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现代地质 ›› 2007, Vol. 21 ›› Issue (Suppl): 21-25.

• 地质学 • 上一篇    下一篇

海洋铁锰沉积物中稀土元素的地球化学特征

李江山,方念乔,张振国,李慧勇,马洪   

  1. 中国地质大学 海洋学院,北京100083
  • 收稿日期:2006-11-05 修回日期:2006-12-10 出版日期:2007-08-20 发布日期:2007-08-20
  • 作者简介:李江山,男,博士研究生,1969年出生,海洋地质专业,主要从事海洋地质方面的研究工作。
  • 基金资助:

    中国大洋协会“十五”课题(DY105-01-04-14)

Rare Earth Elements Geochemistry of Marine Ferromanganese Deposits

LI Jiang-shan, FANG Nian-qiao, ZHANG Zhen-guo, LI Hui-yong, MA Hong   

  1. School of Marine Sciences, China University of Geosciences, Beijing100083, China
  • Received:2006-11-05 Revised:2006-12-10 Online:2007-08-20 Published:2007-08-20

摘要:

海洋铁锰沉积物根据成因的不同可分为水成、成岩和热液3种类型。本次研究利用ICP-MS方法分析了太平洋及印度洋的水成型和成岩型铁锰沉积物中的稀土元素,并与具有代表性的热液铁锰沉积物中稀土元素进行比较,以研究稀土元素在这3种海洋铁锰沉积物的特征及其与生长环境的关系。三者之间具有明显不同的稀土元素地球化学特征,指示:水成型铁锰沉积物生长于相对稳定和相似的氧化环境;成岩型铁锰沉积物形成于亚氧化至还原环境,但在一些时段部分受到水成作用的影响;而热液铁锰结壳则具有热液和海水的混合来源,并且不同地区的热液铁锰沉积物生长环境差异较大。

关键词: 海洋, 铁锰沉积物, 稀土元素, 地球化学

Abstract:

According to the different genesis, marine ferromanganese deposits can be classified into hydrogenetic ferromanganese deposits, diagenetic ferromanganese deposits and hydrothermal ferromanganese deposits. REEs in hydrogenetic and diagenetic ferromanganese deposits from Pacific and Indian Ocean were analyzed by ICP-MS, and were compared with REEs in the representative hydrothermal ferromanganese deposits, to understand the characteristics of REEs and the internal relationship between REEs and growth environment of hydrogenetic ferromanganese deposits, diagenetic ferromanganese deposits and hydrothermal ferromanganese deposits. There are significantly differences in rare earth elements characteristics among the three types. These indicate that hydrogenetic ferromanganese deposits grow in relative stability and similar oxidizing environment; diagenetic ferromanganese deposits form in sub-oxidizing to reducing environment, but at some periods, parts of them may be affected by hydrogenesis; whereas hydrothermal ferromanganese deposits come from hydrothermal fluid and seawater, and there are great differences of growth environment among hydrothermal ferromanganese deposits in different areas.

Key words: marine, ferromanganese deposits, rare earth elements, geochemistry

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