.26	0.50	0.13	3.47	0.01	0.50	2.99	98.52
LH04	75.48	0.08	12.14	0.13	0.10	0.19	1.84	0.13	3.50	0.01	0.50	4.44	98.55
HL01	74.68	0.14	12.62	0.52	0.03	0.48	0.69	0.18	3.72	0.04	1.01	4.86	98.95
HL03	72.38	0.08	13.82	0.34	0.07	0.24	1.95	0.16	3.91	0.01	0.65	4.83	98.44
L05	74.90	0.05	10.67	0.29	0.12	0.35	2.93	1.55	1.90	0.01	1.94	4.65	99.36

表4 “磐龙玉”样品微量元素含量(10-6)

Table 4 Trace element content of “Panlong Jade” samples (10-6)

元素	H02	H04	LH03	LH04	HL01	HL03	L05
Li	4.61	3.93	4.10	3.74	12.30	3.71	15.90
Be	2.36	2.15	2.64	2.25	3.24	2.65	1.73
Sc	1.26	1.10	1.24	1.93	3.26	2.10	2.20
Ti	388.00	361.00	415.00	421.00	784.00	482.00	283.00
V	1.23	1.12	1.55	1.38	6.16	1.52	2.64
Cr	9.56	11.40	9.07	16.10	8.00	8.83	9.11
Mn	186.00	59.50	264.00	878.00	305.00	645.00	1084.00
Co	438.00	493.00	140.00	427.00	161.00	203.00	181.00
Ni	1.42	1.21	1.01	3.38	1.08	1.78	1.71
Cu	1.67	1.67	1.66	2.36	2.94	2.90	1.97
Zn	81.80	520.00	68.60	55.50	24.20	268.00	71.10
Ga	162.00	14.50	17.70	16.20	15.70	18.10	13.40
Ge	1.05	1.17	0.97	0.84	1.02	0.84	1.03
As	2.29	15.10	1.22	3.61	3.23	11.00	2.17
Rb	105.00	100.00	118.00	109.00	100.00	126.00	59.30
Sr	59.50	14.20	24.60	81.60	52.60	61.90	201.00
Y	19.50	17.40	15.50	17.60	17.80	19.90	14.30
Zr	73.70	70.20	77.00	77.20	110.00	87.40	69.00
Nb	4.83	4.05	5.53	4.91	5.90	7.57	4.20
Mo	1.23	1.22	2.57	1.19	1.50	3.45	1.48
Cd	0.26	2.55	0.33	0.32	0.03	1.09	0.18
In	0.03	0.03	0.02	0.02	0.02	0.04	0.02
Sn	2.74	2.26	3.42	3.05	2.67	3.73	2.02
Sb	1.16	1.58	0.69	1.31	1.10	1.27	0.69
Cs	7.24	5.98	7.30	5.29	8.69	7.22	5.55
Ba	186.00	118.00	135.00	156.00	545.00	155.00	220.00
La	27.50	24.00	23.80	25.10	33.20	24.60	17.40
Ce	27.90	27.00	28.10	29.20	56.60	27.30	33.70
Pr	5.13	4.64	4.32	4.57	6.16	4.54	3.63
Nd	17.90	16.00	14.90	16.20	21.10	15.90	13.40
Sm	3.57	3.24	2.85	3.25	3.82	3.16	2.84
Eu	0.28	0.27	0.23	0.23	0.52	0.24	0.40
Gd	3.15	2.74	2.49	2.75	3.11	2.89	2.75
Tb	0.58	0.53	0.43	0.50	0.56	0.52	0.47
Dy	3.54	3.33	2.73	3.29	3.25	3.35	2.76
Ho	0.73	0.64	0.57	0.65	0.66	0.70	0.57
Er	2.42	2.04	1.88	2.10	2.16	2.27	1.77
Tm	0.35	0.31	0.28	0.31	0.32	0.37	0.25
Yb	2.36	2.07	1.89	2.15	2.14	2.53	1.69
Lu	0.34	0.32	0.30	0.34	0.33	0.40	0.27
Hf	3.11	2.93	3.24	3.21	3.92	3.74	2.80
Ta	1.17	0.94	1.10	1.14	1.03	1.42	1.03
W	1171.00	1689.00	707.00	1589.00	849.00	1079.00	1099.00
Tl	0.94	0.45	1.25	0.70	0.84	1.34	0.47
Pb	10.90	14.30	6.06	26.70	8.95	13.90	38.40
Bi	0.10	0.07	0.05	0.11	0.06	0.10	0.02
Th	18.20	16.90	16.90	17.70	18.60	18.50	14.40
U	4.66	5.01	5.64	5.90	5.88	6.54	5.11
∑REE	95.75	87.13	84.77	90.64	133.93	88.77	81.90
∑LREE	82.28	75.15	74.20	78.55	121.40	75.74	71.37
∑HREE	13.47	11.98	10.57	12.09	12.53	13.03	10.53
∑LREE/ ∑HREE	6.11	6.27	7.02	6.50	9.69	5.81	6.78
(La/Sm)_N	4.97	4.78	5.39	4.99	5.61	5.03	3.96
(Gd/Lu)_N	1.15	1.06	1.03	1.00	1.16	0.89	1.26
δEu	0.25	0.27	0.26	0.23	0.45	0.24	0.43
δCe	0.54	0.59	0.63	0.62	0.90	0.59	0.99
Zr/Ti	0.19	0.19	0.19	0.18	0.14	0.18	0.24
Nb/Y	0.25	0.23	0.36	0.28	0.33	0.38	0.29
Nb/Ta	4.13	4.31	5.03	4.31	5.73	5.33	4.08
Th/U	3.91	3.37	3.00	3.00	3.16	2.83	2.82
Rb/Sr	1.76	7.04	4.80	1.34	1.90	2.04	0.30

表4 “磐龙玉”样品微量元素含量(10-6)

Table 4 Trace element content of “Panlong Jade” samples (10-6)

元素	H02	H04	LH03	LH04	HL01	HL03	L05
Li	4.61	3.93	4.10	3.74	12.30	3.71	15.90
Be	2.36	2.15	2.64	2.25	3.24	2.65	1.73
Sc	1.26	1.10	1.24	1.93	3.26	2.10	2.20
Ti	388.00	361.00	415.00	421.00	784.00	482.00	283.00
V	1.23	1.12	1.55	1.38	6.16	1.52	2.64
Cr	9.56	11.40	9.07	16.10	8.00	8.83	9.11
Mn	186.00	59.50	264.00	878.00	305.00	645.00	1084.00
Co	438.00	493.00	140.00	427.00	161.00	203.00	181.00
Ni	1.42	1.21	1.01	3.38	1.08	1.78	1.71
Cu	1.67	1.67	1.66	2.36	2.94	2.90	1.97
Zn	81.80	520.00	68.60	55.50	24.20	268.00	71.10
Ga	162.00	14.50	17.70	16.20	15.70	18.10	13.40
Ge	1.05	1.17	0.97	0.84	1.02	0.84	1.03
As	2.29	15.10	1.22	3.61	3.23	11.00	2.17
Rb	105.00	100.00	118.00	109.00	100.00	126.00	59.30
Sr	59.50	14.20	24.60	81.60	52.60	61.90	201.00
Y	19.50	17.40	15.50	17.60	17.80	19.90	14.30
Zr	73.70	70.20	77.00	77.20	110.00	87.40	69.00
Nb	4.83	4.05	5.53	4.91	5.90	7.57	4.20
Mo	1.23	1.22	2.57	1.19	1.50	3.45	1.48
Cd	0.26	2.55	0.33	0.32	0.03	1.09	0.18
In	0.03	0.03	0.02	0.02	0.02	0.04	0.02
Sn	2.74	2.26	3.42	3.05	2.67	3.73	2.02
Sb	1.16	1.58	0.69	1.31	1.10	1.27	0.69
Cs	7.24	5.98	7.30	5.29	8.69	7.22	5.55
Ba	186.00	118.00	135.00	156.00	545.00	155.00	220.00
La	27.50	24.00	23.80	25.10	33.20	24.60	17.40
Ce	27.90	27.00	28.10	29.20	56.60	27.30	33.70
Pr	5.13	4.64	4.32	4.57	6.16	4.54	3.63
Nd	17.90	16.00	14.90	16.20	21.10	15.90	13.40
Sm	3.57	3.24	2.85	3.25	3.82	3.16	2.84
Eu	0.28	0.27	0.23	0.23	0.52	0.24	0.40
Gd	3.15	2.74	2.49	2.75	3.11	2.89	2.75
Tb	0.58	0.53	0.43	0.50	0.56	0.52	0.47
Dy	3.54	3.33	2.73	3.29	3.25	3.35	2.76
Ho	0.73	0.64	0.57	0.65	0.66	0.70	0.57
Er	2.42	2.04	1.88	2.10	2.16	2.27	1.77
Tm	0.35	0.31	0.28	0.31	0.32	0.37	0.25
Yb	2.36	2.07	1.89	2.15	2.14	2.53	1.69
Lu	0.34	0.32	0.30	0.34	0.33	0.40	0.27
Hf	3.11	2.93	3.24	3.21	3.92	3.74	2.80
Ta	1.17	0.94	1.10	1.14	1.03	1.42	1.03
W	1171.00	1689.00	707.00	1589.00	849.00	1079.00	1099.00
Tl	0.94	0.45	1.25	0.70	0.84	1.34	0.47
Pb	10.90	14.30	6.06	26.70	8.95	13.90	38.40
Bi	0.10	0.07	0.05	0.11	0.06	0.10	0.02
Th	18.20	16.90	16.90	17.70	18.60	18.50	14.40
U	4.66	5.01	5.64	5.90	5.88	6.54	5.11
∑REE	95.75	87.13	84.77	90.64	133.93	88.77	81.90
∑LREE	82.28	75.15	74.20	78.55	121.40	75.74	71.37
∑HREE	13.47	11.98	10.57	12.09	12.53	13.03	10.53
∑LREE/ ∑HREE	6.11	6.27	7.02	6.50	9.69	5.81	6.78
(La/Sm)_N	4.97	4.78	5.39	4.99	5.61	5.03	3.96
(Gd/Lu)_N	1.15	1.06	1.03	1.00	1.16	0.89	1.26
δEu	0.25	0.27	0.26	0.23	0.45	0.24	0.43
δCe	0.54	0.59	0.63	0.62	0.90	0.59	0.99
Zr/Ti	0.19	0.19	0.19	0.18	0.14	0.18	0.24
Nb/Y	0.25	0.23	0.36	0.28	0.33	0.38	0.29
Nb/Ta	4.13	4.31	5.03	4.31	5.73	5.33	4.08
Th/U	3.91	3.37	3.00	3.00	3.16	2.83	2.82
Rb/Sr	1.76	7.04	4.80	1.34	1.90	2.04	0.30

图10 “磐龙玉”原始地幔标准化微量元素蛛网图解(a)和球粒陨石标准化稀土元素配分图(b)(标准化值据文献[23])

Fig.10 Primitive mantle normalized trace element spider diagrams (a) and chondrite-normalized REE distribution patterns (b) (normalization values after reference[23])

图11 “磐龙玉”锆石阴极发光图像和测点位置

Fig.11 CL images and analysis spots of zircon grains in “Panlong Jade” samples

表5 “磐龙玉”锆石样本计算年龄数据

Table 5 Calculation of age data of zircons from “Panlong Jade”

样品编号	含量(10^-6)			²³²Th/ ²³⁸U	同位素比值						同位素年龄(Ma)						谐和度 (%)
样品编号	U	Th	Pb	²³²Th/ ²³⁸U	²⁰⁷Pb/ ²⁰⁶Pb	1σ	²⁰⁷Pb/ ²³⁵U	1σ	²⁰⁷Pb/ ²³⁵U	1σ	²⁰⁷Pb/ ²⁰⁶Pb	1σ	²⁰⁷Pb/ ²³⁵U	1σ	²⁰⁶Pb/ ²³⁸U	1σ	谐和度 (%)
LH10-01	1648.30	901.79	86.45	0.52682	0.05073	0.00041	0.25349	0.00415	0.03607	0.00047	228.36	18.56	229.40	3.36	228.44	2.91	99.58
LH10-02	810.29	466.33	35.65	0.56302	0.05176	0.00117	0.25463	0.00614	0.03578	0.00074	274.77	51.67	230.33	4.97	226.62	4.60	98.39
LH10-03	567.14	434.53	28.71	0.72014	0.04975	0.00060	0.24838	0.00477	0.03608	0.00067	183.54	28.01	225.26	3.88	228.49	4.16	98.57
LH10-04	1607.72	963.61	76.84	0.57496	0.05060	0.00062	0.25072	0.00443	0.03587	0.00064	222.57	28.18	227.16	3.60	227.21	3.97	99.98
LH10-05	1149.91	619.22	54.13	0.51749	0.05108	0.00068	0.25490	0.00471	0.03612	0.00068	244.64	30.85	230.55	3.81	228.71	4.22	99.20
LH10-06	674.30	248.63	33.94	0.34917	0.05093	0.00076	0.25518	0.00450	0.03610	0.00050	237.61	34.51	230.77	3.64	228.63	3.10	99.07
LH10-07	132.65	64.95	6.50	0.46040	0.05103	0.00136	0.25144	0.00680	0.03580	0.00048	242.27	61.58	227.74	5.52	226.75	2.98	99.56
LH10-08	560.77	402.55	27.46	0.67997	0.05130	0.00095	0.25225	0.00465	0.03570	0.00057	254.43	42.51	228.40	3.77	226.11	3.53	99.00
LH10-09	1507.83	612.43	70.15	0.38155	0.05046	0.00053	0.24916	0.00359	0.03573	0.00043	216.07	24.26	225.89	2.92	226.29	2.66	99.83
LH10-10	1208.20	637.94	64.97	0.49588	0.05122	0.00079	0.25450	0.00551	0.03609	0.00044	250.95	35.65	230.23	4.46	228.57	2.77	99.28
LH10-11	948.85	547.37	51.16	0.54084	0.05070	0.00104	0.25148	0.00636	0.03608	0.00045	227.07	47.44	227.77	5.16	228.52	2.82	99.67
LH10-12	1017.20	457.14	46.28	0.42812	0.05135	0.00078	0.25471	0.00434	0.03597	0.00052	256.57	35.00	230.40	3.51	227.81	3.21	98.88
LH10-13	1174.50	707.55	55.22	0.57174	0.05124	0.00084	0.25677	0.00471	0.03631	0.00054	251.54	37.80	232.06	3.81	229.94	3.35	99.08
LH10-14	1517.29	856.30	78.92	0.53048	0.05082	0.00080	0.25416	0.00319	0.03598	0.00053	232.64	36.36	229.95	2.59	227.86	3.32	99.09
LH10-15	1174.06	568.44	50.59	0.46255	0.05032	0.00061	0.24788	0.00491	0.03562	0.00051	209.59	28.27	224.86	3.99	225.60	3.17	99.67
LH10-16	954.84	503.03	46.37	0.49942	0.05130	0.00067	0.25673	0.00455	0.03614	0.00048	254.21	30.25	232.02	3.68	228.87	2.97	98.64
LH10-17	626.88	310.71	26.31	0.46621	0.05126	0.00128	0.25240	0.00774	0.03558	0.00054	252.45	57.45	228.52	6.28	225.39	3.35	98.63

表5 “磐龙玉”锆石样本计算年龄数据

Table 5 Calculation of age data of zircons from “Panlong Jade”

样品编号	含量(10^-6)			²³²Th/ ²³⁸U	同位素比值						同位素年龄(Ma)						谐和度 (%)
样品编号	U	Th	Pb	²³²Th/ ²³⁸U	²⁰⁷Pb/ ²⁰⁶Pb	1σ	²⁰⁷Pb/ ²³⁵U	1σ	²⁰⁷Pb/ ²³⁵U	1σ	²⁰⁷Pb/ ²⁰⁶Pb	1σ	²⁰⁷Pb/ ²³⁵U	1σ	²⁰⁶Pb/ ²³⁸U	1σ	谐和度 (%)
LH10-01	1648.30	901.79	86.45	0.52682	0.05073	0.00041	0.25349	0.00415	0.03607	0.00047	228.36	18.56	229.40	3.36	228.44	2.91	99.58
LH10-02	810.29	466.33	35.65	0.56302	0.05176	0.00117	0.25463	0.00614	0.03578	0.00074	274.77	51.67	230.33	4.97	226.62	4.60	98.39
LH10-03	567.14	434.53	28.71	0.72014	0.04975	0.00060	0.24838	0.00477	0.03608	0.00067	183.54	28.01	225.26	3.88	228.49	4.16	98.57
LH10-04	1607.72	963.61	76.84	0.57496	0.05060	0.00062	0.25072	0.00443	0.03587	0.00064	222.57	28.18	227.16	3.60	227.21	3.97	99.98
LH10-05	1149.91	619.22	54.13	0.51749	0.05108	0.00068	0.25490	0.00471	0.03612	0.00068	244.64	30.85	230.55	3.81	228.71	4.22	99.20
LH10-06	674.30	248.63	33.94	0.34917	0.05093	0.00076	0.25518	0.00450	0.03610	0.00050	237.61	34.51	230.77	3.64	228.63	3.10	99.07
LH10-07	132.65	64.95	6.50	0.46040	0.05103	0.00136	0.25144	0.00680	0.03580	0.00048	242.27	61.58	227.74	5.52	226.75	2.98	99.56
LH10-08	560.77	402.55	27.46	0.67997	0.05130	0.00095	0.25225	0.00465	0.03570	0.00057	254.43	42.51	228.40	3.77	226.11	3.53	99.00
LH10-09	1507.83	612.43	70.15	0.38155	0.05046	0.00053	0.24916	0.00359	0.03573	0.00043	216.07	24.26	225.89	2.92	226.29	2.66	99.83
LH10-10	1208.20	637.94	64.97	0.49588	0.05122	0.00079	0.25450	0.00551	0.03609	0.00044	250.95	35.65	230.23	4.46	228.57	2.77	99.28
LH10-11	948.85	547.37	51.16	0.54084	0.05070	0.00104	0.25148	0.00636	0.03608	0.00045	227.07	47.44	227.77	5.16	228.52	2.82	99.67
LH10-12	1017.20	457.14	46.28	0.42812	0.05135	0.00078	0.25471	0.00434	0.03597	0.00052	256.57	35.00	230.40	3.51	227.81	3.21	98.88
LH10-13	1174.50	707.55	55.22	0.57174	0.05124	0.00084	0.25677	0.00471	0.03631	0.00054	251.54	37.80	232.06	3.81	229.94	3.35	99.08
LH10-14	1517.29	856.30	78.92	0.53048	0.05082	0.00080	0.25416	0.00319	0.03598	0.00053	232.64	36.36	229.95	2.59	227.86	3.32	99.09
LH10-15	1174.06	568.44	50.59	0.46255	0.05032	0.00061	0.24788	0.00491	0.03562	0.00051	209.59	28.27	224.86	3.99	225.60	3.17	99.67
LH10-16	954.84	503.03	46.37	0.49942	0.05130	0.00067	0.25673	0.00455	0.03614	0.00048	254.21	30.25	232.02	3.68	228.87	2.97	98.64
LH10-17	626.88	310.71	26.31	0.46621	0.05126	0.00128	0.25240	0.00774	0.03558	0.00054	252.45	57.45	228.52	6.28	225.39	3.35	98.63

表6 “磐龙玉”锆石微量元素含量(10-6)

Table 6 Trace element content of zircons from “Panlong Jade” samples (10-6)

样品编号	Ti	Sr	Nb	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb
LH10-01	-0.74	0.26	22.93	0.34	41.26	0.27	3.42	8.14	0.08	54.05	20.68
LH10-02	0.92	0.34	5.39	0.03	26.53	0.25	7.10	14.76	0.20	75.76	27.64
LH10-03	3.76	0.27	4.36	0.01	31.45	0.22	3.95	7.51	0.23	40.59	13.59
LH10-04	1.25	0.41	22.19	0.02	44.32	0.12	2.62	8.29	0.05	54.47	21.66
LH10-05	1.12	0.71	16.65	0.23	33.70	0.52	5.26	8.35	0.15	45.48	16.91
LH10-06	0.84	0.27	10.30	0.05	20.82	0.11	1.72	4.73	0.08	28.77	11.36
LH10-07	8.55	1.24	0.92	1.00	8.05	0.49	3.84	4.66	0.74	20.55	6.65
LH10-08	5.01	0.94	3.41	20.39	73.42	7.62	42.72	27.24	0.69	95.75	30.54
LH10-09	1.74	1.55	24.76	0.11	48.99	0.38	4.26	10.55	0.16	60.85	23.48
LH10-10	2.25	0.33	13.22	-	24.58	0.08	1.62	5.25	0.06	34.91	14.02
LH10-11	0.39	0.55	7.57	0.23	28.24	0.34	5.51	15.21	0.11	85.94	31.98
LH10-12	6.62	0.71	17.14	1.16	41.16	3.43	56.69	192.62	12.82	600.87	115.92
LH10-13	2.55	0.78	10.74	2.47	40.04	1.59	12.81	19.15	0.20	93.64	33.21
LH10-14	2.82	0.60	20.19	0.04	37.69	0.20	2.52	8.27	0.10	48.68	18.78
LH10-15	1.88	5.05	17.57	0.18	38.20	0.59	5.80	9.32	0.19	46.32	17.78
LH10-16	0.83	0.51	9.23	8.92	50.40	4.43	24.39	18.46	0.06	83.71	29.85
LH10-17	2.50	1.64	7.24	0.36	18.44	0.86	7.33	10.55	0.17	42.77	15.92
样品编号	Dy	Ho	Er	Tm	Yb	Lu	Hf	Ta	δEu	δCe
LH10-01	261.10	92.50	414.32	83.50	728.55	109.87	8150.12	6.76	0.01	31.55
LH10-02	345.38	120.23	523.28	108.13	968.50	144.60	8824.99	1.60	0.01	31.15
LH10-03	165.79	58.42	259.67	54.28	500.25	80.46	7382.29	1.68	0.03	43.55
LH10-04	269.03	93.85	409.56	82.23	703.25	100.57	8438.72	6.55	0.01	104.50
LH10-05	208.61	74.79	324.15	67.07	586.45	87.08	8846.35	4.80	0.02	17.04
LH10-06	146.46	53.43	241.42	50.64	447.19	71.14	8169.13	3.50	0.02	49.09
LH10-07	81.92	29.58	135.26	29.01	274.80	46.98	5647.70	0.37	0.20	2.82
LH10-08	335.32	115.01	488.91	97.83	872.00	134.32	7199.86	1.04	0.04	1.44
LH10-09	299.06	108.01	480.53	97.83	865.15	129.85	8300.22	6.16	0.01	35.87
LH10-10	180.54	64.31	296.37	59.55	515.99	80.65	7953.48	4.35	0.01	99.03
LH10-11	410.42	142.13	604.12	122.08	985.92	151.86	6629.24	1.92	0.01	20.26
LH10-12	771.88	164.97	541.42	94.55	760.91	108.53	8662.23	4.51	0.11	3.28
LH10-13	411.55	145.65	629.85	127.36	1114.15	168.36	8536.71	2.55	0.01	4.82
LH10-14	234.30	85.51	377.88	76.72	661.42	101.10	8408.59	5.71	0.01	53.41
LH10-15	225.39	80.31	365.73	72.17	653.00	97.56	8794.51	4.99	0.02	17.78
LH10-16	370.65	129.60	566.51	111.53	958.65	143.57	7497.28	2.17	-	1.95
LH10-17	196.92	69.84	309.69	65.56	596.61	90.52	8455.95	1.61	0.02	5.72

表6 “磐龙玉”锆石微量元素含量(10-6)

Table 6 Trace element content of zircons from “Panlong Jade” samples (10-6)

样品编号	Ti	Sr	Nb	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb
LH10-01	-0.74	0.26	22.93	0.34	41.26	0.27	3.42	8.14	0.08	54.05	20.68
LH10-02	0.92	0.34	5.39	0.03	26.53	0.25	7.10	14.76	0.20	75.76	27.64
LH10-03	3.76	0.27	4.36	0.01	31.45	0.22	3.95	7.51	0.23	40.59	13.59
LH10-04	1.25	0.41	22.19	0.02	44.32	0.12	2.62	8.29	0.05	54.47	21.66
LH10-05	1.12	0.71	16.65	0.23	33.70	0.52	5.26	8.35	0.15	45.48	16.91
LH10-06	0.84	0.27	10.30	0.05	20.82	0.11	1.72	4.73	0.08	28.77	11.36
LH10-07	8.55	1.24	0.92	1.00	8.05	0.49	3.84	4.66	0.74	20.55	6.65
LH10-08	5.01	0.94	3.41	20.39	73.42	7.62	42.72	27.24	0.69	95.75	30.54
LH10-09	1.74	1.55	24.76	0.11	48.99	0.38	4.26	10.55	0.16	60.85	23.48
LH10-10	2.25	0.33	13.22	-	24.58	0.08	1.62	5.25	0.06	34.91	14.02
LH10-11	0.39	0.55	7.57	0.23	28.24	0.34	5.51	15.21	0.11	85.94	31.98
LH10-12	6.62	0.71	17.14	1.16	41.16	3.43	56.69	192.62	12.82	600.87	115.92
LH10-13	2.55	0.78	10.74	2.47	40.04	1.59	12.81	19.15	0.20	93.64	33.21
LH10-14	2.82	0.60	20.19	0.04	37.69	0.20	2.52	8.27	0.10	48.68	18.78
LH10-15	1.88	5.05	17.57	0.18	38.20	0.59	5.80	9.32	0.19	46.32	17.78
LH10-16	0.83	0.51	9.23	8.92	50.40	4.43	24.39	18.46	0.06	83.71	29.85
LH10-17	2.50	1.64	7.24	0.36	18.44	0.86	7.33	10.55	0.17	42.77	15.92
样品编号	Dy	Ho	Er	Tm	Yb	Lu	Hf	Ta	δEu	δCe
LH10-01	261.10	92.50	414.32	83.50	728.55	109.87	8150.12	6.76	0.01	31.55
LH10-02	345.38	120.23	523.28	108.13	968.50	144.60	8824.99	1.60	0.01	31.15
LH10-03	165.79	58.42	259.67	54.28	500.25	80.46	7382.29	1.68	0.03	43.55
LH10-04	269.03	93.85	409.56	82.23	703.25	100.57	8438.72	6.55	0.01	104.50
LH10-05	208.61	74.79	324.15	67.07	586.45	87.08	8846.35	4.80	0.02	17.04
LH10-06	146.46	53.43	241.42	50.64	447.19	71.14	8169.13	3.50	0.02	49.09
LH10-07	81.92	29.58	135.26	29.01	274.80	46.98	5647.70	0.37	0.20	2.82
LH10-08	335.32	115.01	488.91	97.83	872.00	134.32	7199.86	1.04	0.04	1.44
LH10-09	299.06	108.01	480.53	97.83	865.15	129.85	8300.22	6.16	0.01	35.87
LH10-10	180.54	64.31	296.37	59.55	515.99	80.65	7953.48	4.35	0.01	99.03
LH10-11	410.42	142.13	604.12	122.08	985.92	151.86	6629.24	1.92	0.01	20.26
LH10-12	771.88	164.97	541.42	94.55	760.91	108.53	8662.23	4.51	0.11	3.28
LH10-13	411.55	145.65	629.85	127.36	1114.15	168.36	8536.71	2.55	0.01	4.82
LH10-14	234.30	85.51	377.88	76.72	661.42	101.10	8408.59	5.71	0.01	53.41
LH10-15	225.39	80.31	365.73	72.17	653.00	97.56	8794.51	4.99	0.02	17.78
LH10-16	370.65	129.60	566.51	111.53	958.65	143.57	7497.28	2.17	-	1.95
LH10-17	196.92	69.84	309.69	65.56	596.61	90.52	8455.95	1.61	0.02	5.72

图12 “磐龙玉”锆石球粒陨石标准化稀土元素配分图(标准化值据文献[23])

Fig.12 Chondrite-normalized REE distribution patterns of zirons from “Panlong Jade” (normalization values after reference[23])

图13 “磐龙玉”锆石岩浆和热液锆石判别图[25]

Fig.13 Discrimination plots for magmatic and hydrothermal zircon[25]

图14 “磐龙玉”锆石U-Pb谐和图(a)和206Pb/238U年龄分布图(b)

Fig.14 U-Pb concordant diagram(a) and 206Pb/238U age distribution diagram(b) of zircons from “Panlong Jade”

图15 “磐龙玉”样品Zr/Ti-Nb/Y图解[29]

Fig.15 Zr/Ti-Nb/Y diagrams of “Panlong Jade” samples[29]

表7 “磐龙玉”样本温度计算结果

Table 7 Temperature calculation results for “Panlong Jade”

点位	HL7-1	HL7-2	HL8-1	HL8-2	HL8-3	L10-1	L10-2	L11-1	L11-2	L11-3
Ti	0.0044	0.0055	0.0054	0.0015	0.0054	0.0010	0.0044	0.0039	0.0093	0.0134
Mg/(Mg+Fe)	0.3918	0.3727	0.3271	0.3745	0.4055	0.5542	0.2920	0.3766	0.4476	0.5082
变质温度(℃)	315	334	330	228	334	209	310	304	394	442

参考文献 31

[1]	吉林省质量技术监督局. 磐龙玉: DB 22/T 2744—2017[S]. 北京: 中国标准出版社, 2017.
[2]	李凯春, 杨言辰, 陈天文, 等. 吉林小红石砬子铅锌银矿区综合物探三维建模及矿体定位预测[J]. 世界地质, 2022, 41(4): 737-750.
[3]	李勇. 吉林省磐石市小红石砬子铅锌矿床成因与构造背景[D]. 长春: 吉林大学, 2017.
[4]	王贵龙, 王达, 白峰, 等. 小红石砬子铅锌(银)矿床成因:来自S-Pb同位素和元素特征的证据[J]. 岩石学报, 2024, 40(1): 241-266.
[5]	汪志刚. 吉林东部中生代内生金属矿床成矿作用研究[D]. 长春: 吉林大学, 2012.
[6]	王磊. 吉林大黑山钼矿矿床地质特征及成矿模式研究[D]. 长春: 吉林大学, 2012.
[7]	杨群, 任云生, 孙新浩, 等. 吉林省中部地区石咀铜多金属矿床成矿时代及矿床成因[J]. 地质论评, 2019, 65(增刊1): 251-252.
[8]	WU F Y, SUN D Y, GE W C, et al. Geochronology of the Phanerozoic granitoids in northeastern China[J]. Journal of Asian Earth Sciences, 2011, 41(1): 1-30.
[9]	常景娟. 吉林省磐石市小红石砬子铅锌矿地质特征及成因研究[D]. 长春: 吉林大学, 2016.
[10]	孟祥振, 赵梅芳. 维氏硬度的法定计量单位及其换算[J]. 宝石和宝石学杂志, 2007, 9(2): 53.
[11]	国家质量监督检验检疫总局, 中国国家标准化管理委员会. 电子探针定量分析方法通则: GB/T 15074—2008[S]. 北京: 中国标准出版社, 2009.
[12]	闻辂, 梁婉雪, 章正刚, 等. 矿物红外光谱学[M]. 重庆: 重庆大学出版社, 1989: 1-190.
[13]	裴景成, 范陆薇, 谢浩. 云南龙陵黄龙玉的振动光谱及XRD光谱表征[J]. 光谱学与光谱分析, 2014, 34(12): 3411-3414.
[14]	曹淑慧, 张立飞, 孙樯, 等. 高压下多硅白云母的拉曼光谱学研究[J]. 岩石矿物学杂志, 2006, 25(1): 71-76.
[15]	毛荐, 柴林涛, 郭守国, 等. 缅甸墨绿色长石质玉石谱学特征研究[J]. 光谱学与光谱分析, 2013, 32(5): 1388-1391.
[16]	张勇, 魏然, 柯捷, 等. 黄色和红色石英质玉石的颜色成因研究[J]. 岩石矿物学杂志, 2016, 35(1): 139-146.
[17]	POTH P. Corrosion books: The iron oxides-structure, properties, reactions, occurences and uses. by: R. M. Cornell, U. schwertmann[J]. Materials and Corrosion, 2004, 55(9): 704.
[18]	DEATON B C, BALSAM W L. Visible spectroscopy: a rapid method for determining hematite and goethite concentration in geological materials[J]. Journal of Sedimentary Research, 1991, 61(4): 628-632.
[19]	BALSAM W, JI J, RENOCK D, et al. Determining hematite content from NUV/Vis/NIR spectra: Limits of detection[J]. American Mineralogist, 2014, 99(11/12): 2280-2291.
[20]	TORRENT J, SCHWERTMANN U, FECHTER H, et al. Quantitative relationships between soil color and hematite content[J]. Soil Science, 1983, 136(6): 354-358.
[21]	TAPPERT M C, RIVARD B, GILES D, et al. The mineral chemistry, near-infrared, and mid-infrared reflectance spectroscopy of phengite from the Olympic Dam IOCG deposit, South Australia[J]. Ore Geology Reviews, 2013, 53: 26-38.
[22]	URIBE-MOGOLLON C, MAHER K. White mica geochemistry of the copper cliff porphyry Cu deposit: Insights from a vectoring tool applied to exploration[J]. Economic Geology, 2018, 113(6): 1269-1295.
[23]	SUN S S, MCDONOUGH W F. Chemical and isotopic systematics of oceanic basalts: Implications for mantle composition and processes[J]. Geological Society, London, Special Publications, 1989, 42(1): 313-345.
[24]	朱弟成, 莫宣学, 王立全, 等. 西藏冈底斯东部察隅高分异I型花岗岩的成因:锆石U-Pb年代学、地球化学和Sr-Nd-Hf同位素约束[J]. 中国科学(地球科学), 2009, 39(7): 833-848.
[25]	HOSKIN P W O. Trace-element composition of hydrothermal zircon and the alteration of Hadean zircon from the Jack Hills, Australia[J]. Geochimica et Cosmochimica Acta, 2005, 69(3): 637-648.
[26]	潘兆橹, 赵爱醒, 潘铁虹. 结晶学及矿物学-下册[M]. 3版. 北京: 地质出版社, 1994: 1-282.
[27]	李勇, 任云生, 陈聪, 等. 吉林小红石砬子矿床赋矿地层形成时代及其地质意义[J]. 中国锰业, 2017, 35(3): 78-80.
[28]	王旭, 杨雷. 吉林磐石“磐龙玉”矿床地质特征及成因探讨[J]. 中国非金属矿工业导刊, 2021(3): 22-26.
[29]	WINCHESTER J A, FLOYD P A. Geochemical discrimination of different magma series and their differentiation products using immobile elements[J]. Chemical Geology, 1977, 20: 325-343.
[30]	WU C M, CHEN H X. Calibration of a Ti-in-muscovite geothermometer for ilmenite-and Al₂SiO₅-bearing metapelites[J]. Lithos, 2015, 212/213/214/215: 122-127.
[31]	曹花花. 华北板块北缘东段晚古生代—早中生代火成岩的年代学与地球化学研究[D]. 长春: 吉林大学, 2013.