贵州普克金矿区黄铁矿和方解石地球化学特征及地质意义

doi:10.19657/j.geoscience.1000-8527.2024.094

摘要/Abstract

摘要：

贵州普克金矿区位于我国著名的滇―黔―桂“金三角”地区泥堡大型金矿西南方向的外围区域,与泥堡金矿处于相同的大地构造环境,地层特征、构造样式基本相同,成矿地质条件良好,对其开展成矿流体性质和物质来源研究,有助于理解普克矿区金的成矿作用,并为下一步找矿勘探提供新的参考。本文在对普克金矿区地表发育的(褐铁矿化)黄铁矿-方解石脉进行野外地质调查的基础上,开展矿物学、方解石稀土元素以及黄铁矿电子探针与微区原位LA-ICP-MS分析,结果显示普克金矿区内大部分方解石脉显示出与泥堡金矿床不含矿方解石脉相似的稀土元素配分特征,少数方解石样品显示出与黔西南卡林型金矿成矿期方解石稀土元素一样的中稀土元素富集和Eu正异常特征。该类方解石脉中的黄铁矿Au元素含量高出平均地壳丰度及沉积成因黄铁矿中Au的含量几个数量级,且Au在黄铁矿中以Au⁺离子形式存在,表明这些黄铁矿形成于金成矿期的热液环境。含金方解石出现中稀土元素富集模式和Eu正异常特征,表明金成矿流体系还原性质。由于地壳抬升剥蚀的影响,普克金矿区内中稀土元素富集、Eu正异常的方解石脉在地表的露头较少,也可能与普克金矿有利成矿地层层位(二叠系峨眉山玄武岩组)埋深较大、能运移到现今地表层位(三叠系永宁镇组)的成矿热液相对较少有关,指示深部有较好的金成矿潜力。

关键词: 地球化学, 热液方解石, 黄铁矿, 中稀土元素富集, 普克金矿区

Abstract:

The Puke gold prospecting area is located 3 km southwest of the famous Nibao gold deposit, sharing the same regional geological background, similar stratigraphic characteristics, tectonic style, and ideal geolo-gical conditions for gold mineralization.Based on field observations of the calcite veins (limonitization) deve-loped on the surface and in drill holes, we conducted mineralogical analysis of calcite and pyrite, rare earth element (REE) analysis of calcite, electron probe micro-analysis (EPMA), and LA-ICP-MS analysis of pyrite to constrain the origin of the ore-forming fluids and materials in the Puke gold prospecting area.The results show that most of the calcite veins in the Puke gold prospect area have similar characteristics to those in the Nibao gold deposit; however, the latter does not contain ore-bearing calcite veins.Most calcite veins in the Puke gold prospect area exhibit REE patterns similar to those of the Nibao gold deposit, and a few calcite samples show positive Eu anomalies, similar to the calcite from the mineralization period of Carlin-type gold deposits in Southeastern Guizhou.However, the Au content of pyrite in these calcite veins is several orders of magnitude higher than that of the average crustal abundance and sedimentary pyrite, with Au existing in pyrite in the form of Au⁺.This suggests that these pyrite veins are of hydrothermal origin.The gold-bearing calcite exhibits an enrichment pattern of medium REE and positive Eu anomalies.This suggests that the gold-forming fluids are reducing, possibly controlled by acidic ore-forming fluids as in the case of the Nibao gold deposit.There are fewer calcite veins exposed on the surface in the Puke gold prospect area, possibly because the favorable ore-forming strata of the Puke gold are deeper.There is less ore-forming hydrothermal fluid transported to the pre-sent-day surface strata, implying that ideal gold mineralization developed at deeper levels.

Key words: geochemistry, hydrothermal calcite, pyrite, medium REE enrichment, the Puke gold prospect area

中图分类号:

P595
P618.51

刘旭, 戢兴忠, 陈强, 李源洪. 贵州普克金矿区黄铁矿和方解石地球化学特征及地质意义[J]. 现代地质, 2024, 38(04): 977-990.

LIU Xu, JI Xingzhong, CHEN Qiang, LI Yuanhong. Geochemical Characteristics and Geological Significance of Pyrite and Calcite in the Puke Gold Prospect Area, Guizhou Province[J]. Geoscience, 2024, 38(04): 977-990.

图/表 10

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样品号	La (10^-6)	Ce (10^-6)	Pr (10^-6)	Nd (10^-6)	Sm (10^-6)	Eu (10^-6)	Gd (10^-6)	Tb (10^-6)	Dy (10^-6)	Ho (10^-6)	Er (10^-6)	Tm (10^-6)	Yb (10^-6)	Lu (10^-6)	ΣREE (10^-6)	LREE/ HREE	La_N/ Yb_N	δEu	δCe
D9001-1	1.314	2.604	0.359	1.497	0.285	0.096	0.295	0.042	0.215	0.039	0.090	0.011	0.063	0.010	6.920	8.05	14.08	1.00	0.88
D9002-1	1.849	4.382	0.678	3.203	0.708	0.503	0.580	0.081	0.346	0.051	0.103	0.012	0.056	0.008	12.560	9.15	22.43	2.33	0.92
D9003-1	1.329	3.130	0.448	1.896	0.425	0.120	0.382	0.056	0.271	0.045	0.119	0.014	0.075	0.012	8.320	7.54	11.94	0.89	0.95
D9011-1	0.853	1.683	0.181	0.685	0.113	0.028	0.133	0.020	0.108	0.020	0.055	0.008	0.037	0.007	3.930	9.13	15.50	0.70	0.96
D9014-1	1.241	2.048	0.265	0.998	0.176	0.045	0.205	0.033	0.174	0.035	0.097	0.011	0.070	0.010	5.410	7.51	11.98	0.73	0.80
D9032-1	4.749	9.745	1.313	5.349	0.970	0.264	1.037	0.155	0.852	0.158	0.397	0.050	0.291	0.043	25.370	7.51	11.03	0.80	0.90
D9033-1	6.394	13.431	1.964	8.866	3.610	2.780	3.047	0.439	1.567	0.180	0.297	0.031	0.162	0.020	42.790	6.45	26.73	2.50	0.88
D9037-1	1.169	2.015	0.241	0.874	0.172	0.045	0.181	0.028	0.147	0.027	0.073	0.009	0.058	0.009	5.050	8.48	13.57	0.77	0.85
D9101-1	2.293	6.804	1.125	5.709	2.077	0.850	0.926	0.109	0.460	0.075	0.164	0.020	0.115	0.017	20.740	10.00	13.52	1.63	0.98
D9103-1	1.062	2.675	0.433	2.083	0.466	0.412	0.452	0.062	0.288	0.040	0.085	0.008	0.046	0.005	8.120	7.23	15.53	2.71	0.92
D9115-1	3.374	6.099	0.755	2.779	0.467	0.117	0.487	0.072	0.407	0.076	0.206	0.025	0.156	0.022	15.040	9.36	14.58	0.74	0.87
D9121-1	0.399	0.520	0.049	0.189	0.043	0.019	0.052	0.008	0.036	0.008	0.019	0.002	0.009	0.001	1.350	9.08	31.21	1.19	0.75
D9134-1	0.876	1.509	0.201	0.925	0.173	0.049	0.219	0.030	0.157	0.031	0.063	0.007	0.038	0.005	4.280	6.78	15.59	0.78	0.82
D9146-1	3.950	7.462	0.943	3.671	0.606	0.135	0.580	0.083	0.411	0.077	0.191	0.026	0.155	0.025	18.310	10.84	17.19	0.68	0.88
D9147-1	1.901	3.267	0.401	1.477	0.262	0.067	0.286	0.044	0.223	0.041	0.106	0.014	0.080	0.012	8.180	9.15	15.96	0.75	0.84
D9163-1	0.730	1.292	0.165	0.596	0.107	0.031	0.105	0.014	0.069	0.012	0.029	0.004	0.020	0.003	3.180	11.34	24.11	0.88	0.85
D9167-1	1.228	2.551	0.317	1.206	0.227	0.054	0.244	0.035	0.201	0.034	0.096	0.014	0.088	0.013	6.310	7.69	9.46	0.70	0.94
D9170-1	1.337	2.207	0.289	1.119	0.196	0.059	0.197	0.029	0.165	0.029	0.079	0.011	0.056	0.010	5.780	9.06	16.23	0.91	0.80
D9175-1	0.327	0.761	0.068	0.293	0.050	0.014	0.065	0.011	0.066	0.014	0.039	0.006	0.031	0.005	1.750	6.37	7.15	0.72	1.15
D9175-3	2.576	4.911	0.600	2.276	0.387	0.094	0.396	0.064	0.318	0.062	0.157	0.022	0.130	0.018	12.010	9.29	13.44	0.73	0.90
D9179-1	2.216	5.019	0.722	3.110	0.565	0.138	0.616	0.087	0.413	0.074	0.170	0.021	0.112	0.017	13.280	7.80	13.42	0.71	0.93
D9505-1	1.562	1.629	0.182	0.705	0.134	0.038	0.199	0.030	0.171	0.033	0.085	0.008	0.039	0.005	4.820	7.45	26.75	0.72	0.61
D9516-1	5.729	12.198	2.744	11.603	1.984	0.494	1.895	0.266	1.198	0.183	0.453	0.050	0.309	0.043	39.150	7.90	12.51	0.77	0.72
D9526-1	7.084	17.426	2.600	10.123	1.763	0.432	1.759	0.254	1.186	0.204	0.482	0.061	0.364	0.054	43.790	9.03	13.14	0.74	0.95
D9529-1	7.324	15.141	1.877	6.833	1.177	0.211	0.990	0.154	0.722	0.118	0.268	0.031	0.175	0.024	35.040	13.12	28.30	0.58	0.94

样品号	La (10^-6)	Ce (10^-6)	Pr (10^-6)	Nd (10^-6)	Sm (10^-6)	Eu (10^-6)	Gd (10^-6)	Tb (10^-6)	Dy (10^-6)	Ho (10^-6)	Er (10^-6)	Tm (10^-6)	Yb (10^-6)	Lu (10^-6)	ΣREE (10^-6)	LREE/ HREE	La_N/ Yb_N	δEu	δCe
D9001-1	1.314	2.604	0.359	1.497	0.285	0.096	0.295	0.042	0.215	0.039	0.090	0.011	0.063	0.010	6.920	8.05	14.08	1.00	0.88
D9002-1	1.849	4.382	0.678	3.203	0.708	0.503	0.580	0.081	0.346	0.051	0.103	0.012	0.056	0.008	12.560	9.15	22.43	2.33	0.92
D9003-1	1.329	3.130	0.448	1.896	0.425	0.120	0.382	0.056	0.271	0.045	0.119	0.014	0.075	0.012	8.320	7.54	11.94	0.89	0.95
D9011-1	0.853	1.683	0.181	0.685	0.113	0.028	0.133	0.020	0.108	0.020	0.055	0.008	0.037	0.007	3.930	9.13	15.50	0.70	0.96
D9014-1	1.241	2.048	0.265	0.998	0.176	0.045	0.205	0.033	0.174	0.035	0.097	0.011	0.070	0.010	5.410	7.51	11.98	0.73	0.80
D9032-1	4.749	9.745	1.313	5.349	0.970	0.264	1.037	0.155	0.852	0.158	0.397	0.050	0.291	0.043	25.370	7.51	11.03	0.80	0.90
D9033-1	6.394	13.431	1.964	8.866	3.610	2.780	3.047	0.439	1.567	0.180	0.297	0.031	0.162	0.020	42.790	6.45	26.73	2.50	0.88
D9037-1	1.169	2.015	0.241	0.874	0.172	0.045	0.181	0.028	0.147	0.027	0.073	0.009	0.058	0.009	5.050	8.48	13.57	0.77	0.85
D9101-1	2.293	6.804	1.125	5.709	2.077	0.850	0.926	0.109	0.460	0.075	0.164	0.020	0.115	0.017	20.740	10.00	13.52	1.63	0.98
D9103-1	1.062	2.675	0.433	2.083	0.466	0.412	0.452	0.062	0.288	0.040	0.085	0.008	0.046	0.005	8.120	7.23	15.53	2.71	0.92
D9115-1	3.374	6.099	0.755	2.779	0.467	0.117	0.487	0.072	0.407	0.076	0.206	0.025	0.156	0.022	15.040	9.36	14.58	0.74	0.87
D9121-1	0.399	0.520	0.049	0.189	0.043	0.019	0.052	0.008	0.036	0.008	0.019	0.002	0.009	0.001	1.350	9.08	31.21	1.19	0.75
D9134-1	0.876	1.509	0.201	0.925	0.173	0.049	0.219	0.030	0.157	0.031	0.063	0.007	0.038	0.005	4.280	6.78	15.59	0.78	0.82
D9146-1	3.950	7.462	0.943	3.671	0.606	0.135	0.580	0.083	0.411	0.077	0.191	0.026	0.155	0.025	18.310	10.84	17.19	0.68	0.88
D9147-1	1.901	3.267	0.401	1.477	0.262	0.067	0.286	0.044	0.223	0.041	0.106	0.014	0.080	0.012	8.180	9.15	15.96	0.75	0.84
D9163-1	0.730	1.292	0.165	0.596	0.107	0.031	0.105	0.014	0.069	0.012	0.029	0.004	0.020	0.003	3.180	11.34	24.11	0.88	0.85
D9167-1	1.228	2.551	0.317	1.206	0.227	0.054	0.244	0.035	0.201	0.034	0.096	0.014	0.088	0.013	6.310	7.69	9.46	0.70	0.94
D9170-1	1.337	2.207	0.289	1.119	0.196	0.059	0.197	0.029	0.165	0.029	0.079	0.011	0.056	0.010	5.780	9.06	16.23	0.91	0.80
D9175-1	0.327	0.761	0.068	0.293	0.050	0.014	0.065	0.011	0.066	0.014	0.039	0.006	0.031	0.005	1.750	6.37	7.15	0.72	1.15
D9175-3	2.576	4.911	0.600	2.276	0.387	0.094	0.396	0.064	0.318	0.062	0.157	0.022	0.130	0.018	12.010	9.29	13.44	0.73	0.90
D9179-1	2.216	5.019	0.722	3.110	0.565	0.138	0.616	0.087	0.413	0.074	0.170	0.021	0.112	0.017	13.280	7.80	13.42	0.71	0.93
D9505-1	1.562	1.629	0.182	0.705	0.134	0.038	0.199	0.030	0.171	0.033	0.085	0.008	0.039	0.005	4.820	7.45	26.75	0.72	0.61
D9516-1	5.729	12.198	2.744	11.603	1.984	0.494	1.895	0.266	1.198	0.183	0.453	0.050	0.309	0.043	39.150	7.90	12.51	0.77	0.72
D9526-1	7.084	17.426	2.600	10.123	1.763	0.432	1.759	0.254	1.186	0.204	0.482	0.061	0.364	0.054	43.790	9.03	13.14	0.74	0.95
D9529-1	7.324	15.141	1.877	6.833	1.177	0.211	0.990	0.154	0.722	0.118	0.268	0.031	0.175	0.024	35.040	13.12	28.30	0.58	0.94

样品号	As	Se	Co	Te	Fe	Ni	Cu	Zn	S	Ag	Sb	Au	总量(%)
D9001-1-1	0.019	0	0.061	0	46.763	0	0.008	0	53.060	0.014	0.013	0	99.94
D9001-1-2	0.024	0	0.048	0.009	46.103	0.021	0.004	0.017	52.676	0	0.019	0	98.92
D9001-1-3	0.035	0	0.038	0	46.559	0	0.012	0.019	52.949	0	0	0.007	99.62
D9001-1-4	0.054	0	0.026	0	46.195	0.006	0	0	52.717	0	0	0.012	99.01
D9001-1-5	0.025	0	0.051	0	46.624	0.003	0.012	0	52.742	0	0.010	0.056	99.52
D9001-1-6	0	0.011	0.022	0	46.868	0	0	0	52.629	0.002	0	0.025	99.56
D9001-1-7	0.044	0.016	0.078	0	46.593	0	0.036	0	52.765	0.004	0	0.005	99.54
D9001-1-8	0.012	0	0.068	0.016	46.550	0.013	0.011	0.017	53.208	0.013	0.016	0	99.92
D9001-1-9	0.059	0	0.048	0	45.912	0	0.011	0.036	53.300	0	0.005	0	99.37
D9001-1-10	0.057	0.020	0.02	0	46.407	0	0.007	0.023	53.085	0.007	0	0.030	99.66
D9103-1-1	0.051	0	0.012	0.002	46.423	0	0.021	0	53.209	0	0	0	99.72
D9103-1-2	0.020	0.023	0.013	0	47.319	0.055	0	0.041	53.222	0	0.033	0.012	100.74
D9103-1-3	0	0	0.043	0.017	46.798	0.039	0.015	0.021	52.413	0.008	0	0.023	99.38
D9103-1-4	0.025	0	0.036	0	46.276	0	0.01	0.01	52.927	0.006	0.001	0.008	99.30
D9103-1-5	0	0.05	0.025	0	46.787	0	0	0.007	52.924	0.012	0	0	99.81
D9103-1-6	0.064	0	0.033	0	46.138	0.003	0.051	0	52.972	0.002	0	0.017	99.28
D9103-1-7	0.023	0	0.054	0	46.783	0.006	0	0.01	52.736	0	0.008	0	99.62
D9103-1-8	0.050	0	0.028	0.026	46.716	0	0.008	0	52.706	0	0	0.030	99.56
D9103-1-9	0.019	0	0.007	0	47.060	0.021	0.017	0	52.850	0	0.007	0.052	100.03
D9103-1-10	0	0.021	0.023	0.025	47.273	0.015	0.009	0.004	53.136	0	0	0	100.51
D9103-1-11	0.008	0.014	0.052	0	46.142	0	0	0.029	52.833	0.021	0	0.002	99.10
D9103-1-12	0.021	0	0.065	0	46.896	0	0	0	53.044	0	0	0.035	100.06
D9103-1-13	0.028	0.046	0.004	0.019	46.593	0	0	0.014	53.285	0	0	0	99.99
D9101-1-1	0.03	0.012	0.109	0	46.689	0.082	0	0.011	52.122	0.002	0.004	0	99.06
D9101-1-2	0.038	0	0.063	0	46.490	0.029	0.001	0	52.905	0	0	0.046	99.57
D9101-1-4	0.030	0	0.084	0.014	45.643	0	0	0	52.304	0.002	0	0	98.08
D9101-1-5	0	0	0.058	0	46.180	0	0.019	0.057	52.601	0	0	0.063	98.98
D9101-1-3	0.048	0	0.105	0.001	45.764	0	0	0.016	52.341	0.004	0	0	98.28
D9101-1-6	0.026	0	0.058	0	45.881	0.027	0.007	0	53.118	0	0.016	0.062	99.20
D9101-1-7	0.045	0.022	0.084	0	45.916	0	0.025	0	51.937	0	0.019	0.025	98.07
D9101-1-8	0	0	0.065	0	46.141	0.014	0.038	0	52.312	0.011	0.013	0.003	98.60
D9033-1-1	0.017	0.143	0.112	0	45.821	0	0.015	0.017	52.987	0	0.014	0.021	99.15
D9033-1-2	0.045	0.023	0.031	0.027	45.883	0	0	0.012	53.518	0	0	0.016	99.56
D9033-1-4	0.043	0	0.064	0.022	45.231	0.077	0.068	0.058	53.019	0.013	0.010	0	98.61
D9033-1-3	0.016	0	0.102	0	45.901	0.057	0.075	0	52.903	0	0.006	0.002	99.06
D9033-1-6	0.023	0	0.022	0	45.897	0.168	0.02	0.009	53.418	0	0.002	0.033	99.60
D9033-1-7	0.006	0.021	0.047	0	45.753	0.119	0.312	0	53.338	0.016	0.002	0	99.61
D9033-1-5	0.055	0.028	0.067	0	45.730	0.019	0.007	0.056	53.254	0	0	0.008	99.22

样品号	As	Se	Co	Te	Fe	Ni	Cu	Zn	S	Ag	Sb	Au	总量(%)
D9001-1-1	0.019	0	0.061	0	46.763	0	0.008	0	53.060	0.014	0.013	0	99.94
D9001-1-2	0.024	0	0.048	0.009	46.103	0.021	0.004	0.017	52.676	0	0.019	0	98.92
D9001-1-3	0.035	0	0.038	0	46.559	0	0.012	0.019	52.949	0	0	0.007	99.62
D9001-1-4	0.054	0	0.026	0	46.195	0.006	0	0	52.717	0	0	0.012	99.01
D9001-1-5	0.025	0	0.051	0	46.624	0.003	0.012	0	52.742	0	0.010	0.056	99.52
D9001-1-6	0	0.011	0.022	0	46.868	0	0	0	52.629	0.002	0	0.025	99.56
D9001-1-7	0.044	0.016	0.078	0	46.593	0	0.036	0	52.765	0.004	0	0.005	99.54
D9001-1-8	0.012	0	0.068	0.016	46.550	0.013	0.011	0.017	53.208	0.013	0.016	0	99.92
D9001-1-9	0.059	0	0.048	0	45.912	0	0.011	0.036	53.300	0	0.005	0	99.37
D9001-1-10	0.057	0.020	0.02	0	46.407	0	0.007	0.023	53.085	0.007	0	0.030	99.66
D9103-1-1	0.051	0	0.012	0.002	46.423	0	0.021	0	53.209	0	0	0	99.72
D9103-1-2	0.020	0.023	0.013	0	47.319	0.055	0	0.041	53.222	0	0.033	0.012	100.74
D9103-1-3	0	0	0.043	0.017	46.798	0.039	0.015	0.021	52.413	0.008	0	0.023	99.38
D9103-1-4	0.025	0	0.036	0	46.276	0	0.01	0.01	52.927	0.006	0.001	0.008	99.30
D9103-1-5	0	0.05	0.025	0	46.787	0	0	0.007	52.924	0.012	0	0	99.81
D9103-1-6	0.064	0	0.033	0	46.138	0.003	0.051	0	52.972	0.002	0	0.017	99.28
D9103-1-7	0.023	0	0.054	0	46.783	0.006	0	0.01	52.736	0	0.008	0	99.62
D9103-1-8	0.050	0	0.028	0.026	46.716	0	0.008	0	52.706	0	0	0.030	99.56
D9103-1-9	0.019	0	0.007	0	47.060	0.021	0.017	0	52.850	0	0.007	0.052	100.03
D9103-1-10	0	0.021	0.023	0.025	47.273	0.015	0.009	0.004	53.136	0	0	0	100.51
D9103-1-11	0.008	0.014	0.052	0	46.142	0	0	0.029	52.833	0.021	0	0.002	99.10
D9103-1-12	0.021	0	0.065	0	46.896	0	0	0	53.044	0	0	0.035	100.06
D9103-1-13	0.028	0.046	0.004	0.019	46.593	0	0	0.014	53.285	0	0	0	99.99
D9101-1-1	0.03	0.012	0.109	0	46.689	0.082	0	0.011	52.122	0.002	0.004	0	99.06
D9101-1-2	0.038	0	0.063	0	46.490	0.029	0.001	0	52.905	0	0	0.046	99.57
D9101-1-4	0.030	0	0.084	0.014	45.643	0	0	0	52.304	0.002	0	0	98.08
D9101-1-5	0	0	0.058	0	46.180	0	0.019	0.057	52.601	0	0	0.063	98.98
D9101-1-3	0.048	0	0.105	0.001	45.764	0	0	0.016	52.341	0.004	0	0	98.28
D9101-1-6	0.026	0	0.058	0	45.881	0.027	0.007	0	53.118	0	0.016	0.062	99.20
D9101-1-7	0.045	0.022	0.084	0	45.916	0	0.025	0	51.937	0	0.019	0.025	98.07
D9101-1-8	0	0	0.065	0	46.141	0.014	0.038	0	52.312	0.011	0.013	0.003	98.60
D9033-1-1	0.017	0.143	0.112	0	45.821	0	0.015	0.017	52.987	0	0.014	0.021	99.15
D9033-1-2	0.045	0.023	0.031	0.027	45.883	0	0	0.012	53.518	0	0	0.016	99.56
D9033-1-4	0.043	0	0.064	0.022	45.231	0.077	0.068	0.058	53.019	0.013	0.010	0	98.61
D9033-1-3	0.016	0	0.102	0	45.901	0.057	0.075	0	52.903	0	0.006	0.002	99.06
D9033-1-6	0.023	0	0.022	0	45.897	0.168	0.02	0.009	53.418	0	0.002	0.033	99.60
D9033-1-7	0.006	0.021	0.047	0	45.753	0.119	0.312	0	53.338	0.016	0.002	0	99.61
D9033-1-5	0.055	0.028	0.067	0	45.730	0.019	0.007	0.056	53.254	0	0	0.008	99.22

样品号	V	Cr	Co	Ni	Cu	Zn	Ag	Au	As	Sb	Hg	Pb
D9001-1-1	—	4.945	2.298	—	13.160	2.312	—	—	27.060	0.614	—	0.711
D9001-1-2	0.125	10.710	4.023	26.230	1.026	4.230	0.085	—	26.340	0.297	—	2.613
D9001-1-3	2.044	5.531	33.610	357.200	15.700	3.945	0.043	0.005	54.570	1.054	—	18.290
D9001-1-4	0.221	1.976	0.186	2.717	1.097	4.033	0.041	0.013	9.248	0.075	—	0.062
D9001-1-5	40.410	128.700	193.400	69.35	6.623	14.230	0.167	—	26.710	4.521	—	102.100
D9001-1-6	0.620	1.321	1.291	4.997	2.395	5.526	—	0.020	154.100	0.058	—	0.924
D9001-1-7	0.705	0.565	0.537	9.501	6.873	3.652	0.076	—	17.800	0.135	—	0.378
D9001-1-8	—	0.864	0.136	—	0.418	5.539	0.012	0.003	11.990	0.384	—	0.105
D9001-1-9	0.094	1.465	0.308	4.938	0.711	5.520	—	0.013	7.324	0.358	—	0.648
D9001-1-10	0.022	1.663	0.193	5.951	0.823	6.895	—	0.012	7.416	0.341	—	0.547
D9001-1-11	2.010	5.713	6.406	9.443	2.458	7.635	—	0.041	23.240	0.142	—	7.141
D9001-1-12	0.682	2.552	5.064	87.310	6.336	10.290	0.116	0.118	82.800	0.056	—	5.531
D9001-1-13	2.006	38.770	19.770	15.270	34.890	8.118	0.133	—	12.650	—	—	4.731
D9001-1-14	1.203	5.145	0.633	3.058	7.733	5.407	0.069	0.016	17.970	0.105	—	0.331
D9001-1-15	0.670	7.071	4.561	0.478	7.446	5.999	0.012	0.010	19.350	0.043	—	0.876
D9103-1-1	0.134	1.143	0.282	6.687	—	5.150	0.025	—	11.700	0.331	1.337	0.608
D9103-1-2	4.297	1.569	1.345	19.840	0.405	8.426	0.176	0.007	64.380	0.096	0.178	0.921
D9103-1-3	2.230	11.080	0.631	28.230	12.640	17.490	—	0.013	53.840	0.324	1.013	6.600
D9103-1-4	2.466	4.304	3.275	33.520	1.243	8.042	—	0.009	85.650	0.177	0.872	7.070
D9103-1-5	2.231	15.650	18.550	264.000	11.420	8.147	0.025	0.007	20.810	0.197	0.651	15.200
D9103-1-6	0.304	2.618	0.795	19.910	7.749	8.731	0.199	—	38.350	—	0.605	1.264
D9103-1-7	0.058	2.796	0.624	9.196	1.988	9.599	0.090	0.005	15.990	0.170	0.272	0.537
D9103-1-8	0.291	8.119	0.113	4.042	2.487	9.652	0.076	—	22.130	0.162	0.892	0.547
D9103-1-9	0.499	8.309	0.151	2.365	4.066	12.050	0.027	—	19.160	0.930	4.447	0.757
D9103-1-10	0.657	5.514	0.441	0.863	3.776	10.330	0.193	0.008	30.750	0.329	1.543	0.341
D9103-1-11	0.209	9.727	2.601	4.791	5.799	11.620	—	0.016	8.338	0.122	0.699	0.267
D9103-1-12	—	4.379	6.068	—	4.284	9.310	0.210	—	9.093	0.505	0.970	1.899
D9103-1-13	0.992	4.260	10.330	17.140	3.346	9.813	—	0.015	19.420	0.161	0.686	4.388
D9103-1-14	0.188	1.106	5.404	97.440	5.243	10.990	—	—	1.943	0.083	0.450	1.322
D9103-1-15	0.147	1.989	6.159	82.830	5.140	10.280	0.072	—	1.134	0.004	0.254	2.106
D9103-1-16	0.706	17.820	8.957	207.600	9.487	14.010	—	0.014	13.760	0.587	0.987	15.480
D9103-1-17	0.415	4.794	4.190	63.650	4.382	9.631	0.144	—	29.810	0.330	0.564	4.961
D9103-1-18	8.039	214.300	46.840	79.980	7.802	13.600	—	0.008	8.767	0.498	0.959	15.090
D9033-1-1	0.186	3.209	508.600	1133.000	589.000	22.870	5.467	0.216	101.300	19.020	0.695	571.900
D9033-1-2	0.152	2.630	499.800	1144.000	586.200	20.480	4.324	0.197	93.350	17.120	0.459	555.900
D9033-1-3	0.142	30.740	462.700	1018.000	542.700	17.160	4.724	0.327	84.560	15.750	0.817	527.500
D9033-1-4	2.679	2.222	546.40	1266.000	603.800	22.180	4.824	0.311	106.200	18.330	0.638	560.400
D9033-1-5	0.013	1.016	490.400	1025.000	569.500	22.940	3.970	0.163	88.420	16.830	0.676	502.300
D9033-1-6	0.200	42.500	533.800	1112.000	573.700	20.930	3.890	0.172	89.230	15.930	0.421	548.700
D9033-1-7	0.275	19.780	485.800	1119.000	539.300	21.560	3.963	0.145	88.290	15.280	0.455	522.100
D9033-1-8	0.170	6.896	506.800	1062.000	568.200	20.750	4.976	0.142	87.870	14.940	0.778	584.700