辽宁红透山铜锌矿床含矿岩系地球化学特征及找矿指示

doi:10.19657/j.geoscience.1000-8527.2022.01.32

摘要/Abstract

摘要：

红透山铜锌矿床是产于太古宙绿岩带中的块状硫化物矿床。含矿岩系为角闪斜长片麻岩、角闪斜长(石英)片麻岩、黑云斜长片麻岩、黑云斜长(石英)片麻岩、黑云石英片麻岩。通过对变质岩原岩进行恢复及构造环境判别,得出变质岩原岩均为火山岩,其中角闪斜长片麻岩与角闪斜长(石英)片麻岩的原岩为基性火山岩,黑云斜长片麻岩、黑云斜长(石英)片麻岩与黑云石英片麻岩的原岩为中酸性火山岩,岩性组合为双峰式火山喷发的产物。为探讨含矿岩系地球化学参数作为找矿指标的可能性,对含矿岩系的主量元素、稀土及微量元素进行分析,发现红透山铜锌矿床角闪斜长(石英)片麻岩的Cu元素含量(290.82 μg/g)、SiO₂含量(57.24%)、稀土元素总量(53.78 μg/g)、LREE/HREE比值(4.29)及黑云斜长(石英)片麻岩和黑云石英片麻岩的Cu元素含量(88.09 μg/g)、SiO₂含量(70.50%)可作为重要的找矿指标。

关键词: 红透山铜锌矿床, 主量、微量、稀土元素, 原岩恢复, 构造环境, 找矿指标

Abstract:

The Hongtoushan copper-zinc deposit, located in the Archean greenstone belt, is a massive sulfide deposit. The ore-bearing rocks are composed of hornblende plagiogneiss, hornblende (quartz) plagiogneiss, biotite plagiogneiss, biotite (quartz) plagiogneiss, and biotite quartz gneiss. It suggests that protoliths of these metamorphic rocks are volcanic rocks based on protolith restoration and discrimination of tectonic environment. Among them, protoliths of the hornblende plagiogneiss and hornblende (quartz) plagiogneiss are basic volcanic rocks, whereas protoliths of the biotite plagiogneiss, biotite (quartz) plagiogneiss, and biotite quartz gneiss are intermediate-acid volcanic rocks, together they were the products of the bimodal volcanics. In order to best reveal the possibility of geochemical parameters of the ore-bearing rocks as prospecting indicators, based on the major elements, rare earth elements and trace elements of the ore-bearing rocks, the authors found that the Cu (290.82 μg/g), SiO₂ (57.24%), total rare earth elements (ΣREE) concentration (53.78 μg/g), and LREE/HREE ratio (4.29) of the hornblende (quartz) plagiogneiss, while the Cu (88.09 μg/g ) and SiO₂ (70.50%) concentrations of the biotite (quartz) plagiogneiss and biotite quartz gneiss can be used as important prospecting indicators for the Hongtoushan copper-zinc deposit.

Key words: the Hongtoushan copper-zinc deposit, major, trace and rare earth elements, protolith restoration, tectonic environment, prospecting indicator

中图分类号:

P618.4

吴小雷, 常晋阳, 曾南石, 徐文杰, 陶明荣, 赵刚, 韩建. 辽宁红透山铜锌矿床含矿岩系地球化学特征及找矿指示[J]. 现代地质, 2022, 36(01): 362-377.

WU Xiaolei, CHANG Jinyang, ZENG Nanshi, XU Wenjie, TAO Mingrong, ZHAO Gang, HAN Jian. Geochemical Characteristics and Prospecting Indication of Ore-bearing Rocks in the Hongtoushan Copper-zinc Deposit, Liaoning[J]. Geoscience, 2022, 36(01): 362-377.

图/表 17

参考文献 47

[1]	陈路, 刘连登. 中国红透山太古宙块状硫化物矿床集中区地质[J]. 长春地质学院学报, 1982(S1):117-138.
[2]	顾连兴, 汤晓茜, 吴昌志, 等. 辽宁红透山块状硫化物矿床矿石糜棱岩铜-金富集机制[J]. 地学前缘, 2004, 11(2):339-351.
[3]	顾连兴, 汤晓茜, 郑远川, 等. 辽宁红透山铜锌块状硫化物矿床的变质变形和成矿组分再活化[J]. 岩石学报, 2004, 20(4):923-934.
[4]	ZHAI M G, GUO J H, LIU W J. Neoarchean to Paleoproterozoic continental evolution and tectonic history of the North China Craton: a review[J]. Journal of Asian Earth Sciences, 2005, 24(5):547-561. DOI URL
[5]	GU L X, ZHENG Y C, TANG X Q, et al. Copper, gold and silver enrichment in ore mylonites within massive sulphide orebodies at Hongtoushan VHMS deposit, N.E.China[J]. Ore Geology Reviews, 2007, 30(1):1-29. DOI URL
[6]	张增杰, 邢树文, 马玉波, 等. 辽宁红透山铜锌矿围岩黑云斜长角闪岩锆石U-Pb定年及其块状硫化物指示意义[J]. 吉林大学学报(地球科学版), 2013, 43(4): 1159-1168.
[7]	张雅静. 辽宁红透山铜锌矿矿床地质特征及成矿模式研究[D]. 长春: 吉林大学, 2010: 1-75.
[8]	高桂荣. 红透山铜锌矿床地质特征及成矿模式浅析[J]. 世界有色金属, 2018(24):84-85.
[9]	刘军, 王静纯. 辽宁红透山铜锌矿床矿化空间分布规律研究[J]. 矿物学报, 2013, 33(S2):938-939.
[10]	郑远川, 顾连兴, 汤晓茜, 等. 辽宁红透山块状硫化物矿床高级变质下盘蚀变带研究[J]. 岩石学报, 2008, 24(8): 1928-1936.
[11]	郑远川, 顾连兴, 汤晓茜, 等. 辽宁红透山块状硫化物矿床蚀变带元素迁移特征及定量计算[J]. 矿床地质, 2010, 29(5):785-809.
[12]	钱烨, 孙丰月, 李碧乐, 等. 变质重结晶锆石微量元素地球化学与U-Pb年代学: 以辽宁红透山铜锌矿床赋矿片麻岩为例[J]. 中南大学学报(自然科学版), 2013, 44(4): 1500-1509.
[13]	张秋生, 李守义, 刘连登. 中国早前寒武纪地质及成矿作用[M]. 长春: 吉林人民出版社, 1984: 1-536.
[14]	邓功全. 辽北-吉南太古宙地体有色金属矿床[M]// 芮宗瑶, 施林道, 方如恒, 等. 华北陆块北缘及邻区有色金属矿床地质. 北京: 地质出版社, 1994: 25-53.
[15]	李俊健, 沈保丰, 李双保, 等. 清原-夹皮沟绿岩带地质及金的成矿作用[M]. 天津: 天津科学技术出版社, 1995:1-132.
[16]	刘连登, 朱永正, 戴仕炳. 金矿与韧性剪切带及叠加构造[M]// 张贻侠, 刘连登. 中国前寒武纪矿床和构造. 北京: 地震出版社, 1994: 39-77.
[17]	顾连兴, 肖新建, 倪培, 等. 辽宁红透山块状硫化物矿床中沉积磁黄铁矿的变质和流体作用[J]. 地质论评, 2001, 47(2): 188-193.
[18]	LIU Y S, ZONG K Q, KELEMEN P B, et al. Geochemistry and magmatic history of eclogites and ultramafic rocks from the Chinese continental scientific drill hole: Subduction and ultrahigh-pressure metamorphism of lower crustal cumulates[J]. Chemical Geology, 2008, 247(1/2):133-153. DOI URL
[19]	TAYLOR S R, MCLENNAN S M. The Continental Crust: Its Composition and Evolution[M]. Oxford: Blackwell Scientific Publications, 1985:1-39.
[20]	SIMONEN A J P. Stratigraphy and sedimentation of the Sveocofennidic, Early Archean supracrustal rocks in southwestern Finland[J]. Bulletin de la Commission Geologique de Finlande, 1953, 160: 1-64.
[21]	TARNEY J. Geochemistry of Archean High Grade Gnesses, with Implications as to Origin and Evolution of the Precambrian Crust[M]. London: Wiley, 1976: 405-417.
[22]	СЕМЕНЕНКО H П.Метаморфизм подвижных зон[M]. Киев: Наука, 1966: 68-123.
[23]	陈磊. 马来半岛Ulu Sokor地区Rixen矿床变质岩原岩恢复[D]. 长沙: 中南大学, 2014: 1-59.
[24]	IRVINE T N, BARAGAR W. A guide to the chemical classification of the common volcanic rocks[J]. Canadian Journal of Earth Science, 1971, 8(5): 528-548.
[25]	MULLEN E D. MnO/TiO₂/P₂O₅: a minor element discriminant for basaltic rocks of oceanic environments and its implications for petrogenesis[J]. Earth and Planetary Science Letters, 1983, 62(1): 53-62. DOI URL
[26]	王仁民, 贺高品, 陈珍珍, 等. 变质岩原岩图解判别法[M]. 北京: 地质出版社, 1987:1-165.
[27]	PEARCE J A, CANN J R. Tectonic setting of basic volcanic rocks determined using trace element analyses[J]. Earth and Planetary Science Letters, 1973, 19(2):290-300. DOI URL
[28]	陈德潜. 实用稀土元素地球化学[M]. 北京: 冶金工业出版社, 1990: 144-158.
[29]	赵振华. 微量元素地球化学原理[M]. 北京: 科学出版社, 1997: 200-206.
[30]	赵振华. 关于岩石微量元素构造环境判别图解使用的有关问题[J]. 大地构造与成矿学, 2007, 31(1): 92-103.
[31]	韩吟文, 马振东. 地球化学[M]. 北京: 地质出版社, 2002: 189-212.
[32]	翟明国, WINDLEY B F, SILLS J D, 等. 鞍本太古代条带状铁建造(BIF)的稀土及微量元素特征[J]. 地球化学, 1989(3):241-250.
[33]	武平. 物质成分对岛弧拉斑玄武岩成因的指示意义[J]. 新疆有色金属, 2005, 28(4):12-13.
[34]	PEARCE J A, HARRIS B W, TINDLE A G. Trace element discrimination diagrams for the tectonic interpretations of granitic rocks[J]. Journal of Petrology, 1984, 25(4): 956-983. DOI URL
[35]	GEIST D, HOWARD K A, LARSON P. The generation of ocea-nic rhyolites by crystal fractionation: the basalt-rhyolite association at Volcan Alcedo, Galapagos Archipelago[J]. Journal of Petrology, 1995, 36(4): 965-982. DOI URL
[36]	DUNCAN A R, ERLANK A J, MARSH J S. Regional geoche-mistry of the Karoo igneous province[M]//ERLANK A J. Petrogenesis of the Volcanic Rocks of the Karoo Province. Johannesburg: Geological Society of South Africa, Special Publication, 1984, 13: 355-388.
[37]	GARLAND F, HAWKESWORTH C J, MANTOVANI M. Description and petrogenesis of the Paraná rhyolites, southern Brazil[J]. Journal of Petrology, 1995, 36(5): 1193-1227. DOI URL
[38]	PIN C, MARINI F. Early Ordovician continental break-up in Variscan Europe:Nd-Sr isotope and trace element evidence from bimodal igneous associations of the Southern Massif Central, France[J]. Lithos, 1993, 29(3/4): 177-196. DOI URL
[39]	BROUXEL M, LAPIERRE H, MICHARD A, et al. The deep layers of a Paleozoic arc: geochemistry of the Copley-Balaklala series, northern California[J]. Earth and Planetary Science Letters, 1987, 85(4):386-400. DOI URL
[40]	HOCHSTAEDTER A G, GILL J B, KUSAKABE M, et al. Volcanism in the Sumisu Rift, I. Major element, volatile, and stable isotope geochemistry[J]. Earth and Planetary Science Letters, 1990, 100(1/2/3):179-194. DOI URL
[41]	HOCHSTAEDTER A G, GILL J B, MORRIS J D. Volcanism in the Sumisu Rift, II. Subduction and non-subduction related components[J]. Earth and Planetary Science Letters, 1990, 100(1/2/3): 195-209. DOI URL
[42]	FREY F A, GERLACH D C, HICKEY R L, et al. Petrogenesis of the Laguna del Maule volcanic complex, Chile (36°S)[J]. Contributions to Mineralogy and Petrology, 1984, 88(1):133-149. DOI URL
[43]	PIN C, PAQUETTE J L. A mantle-derived bimodal suite in the Hercynian Belt: Nd isotope and trace element evidence for a subduction-related rift origin of the Late Devonian Brévenne metavolcanics, Massif Central (France)[J]. Contributions to Mineralogy and Petrology, 1997, 129(2/3):222-238. DOI URL
[44]	COULON C, MALUSKI H, BOLLINGER C, et al. Mesozoic and Cenozoic volcanic rocks from central and southern Tibet: ³⁹Ar- ⁴⁰Ar dating, petrological characteristics and geodynamical significance[J]. Earth and Planetary Science Letters, 1986, 79(3/4):281-302. DOI URL
[45]	WANG J S, CHANG J Y, LI C, et al. Significance of calcite trace elements contents and C-O isotopic compositions for ore-forming fluids and gold prospecting in the Zhesang Carlin-like gold deposit of Southeastern Yunnan, China[J]. Minerals, 2020, 10(4): 338-361. DOI URL
[46]	王加昇, 韩振春, 李超, 等. 黔西南板其卡林型金矿床方解石REE、Fe、Mn元素特征及其对找矿的指示意义[J]. 大地构造与成矿学, 2018, 42(3):494-504.
[47]	闫俊, 夏勇, 谭亲平, 等. 黔西南赖子山背斜东南缘卡林型金矿地质地球化学特征与成矿预测[J]. 黄金科学技术, 2015, 23(2): 28-37.

样品编号	样品类型	样品名称	采样位置
H2	A	角闪斜长片麻岩	13 m中段14#穿脉
H7			-527 m中段45#穿脉
H8			-647 m中段44#穿脉
H9			-767 m中段24#穿脉
H14			-767 m中段42#穿脉
H13	B	角闪斜长(石英)片麻岩	-767 m中段24#穿脉
H18	C	黑云斜长片麻岩	-767 m中段24#穿脉
H3	D	黑云斜长(石英)片麻岩	13 m中段14#穿脉
H4	D	黑云斜长(石英)片麻岩	13 m中段14#穿脉
H15	E	黑云石英片麻岩	-767 m中段42#穿脉
H16	E	黑云石英片麻岩	-767 m中段42#穿脉

样品编号	样品类型	样品名称	采样位置
H2	A	角闪斜长片麻岩	13 m中段14#穿脉
H7			-527 m中段45#穿脉
H8			-647 m中段44#穿脉
H9			-767 m中段24#穿脉
H14			-767 m中段42#穿脉
H13	B	角闪斜长(石英)片麻岩	-767 m中段24#穿脉
H18	C	黑云斜长片麻岩	-767 m中段24#穿脉
H3	D	黑云斜长(石英)片麻岩	13 m中段14#穿脉
H4	D	黑云斜长(石英)片麻岩	13 m中段14#穿脉
H15	E	黑云石英片麻岩	-767 m中段42#穿脉
H16	E	黑云石英片麻岩	-767 m中段42#穿脉

样号	样品类型	SiO₂	TiO₂	Al₂O₃	Fe₂O₃	MnO	MgO	CaO	Na₂O	K₂O	P₂O₅	烧失量	总和	资料来源
H2	A	55.01	0.54	16.91	8.78	0.16	4.89	9.38	3.42	0.45	0.12	0.78	100.42	本文
H7		54.00	0.68	15.82	11.22	0.15	6.72	6.61	3.27	0.51	0.17	1.01	100.15
H8		51.93	0.60	16.52	9.50	0.17	6.01	8.47	3.93	1.17	0.14	1.94	100.40
H9		56.15	0.51	16.07	8.71	0.16	6.09	7.57	3.75	0.70	0.12	0.71	100.53
H14		48.90	0.35	17.44	10.06	0.18	8.20	10.62	2.34	0.64	0.07	1.25	100.05
H13	B	59.19	0.45	10.75	11.14	0.34	6.65	7.08	0.81	0.65	0.06	2.35	99.47	本文郑远川等^[11]
HZ-3	B	63.39	0.79	14.77	11.32	0.16	4.28	1.95	3.66	0.06	0.15	0.03	100.56	本文郑远川等^[11]
H18	C	64.88	0.38	12.20	5.72	0.34	6.65	7.08	0.81	0.65	0.06	0.82	95.32	本文郑远川等^[11]
HZ-260	C	69.19	0.43	13.39	5.18	0.04	2.34	3.21	3.11	1.91	0.15	0.57	100.03	本文郑远川等^[11]
H3	D	74.63	0.23	11.63	3.51	0.08	0.61	1.84	2.97	3.12	0.03	1.73	100.36	本文
H4	D	73.28	0.19	13.11	2.93	0.08	1.03	2.70	3.65	1.22	0.04	1.92	100.15	本文
H15	E	77.44	0.17	9.81	3.37	0.08	0.59	1.98	1.36	2.60	0.03	2.36	99.81	本文
H16	E	80.04	0.09	8.26	4.19	0.09	0.55	2.32	2.45	0.30	0.01	1.88	100.16	本文

样号	样品类型	SiO₂	TiO₂	Al₂O₃	Fe₂O₃	MnO	MgO	CaO	Na₂O	K₂O	P₂O₅	烧失量	总和	资料来源
H2	A	55.01	0.54	16.91	8.78	0.16	4.89	9.38	3.42	0.45	0.12	0.78	100.42	本文
H7		54.00	0.68	15.82	11.22	0.15	6.72	6.61	3.27	0.51	0.17	1.01	100.15
H8		51.93	0.60	16.52	9.50	0.17	6.01	8.47	3.93	1.17	0.14	1.94	100.40
H9		56.15	0.51	16.07	8.71	0.16	6.09	7.57	3.75	0.70	0.12	0.71	100.53
H14		48.90	0.35	17.44	10.06	0.18	8.20	10.62	2.34	0.64	0.07	1.25	100.05
H13	B	59.19	0.45	10.75	11.14	0.34	6.65	7.08	0.81	0.65	0.06	2.35	99.47	本文郑远川等^[11]
HZ-3	B	63.39	0.79	14.77	11.32	0.16	4.28	1.95	3.66	0.06	0.15	0.03	100.56	本文郑远川等^[11]
H18	C	64.88	0.38	12.20	5.72	0.34	6.65	7.08	0.81	0.65	0.06	0.82	95.32	本文郑远川等^[11]
HZ-260	C	69.19	0.43	13.39	5.18	0.04	2.34	3.21	3.11	1.91	0.15	0.57	100.03	本文郑远川等^[11]
H3	D	74.63	0.23	11.63	3.51	0.08	0.61	1.84	2.97	3.12	0.03	1.73	100.36	本文
H4	D	73.28	0.19	13.11	2.93	0.08	1.03	2.70	3.65	1.22	0.04	1.92	100.15	本文
H15	E	77.44	0.17	9.81	3.37	0.08	0.59	1.98	1.36	2.60	0.03	2.36	99.81	本文
H16	E	80.04	0.09	8.26	4.19	0.09	0.55	2.32	2.45	0.30	0.01	1.88	100.16	本文

元素含量及特征值	样品号
	H2	H7	H8	H9		H14	H13	HZ-3	H18	HZ-260	H3	H4	H15	H16
	A						B		C		D		E
La	4.61	5.40	5.97	5.09	2.11		14.20	11.37	7.75	24.10	19.09	21.34	23.05	23.36
Ce	11.11	13.42	15.42	13.40	5.68		30.84	22.69	18.13	58.57	40.43	45.73	48.16	62.85
Pr	1.47	1.79	2.08	1.73	0.82		3.69	3.26	2.26	5.96	5.21	4.85	6.03	6.53
Nd	6.16	7.81	8.30	7.41	3.72		14.05	13.26	9.74	20.73	19.66	16.95	21.52	22.91
Sm	1.59	2.28	1.99	1.85	1.05		3.18	2.87	2.48	3.41	4.02	2.89	4.92	5.35
Eu	0.60	0.68	0.75	0.67	0.49		1.12	1.03	0.69	1.03	0.81	0.70	0.58	0.96
Gd	1.84	2.58	2.23	2.20	1.17		3.27	3.04	3.04	3.26	3.39	2.06	4.85	4.71
Tb	0.29	0.43	0.34	0.33	0.20		0.48	0.54	0.47	0.49	0.45	0.27	0.70	0.77
Dy	1.90	2.97	2.12	2.24	1.33		2.94	3.15	3.38	2.57	2.21	1.17	3.79	4.65
Ho	0.39	0.59	0.46	0.47	0.30		0.60	0.74	0.70	0.51	0.40	0.21	0.73	0.90
Er	1.24	1.87	1.40	1.38	0.89		1.90	1.95	2.07	1.40	1.12	0.60	1.92	2.59
Tm	0.16	0.26	0.19	0.21	0.14		0.26	0.30	0.32	0.21	0.16	0.08	0.26	0.38
Yb	1.22	1.85	1.28	1.32	1.05		1.74	1.91	2.19	1.25	1.03	0.61	1.64	2.59
Lu	0.18	0.28	0.22	0.22	0.16		0.26	0.32	0.34	0.21	0.19	0.11	0.26	0.33
Y	10.49	15.77	11.04	11.46	6.86		16.53	17.85	18.48	14.14	9.75	5.30	17.10	21.32
ΣREE	32.76	42.21	42.75	38.52	19.11		78.53	66.43	53.56	123.70	98.17	97.57	118.41	138.88
LREE	25.54	31.38	34.51	30.15	13.87		67.08	54.48	41.05	113.80	89.22	92.46	104.26	121.96
HREE	7.22	10.83	8.24	8.37	5.24		11.45	11.95	12.51	9.90	8.95	5.11	14.15	16.92
LREE/HREE	3.54	2.90	4.19	3.60	2.65		5.86	4.56	3.28	11.49	9.97	18.09	7.37	7.21
(La/Yb)_N	2.55	1.97	3.15	2.61	1.36		5.51	4.02	2.39	13.03	12.52	23.64	9.50	6.09
δEu	1.07	0.85	1.08	1.01	1.35		1.05	1.06	0.77	0.93	0.65	0.84	0.36	0.57
δCe	1.00	1.01	1.02	1.06	1.01		0.98	0.87	1.01	1.12	0.94	1.02	0.94	1.18