山西西铭煤矿煤中稀土元素地球化学特征及指示意义

doi:10.19657/j.geoscience.1000-8527.2020.092

摘要/Abstract

摘要：

采用电感耦合等离子体质谱(ICP-MS)及X射线荧光光谱(XRF)等方法,分析山西西铭煤矿2号、3号、8 号和9号煤中稀土元素的含量特征和赋存状态,并根据稀土元素Ce、Eu、Gd、Y和常量元素Al₂O₃/TiO₂的异常揭示其成煤环境及物质来源。研究结果显示:(1)西铭煤矿煤中稀土元素含量与世界煤值和美国煤值基本相等,但低于中国煤中稀土元素含量的平均值;稀土元素以中-重稀土富集型为主,其次是轻稀土富集型和轻-中稀土富集型。(2)西铭煤矿成煤环境总体上以弱还原性为主,且受酸性沼泽水环境影响。(3)煤中稀土元素的物质来源主要为陆源碎屑物质,判断其沉积源岩为酸性或中-酸性岩浆岩。

关键词: 稀土元素, 地球化学特征, 成煤环境, 西铭煤矿

Abstract:

Concentration characteristics and state of occurrence of rare earth elements (REEs) in No.2,No.3, No.8 and No.9 coals of the Ximing Mine in Shanxi were analyzed by inductively coupled plasma mass spectrometry (ICP-MS) and X-ray fluorescence spectrometry (XRF). According to the anomalies of Ce, Eu, Gd, La, Y and TiO₂/Al₂O₃, we revealed the formation environment of coal and the possible REE sources. The results show that: (1) The REE contents of the Ximing coal is very similar to the global average value and the value of the United States coal, but lower than the average value of the Chinese coal. The REEs are mainly MREE-HREE-enriched, followed by LREE and LREE-MREE-enriched. (2) The coal-forming environment is mainly weakly reducing and affected by acidic marsh water environment. (3) The REEs source may have been mainly terrigenous detrital materials, and the sedimentary source rocks are determined to be felsic or intermediate-felsic magmatic rocks.

Key words: rare earth element, geochemical characteristic, coal-forming environment, Ximing coal mine

中图分类号:

P618.11
P595

王珍珍, 李进孝, 张珂, 郭文牧, 张绍韡, 肖林. 山西西铭煤矿煤中稀土元素地球化学特征及指示意义[J]. 现代地质, 2021, 35(04): 1009-1017.

WANG Zhenzhen, LI Jinxiao, ZHANG Ke, GUO Wenmu, ZHANG Shaowei, XIAO Lin. Geochemical Characteristics of Rare Earth Elements and the Indicative Significance in the Ximing Coal Mine, Shanxi Province[J]. Geoscience, 2021, 35(04): 1009-1017.

图/表 8

参考文献 40

[1]	RBUZOV S I, CHEKRYZHOV I Y, FINKELMAN R B, et al. Comments on the geochemistry of rare-earth elements (La,Ce,Sm,Eu,Tb,Yb,Lu) with examples from coals of north Asia (Siberia, Russian Far East, North China, Mongolia and Kazakhstan)[J]. International Journal of Coal Geology, 2019, 206:106-120. DOI URL
[2]	WANG W F, QIN Y, SANG S X, et al. Geochemistry of rare earth elements in a marine influenced coal and its organic solvent extracts from the Antaibao mining district, Shanxi, China[J]. International Journal of Coal Geology, 2008, 76(4):309-317. DOI URL
[3]	吴盾, 孙若愚, 刘桂建. 淮南朱集井田二叠纪煤中稀土元素地球化学特征及其地质解释[J]. 地质学报, 2013, 87(8):1158-1163.
[4]	SEREDIN V V, DAI S F. Coal deposits as potential alternative sources for lanthanides and yttrium[J]. International Journal of Coal Geology, 2012, 94(5):67-93. DOI URL
[5]	蔡观强, 邱燕, 彭学超, 等. 南海西南海域表层沉积物中微量元素Ba的地球化学特征[J]. 现代地质, 2010, 24(3):560-569.
[6]	蒋苏扬, 黄文辉, 张永生. 鄂尔多斯盆地西缘中奥陶统地球化学特征及古环境意义[J]. 现代地质, 2020, 34(3):545-553.
[7]	ZHAO C L, LIU B J, XIAO L, et al. Significant enrichment of Ga, Rb, Cs, REEs and Y in the Jurassic No.6 coal in the Iqe Coalfield, northern Qaidam Basin, China—A Hidden Gem[J]. Ore geology Reviews, 2017, 83:1-13. DOI URL
[8]	XU J, SUN Y Z, KALKREUTH W. Characteristics of trace elements of the No.6 Coal in the Guanbanwusu Mine, Junger Coalfield, Inner Mongolia[J]. Energy Exploration & Exploitation, 2011, 29(6):827-842.
[9]	刘贝, 黄文辉, 敖卫华, 等. 沁水盆地晚古生代煤中稀土元素地球化学特征[J]. 煤炭学报, 2015, 40(12):2916-2926.
[10]	SUN Y Z, ZHAO C L, QIN S J, et al. Occurrence of some valuable elements in the unique ‘high-aluminium coals’ from the Jungar coalfield,China[J]. Ore Geology Reviews, 2016, 72:659-668. DOI URL
[11]	肖林, 张佳为, 周建飞, 等. 青海石灰沟矿区克鲁克组煤中稀土元素地球化学特征[J]. 煤炭学报, 2018, 43(增):505-512.
[12]	邹雨, 刘东娜, 刘海燕. 大同煤田太原组5号煤层化学元素赋存特征[J]. 煤炭科学技术, 2016, 44(增):167-172.
[13]	QIN S J, GAO K, SUN Y Z, et al. Geochemical characteristics of rare-metal, rare scattered, and rare-earth elements and minerals in the Late Permian coals from the Moxinpo Mine, Chongqing, China[J]. Energy & Fuels, 2018, 32(3):3138-3151. DOI URL
[14]	SUN Y Z, ZHAO C L, LI Y H, et al. Anomalous concentrations of rare metal elements, rare-scattered (dispersed) elements and rare earth elements in the coal from Iqe Coalfield, Qinghai Province, China[J]. Acta Geologica Sinica, 2015, 89(1):229-241. DOI URL
[15]	DAI S F, WANG X B, SEREDIN V V, et al. Petrology, mineralogy, and geochemistry of the Ge-rich coal from the Wulantuga Ge ore deposit, Inner Mongolia, China: New data and genetic implications[J]. International Journal of Coal Geology, 2012, 90:72-99.
[16]	邹建华, 刘东, 田和明, 等. 内蒙古阿刀亥矿晚古生代煤的微量元素和稀土元素地球化学特征[J]. 煤炭学报, 2013, 38(6):1012-1018.
[17]	吴艳艳, 秦勇, 易同生. 贵州凯里梁山组高硫煤中稀土元素的富集及其地质成因[J]. 地质学报, 2010, 84(2):280-285.
[18]	赵志根, 唐修义, 李宝芳. 淮南矿区煤的稀土元素地球化学[J]. 沉积学报, 2000, 18(3):453-459.
[19]	王文峰, 秦勇, 宋党育, 等. 晋北中高硫煤中稀土元素的地球化学特征[J]. 地球化学, 2002, 31(6):564-570.
[20]	曾玲, 孙晓光, 崔少华, 等. 西山煤田构造-水文地质对煤层气成藏的控制作用[J]. 煤炭科学技术, 2019, 47(9):80-88.
[21]	FINKELMAN R B. Trace and minor elements in coal[M]// ENGEL M H, MACKO S A. Organic Geochemistry. New York: Plenum, 1993: 593-607.
[22]	DAI S F, REN D Y, CHOU C L, et al. Geochemistry of trace elements in Chinese coals: A review of abundances, genetic types, impacts on human health, and industrial utilization[J]. International Journal of Coal Geology, 2012, 94(1):3-21. DOI URL
[23]	TAYLOR R S, MCLENNAN S M. The Continental Crust: Its Composition and Evolution[M]. Oxford: Blackwell, 1985:1-312.
[24]	崔晓南, 黄文辉, 敖卫华, 等. 渭北煤田下峪口矿二叠纪煤中稀土元素地球化学研究[J]. 地学前缘, 2016, 23(3):90-96.
[25]	秦身钧, 高康, 王金喜, 等. 黔西南盘县火烧铺和金佳矿区晚二叠世煤中伴生元素的地球化学特征[J]. 煤炭学报, 2016, 41(6):1507-1516.
[26]	孔洪亮, 曾荣树, 庄新国, 等. 辽宁北票地区煤中微量元素研究[J]. 现代地质, 2001, 15(4):415-420.
[27]	姚文博, 杨珍, 刘蔚阳, 等. 彬长矿区侏罗统延安组4号煤微量元素地球化学特征[J]. 中国煤炭地质, 2018, 30(5):6-9.
[28]	DAI S F, GRAHAM I T, COLIN R W. A review of anomalous rare earth elements and yttrium in coal[J]. International Journal of Coal Geology, 2016, 159:82-95. DOI URL
[29]	赵存良. 鄂尔多斯盆地与煤伴生多金属元素的分布规律和富集机理[D]. 北京: 中国矿业大学(北京), 2014:1-156.
[30]	王佩佩. 滇东黔西晚二叠世煤中矿物及微量元素富集分异机理[D]. 北京: 中国矿业大学(北京), 2017:1-166.
[31]	代世峰, 任德贻, 李生盛. 华北若干晚古生代煤中稀土元素的赋存特征[J]. 地球学报, 2003, 24(3):273-278.
[32]	王剑, 陈立江, 武卫东, 等. 太原西山煤田微量元素地球化学特征及其地质意义[J]. 科学技术与工程, 2016, 16(15):15-21.
[33]	熊树斌, 李杨浩, 瞿亮, 等. 云南临沧大田河锗煤矿床稀土元素地球化学特征[J]. 矿物学报, 2018, 38(3):313-320.
[34]	DAI S F, SEREDIN V V, WARD C R, et al. Origin of minerals and elements in the Late Permian coals, tonsteins, and host rocks of the Xinde Mine, Xuanwei, eastern Yunnan, China[J]. Coal Geology, 2014, 121:53-78. DOI URL
[35]	DAI S F, SEREDIN V V, WARD C R, et al. Enrichment of U-Se-Mo-Re-V in coals preserved within marine carbonate successions: geochemical and mineralogical data from the Late Permian Guiding Coalfield, Guizhou, China[J]. Mineral Deposita, 2015, 50(2):159-186. DOI URL
[36]	SHAND P, JOHANNESSON K H, CHUDAVE O, et al. Rare earth element contents of high P_CO₂ groundwaters of Primory, Russia: mineral stability and complexation controls[M]// JOHANNESSON K H. Rare Earth Elements in Groundwater Flow System. Netherlands: Springer, 2005:161-186.
[37]	HE B, XU Y, ZHONG Y, et al. The Guadalupian-Lopingian boundary mudstones at Chaotian (SW China) are clastic rocks rather than acidic tuffs: Implication for a temporal coincidence between the end Guadalupian mass extinction and the Emeishan volcanism[J]. Lithos, 2010, 119(1/2):10-19. DOI URL
[38]	HAYASHI K I, FUJISAWA H, HOLLAND H D, et al. Geochemistry of 1.9 Ga sedimentary rocks from northeastern Labrador, Canada[J]. Geochimica et Cosmochimica Acta, 1997, 61(19):4115-4137. DOI URL
[39]	DAI S F, ZHANG W G, WARD C R, et al. Mineralogical and geochemical anomalies of late Permian coals from the Fusui Coalfield, Guangxi Province, southern China: Influences of terrigenous materials and hydrothermal fluids[J]. International Journal of Coal Geology, 2013, 105:60-84. DOI URL
[40]	DAI S F, LIU J L, WARD C R, et al. Mineralogical and geochemical compositions of Late Permian coals and host rocks from the Guxu Coalfield, Sichuan Province, China, with emphasis on enrichment of rare metals[J]. International Journal of Coal Geology, 2016, 166:71-95. DOI URL

样品编号	样品种类	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Y	Ho	Er	Tm	Yb	Lu	ΣREE	富集系数
2#-M1	煤	26.40	60.10	5.89	22.10	4.48	0.62	4.72	0.70	4.51	21.20	0.91	2.98	0.41	2.82	0.40	158.24	1.15
2#-M2	煤	15.70	31.60	3.58	13.80	2.82	0.43	2.82	0.41	2.51	10.70	0.43	1.50	0.20	1.33	0.18	88.01	0.64
2#-M3	煤	12.00	23.80	2.70	10.20	1.98	0.30	2.06	0.29	1.76	8.36	0.34	1.10	0.14	1.06	0.15	66.24	0.48
2#-M4	煤	12.20	24.20	2.76	10.50	2.02	0.31	2.06	0.28	1.68	8.18	0.33	1.06	0.14	0.97	0.14	66.83	0.49
3#-M1	煤	9.19	17.60	1.98	7.69	1.72	0.41	2.21	0.40	2.84	14.30	0.60	2.01	0.28	2.06	0.31	63.60	0.46
3#-M2	煤	37.00	75.90	8.22	29.90	5.62	0.86	5.52	0.69	3.80	14.80	0.68	2.12	0.27	1.86	0.25	187.49	1.37
3#-M3	煤	23.40	46.20	5.19	19.20	3.72	0.63	3.94	0.55	3.26	14.40	0.62	1.94	0.25	1.72	0.23	125.25	0.91
3#-M4	煤	21.00	40.80	4.60	17.40	3.31	0.56	3.44	0.48	2.94	13.40	0.57	1.80	0.23	1.54	0.21	112.28	0.82
8#-M1	煤	8.54	15.00	1.68	6.24	1.14	0.19	1.21	0.15	0.85	4.43	0.17	0.55	0.07	0.52	0.07	40.81	0.30
8#-M2	煤	9.25	17.40	1.93	7.16	1.34	0.23	1.43	0.18	1.02	4.93	0.19	0.63	0.08	0.58	0.08	46.43	0.34
8#-M3	煤	7.35	13.00	1.48	5.62	1.04	0.18	1.14	0.14	0.79	4.02	0.15	0.49	0.06	0.47	0.06	35.99	0.26
8#-M4	煤	17.50	33.70	4.10	17.40	3.59	0.68	3.60	0.45	2.57	13.10	0.50	1.68	0.23	1.64	0.24	100.98	0.74
8#-M5	煤	9.49	20.90	2.76	12.30	2.64	0.50	2.68	0.34	1.79	8.22	0.32	1.01	0.13	0.93	0.14	64.15	0.47
8#-M6	煤	11.20	26.20	3.44	15.60	3.45	0.63	3.25	0.39	2.05	10.20	0.38	1.26	0.17	1.20	0.18	79.60	0.58
9#-M1	煤	7.90	14.60	1.68	6.52	1.44	0.28	1.56	0.23	1.56	8.66	0.32	1.09	0.15	1.08	0.15	47.22	0.34
9#-M2	煤	9.92	20.70	2.52	10.40	2.36	0.41	2.08	0.25	1.46	7.42	0.29	0.98	0.13	0.96	0.14	60.02	0.44
9#-M3	煤	7.80	16.90	2.19	9.36	2.11	0.34	1.72	0.20	1.12	5.81	0.22	0.76	0.10	0.77	0.11	49.51	0.36
9#-M4	煤	6.02	11.20	1.34	5.48	1.24	0.22	1.30	0.19	1.26	6.42	0.25	0.81	0.11	0.76	0.11	36.71	0.27
9#-M5	煤	8.42	16.70	2.03	8.43	1.87	0.32	1.63	0.18	0.98	4.49	0.18	0.58	0.07	0.50	0.07	46.45	0.34
9#-M6	煤	14.00	31.20	3.77	15.70	3.77	0.66	3.52	0.48	2.83	12.00	0.53	1.63	0.21	1.38	0.18	91.86	0.67
9#-M7	煤	12.60	25.20	2.89	11.60	2.56	0.44	2.42	0.31	1.78	7.80	0.33	1.04	0.13	0.92	0.13	70.15	0.51
9#-M8	煤	13.00	26.80	3.13	12.60	2.90	0.51	2.88	0.41	2.42	10.40	0.45	1.36	0.17	1.16	0.16	78.35	0.57
2#-D1	顶板	42.30	100.00	9.36	35.00	6.46	0.80	6.47	0.85	4.94	21.20	0.93	3.04	0.42	3.00	0.44	235.21	1.71
2#-D2	底板	46.20	85.90	9.16	28.20	4.16	0.88	5.00	0.76	4.06	18.40	0.83	2.26	0.34	2.33	0.34	208.82	1.52
3#-J1	夹矸	74.30	138.00	14.60	47.20	8.16	1.31	9.02	1.36	8.12	35.80	1.72	4.71	0.67	4.53	0.65	350.15	2.55
3#-D1	顶板	66.50	120.00	11.90	39.20	6.82	1.20	7.51	1.07	6.08	28.80	1.30	3.69	0.54	3.68	0.53	298.82	2.18
8#-J1	夹矸	57.40	120.00	12.70	45.40	7.54	1.40	7.74	0.92	5.28	24.10	1.02	3.34	0.45	3.18	0.47	290.94	2.12
中国煤值^[20]		22.50	46.70	6.42	22.30	4.07	0.84	4.65	0.62	3.74	18.20	1.79	0.96	1.79	0.64	2.08	137.30	-
美国煤值^[19]		12.00	21.00	2.40	9.50	1.70	0.40	1.80	0.30	1.90	8.50	0.35	1.10	0.15	0.95	0.14	62.19	-
世界煤值^[20]		11.30	23.10	3.51	12.20	2.10	0.47	2.70	0.32	2.10	8.40	0.54	0.93	0.31	1.00	0.20	69.18	-
上陆壳值^[21]		30.00	64.00	7.10	26.00	4.50	0.88	3.80	0.64	3.50	22.00	2.30	0.80	2.30	0.33	2.20	170.35	-

样品编号	样品种类	La	Ce	Pr	Nd	Sm	Eu	Gd	Tb	Dy	Y	Ho	Er	Tm	Yb	Lu	ΣREE	富集系数
2#-M1	煤	26.40	60.10	5.89	22.10	4.48	0.62	4.72	0.70	4.51	21.20	0.91	2.98	0.41	2.82	0.40	158.24	1.15
2#-M2	煤	15.70	31.60	3.58	13.80	2.82	0.43	2.82	0.41	2.51	10.70	0.43	1.50	0.20	1.33	0.18	88.01	0.64
2#-M3	煤	12.00	23.80	2.70	10.20	1.98	0.30	2.06	0.29	1.76	8.36	0.34	1.10	0.14	1.06	0.15	66.24	0.48
2#-M4	煤	12.20	24.20	2.76	10.50	2.02	0.31	2.06	0.28	1.68	8.18	0.33	1.06	0.14	0.97	0.14	66.83	0.49
3#-M1	煤	9.19	17.60	1.98	7.69	1.72	0.41	2.21	0.40	2.84	14.30	0.60	2.01	0.28	2.06	0.31	63.60	0.46
3#-M2	煤	37.00	75.90	8.22	29.90	5.62	0.86	5.52	0.69	3.80	14.80	0.68	2.12	0.27	1.86	0.25	187.49	1.37
3#-M3	煤	23.40	46.20	5.19	19.20	3.72	0.63	3.94	0.55	3.26	14.40	0.62	1.94	0.25	1.72	0.23	125.25	0.91
3#-M4	煤	21.00	40.80	4.60	17.40	3.31	0.56	3.44	0.48	2.94	13.40	0.57	1.80	0.23	1.54	0.21	112.28	0.82
8#-M1	煤	8.54	15.00	1.68	6.24	1.14	0.19	1.21	0.15	0.85	4.43	0.17	0.55	0.07	0.52	0.07	40.81	0.30
8#-M2	煤	9.25	17.40	1.93	7.16	1.34	0.23	1.43	0.18	1.02	4.93	0.19	0.63	0.08	0.58	0.08	46.43	0.34
8#-M3	煤	7.35	13.00	1.48	5.62	1.04	0.18	1.14	0.14	0.79	4.02	0.15	0.49	0.06	0.47	0.06	35.99	0.26
8#-M4	煤	17.50	33.70	4.10	17.40	3.59	0.68	3.60	0.45	2.57	13.10	0.50	1.68	0.23	1.64	0.24	100.98	0.74
8#-M5	煤	9.49	20.90	2.76	12.30	2.64	0.50	2.68	0.34	1.79	8.22	0.32	1.01	0.13	0.93	0.14	64.15	0.47
8#-M6	煤	11.20	26.20	3.44	15.60	3.45	0.63	3.25	0.39	2.05	10.20	0.38	1.26	0.17	1.20	0.18	79.60	0.58
9#-M1	煤	7.90	14.60	1.68	6.52	1.44	0.28	1.56	0.23	1.56	8.66	0.32	1.09	0.15	1.08	0.15	47.22	0.34
9#-M2	煤	9.92	20.70	2.52	10.40	2.36	0.41	2.08	0.25	1.46	7.42	0.29	0.98	0.13	0.96	0.14	60.02	0.44
9#-M3	煤	7.80	16.90	2.19	9.36	2.11	0.34	1.72	0.20	1.12	5.81	0.22	0.76	0.10	0.77	0.11	49.51	0.36
9#-M4	煤	6.02	11.20	1.34	5.48	1.24	0.22	1.30	0.19	1.26	6.42	0.25	0.81	0.11	0.76	0.11	36.71	0.27
9#-M5	煤	8.42	16.70	2.03	8.43	1.87	0.32	1.63	0.18	0.98	4.49	0.18	0.58	0.07	0.50	0.07	46.45	0.34
9#-M6	煤	14.00	31.20	3.77	15.70	3.77	0.66	3.52	0.48	2.83	12.00	0.53	1.63	0.21	1.38	0.18	91.86	0.67
9#-M7	煤	12.60	25.20	2.89	11.60	2.56	0.44	2.42	0.31	1.78	7.80	0.33	1.04	0.13	0.92	0.13	70.15	0.51
9#-M8	煤	13.00	26.80	3.13	12.60	2.90	0.51	2.88	0.41	2.42	10.40	0.45	1.36	0.17	1.16	0.16	78.35	0.57
2#-D1	顶板	42.30	100.00	9.36	35.00	6.46	0.80	6.47	0.85	4.94	21.20	0.93	3.04	0.42	3.00	0.44	235.21	1.71
2#-D2	底板	46.20	85.90	9.16	28.20	4.16	0.88	5.00	0.76	4.06	18.40	0.83	2.26	0.34	2.33	0.34	208.82	1.52
3#-J1	夹矸	74.30	138.00	14.60	47.20	8.16	1.31	9.02	1.36	8.12	35.80	1.72	4.71	0.67	4.53	0.65	350.15	2.55
3#-D1	顶板	66.50	120.00	11.90	39.20	6.82	1.20	7.51	1.07	6.08	28.80	1.30	3.69	0.54	3.68	0.53	298.82	2.18
8#-J1	夹矸	57.40	120.00	12.70	45.40	7.54	1.40	7.74	0.92	5.28	24.10	1.02	3.34	0.45	3.18	0.47	290.94	2.12
中国煤值^[20]		22.50	46.70	6.42	22.30	4.07	0.84	4.65	0.62	3.74	18.20	1.79	0.96	1.79	0.64	2.08	137.30	-
美国煤值^[19]		12.00	21.00	2.40	9.50	1.70	0.40	1.80	0.30	1.90	8.50	0.35	1.10	0.15	0.95	0.14	62.19	-
世界煤值^[20]		11.30	23.10	3.51	12.20	2.10	0.47	2.70	0.32	2.10	8.40	0.54	0.93	0.31	1.00	0.20	69.18	-
上陆壳值^[21]		30.00	64.00	7.10	26.00	4.50	0.88	3.80	0.64	3.50	22.00	2.30	0.80	2.30	0.33	2.20	170.35	-

样品编号	Ad	煤灰成分
样品编号	Ad	SiO₂	Al₂O₃	Fe₂O₃	CaO	MgO	TiO₂	SO₃	P₂O₅	K₂O	Na₂O	MnO₂	总和
2#-M1	30.78	54.22	38.57	1.42	1.26	0.29	1.48	0.18	0.14	0.62	0.22	0.01	98.41
2#-M2	15.84	49.52	40.55	1.49	1.76	0.24	1.66	1.52	0.04	0.31	0.13	0.03	97.25
2#-M3	9.66	46.28	40.50	5.92	1.24	0.56	1.36	1.45	0.04	0.17	0.20	0.15	97.87
2#-M4	10.62	46.90	38.48	6.16	1.75	0.58	1.34	2.34	0.06	1.16	0.24	0.10	99.11
3#-M1	18.29	51.90	41.76	1.11	0.44	0.38	1.28	0.22	0.08	0.92	0.18	0.01	98.28
3#-M2	21.61	49.88	41.91	1.19	1.14	0.21	1.34	1.04	0.10	0.40	0.19	0	97.40
样品编号	Ad	煤灰成分
样品编号	Ad	SiO₂	Al₂O₃	Fe₂O₃	CaO	MgO	TiO₂	SO₃	P₂O₅	K₂O	Na₂O	MnO₂	总和
3#-M3	13.01	50.00	42.72	0.88	1.24	0.20	1.66	0.68	0.10	0.20	0.19	0.01	97.88
3#-M4	13.62	48.00	43.34	0.81	0.98	0.21	1.59	0.83	0.08	0.27	0.19	0.01	96.31
8#-M4	13.55	42.65	33.31	18.40	0.45	0.21	1.28	0.51	0.11	0.36	0.09	0.05	97.42
8#-M5	8.83	41.55	31.66	21.18	0.85	0.26	0.66	1.18	0.05	0.39	0.19	0.14	98.11
8#-M6	13.76	45.00	34.16	15.95	0.64	0.25	1.16	1.10	0.06	0.46	0.24	0.09	99.11
8#-M1	5.38	36.35	29.16	24.78	1.64	0.28	0.50	2.60	0.05	2.27	0.14	0.06	97.83
8#-M2	6.50	35.20	28.26	28.08	1.26	0.25	0.54	1.68	0.04	1.60	0.14	0.05	97.10
8#-M3	7.51	23.45	19.20	50.95	1.16	0.22	0.30	1.52	0.04	1.46	0.12	0.04	98.46
9#-M1	11.05	44.15	37.64	7.15	2.42	0.67	1.36	2.39	0.06	0.25	0.16	0.09	96.34
9#-M2	9.92	48.30	39.63	3.54	2.04	0.47	1.10	2.08	0.06	0.22	0.18	0.06	97.68
9#-M3	9.27	47.38	40.26	4.25	1.18	0.20	0.60	1.86	0.06	0.17	0.30	0.04	96.30
9#-M4	8.54	48.90	39.57	2.07	2.26	0.40	1.14	2.98	0.04	0.21	0.30	0.05	97.92
9#-M5	6.06	46.58	38.84	2.89	2.70	0.37	0.74	4.16	0.04	0.06	0.20	0.07	96.65
9#-M6	12.10	45.55	38.60	3.87	2.60	0.76	1.70	2.74	0.07	0.04	0.20	0.07	96.20
9#-M7	10.33	48.08	37.04	4.21	3.36	0.90	1.12	4.30	0.04	0.05	0.15	0.09	99.34
9#-M8	14.10	48.55	39.40	4.30	1.61	0.44	1.82	2.18	0.04	0.06	0.11	0.06	98.57
2#-D1	56.38	54.01	39.59	1.65	0.16	0.20	0.83	1.06	0.05	0.46	0.18	0.01	98.20
2#-D2	81.88	51.15	31.31	6.00	0.17	0.49	1.12	4.25	0.04	3.64	0.13	0.01	98.31
3#-J1	68.51	52.62	39.29	0.96	0.25	0.32	3.71	0.23	0.09	0.82	0.23	0	98.54
3#-D1	75.59	55.83	35.86	0.77	0.11	0.29	2.06	0.11	0.05	1.28	0.21	0	96.58
8#-J1	56.06	50.12	41.47	1.71	0.41	0.12	0.77	2.89	0.05	0.43	0.05	0.01	98.05

样品编号	Ad	煤灰成分
样品编号	Ad	SiO₂	Al₂O₃	Fe₂O₃	CaO	MgO	TiO₂	SO₃	P₂O₅	K₂O	Na₂O	MnO₂	总和
2#-M1	30.78	54.22	38.57	1.42	1.26	0.29	1.48	0.18	0.14	0.62	0.22	0.01	98.41
2#-M2	15.84	49.52	40.55	1.49	1.76	0.24	1.66	1.52	0.04	0.31	0.13	0.03	97.25
2#-M3	9.66	46.28	40.50	5.92	1.24	0.56	1.36	1.45	0.04	0.17	0.20	0.15	97.87
2#-M4	10.62	46.90	38.48	6.16	1.75	0.58	1.34	2.34	0.06	1.16	0.24	0.10	99.11
3#-M1	18.29	51.90	41.76	1.11	0.44	0.38	1.28	0.22	0.08	0.92	0.18	0.01	98.28
3#-M2	21.61	49.88	41.91	1.19	1.14	0.21	1.34	1.04	0.10	0.40	0.19	0	97.40
样品编号	Ad	煤灰成分
样品编号	Ad	SiO₂	Al₂O₃	Fe₂O₃	CaO	MgO	TiO₂	SO₃	P₂O₅	K₂O	Na₂O	MnO₂	总和
3#-M3	13.01	50.00	42.72	0.88	1.24	0.20	1.66	0.68	0.10	0.20	0.19	0.01	97.88
3#-M4	13.62	48.00	43.34	0.81	0.98	0.21	1.59	0.83	0.08	0.27	0.19	0.01	96.31
8#-M4	13.55	42.65	33.31	18.40	0.45	0.21	1.28	0.51	0.11	0.36	0.09	0.05	97.42
8#-M5	8.83	41.55	31.66	21.18	0.85	0.26	0.66	1.18	0.05	0.39	0.19	0.14	98.11
8#-M6	13.76	45.00	34.16	15.95	0.64	0.25	1.16	1.10	0.06	0.46	0.24	0.09	99.11
8#-M1	5.38	36.35	29.16	24.78	1.64	0.28	0.50	2.60	0.05	2.27	0.14	0.06	97.83
8#-M2	6.50	35.20	28.26	28.08	1.26	0.25	0.54	1.68	0.04	1.60	0.14	0.05	97.10
8#-M3	7.51	23.45	19.20	50.95	1.16	0.22	0.30	1.52	0.04	1.46	0.12	0.04	98.46
9#-M1	11.05	44.15	37.64	7.15	2.42	0.67	1.36	2.39	0.06	0.25	0.16	0.09	96.34
9#-M2	9.92	48.30	39.63	3.54	2.04	0.47	1.10	2.08	0.06	0.22	0.18	0.06	97.68
9#-M3	9.27	47.38	40.26	4.25	1.18	0.20	0.60	1.86	0.06	0.17	0.30	0.04	96.30
9#-M4	8.54	48.90	39.57	2.07	2.26	0.40	1.14	2.98	0.04	0.21	0.30	0.05	97.92
9#-M5	6.06	46.58	38.84	2.89	2.70	0.37	0.74	4.16	0.04	0.06	0.20	0.07	96.65
9#-M6	12.10	45.55	38.60	3.87	2.60	0.76	1.70	2.74	0.07	0.04	0.20	0.07	96.20
9#-M7	10.33	48.08	37.04	4.21	3.36	0.90	1.12	4.30	0.04	0.05	0.15	0.09	99.34
9#-M8	14.10	48.55	39.40	4.30	1.61	0.44	1.82	2.18	0.04	0.06	0.11	0.06	98.57
2#-D1	56.38	54.01	39.59	1.65	0.16	0.20	0.83	1.06	0.05	0.46	0.18	0.01	98.20
2#-D2	81.88	51.15	31.31	6.00	0.17	0.49	1.12	4.25	0.04	3.64	0.13	0.01	98.31
3#-J1	68.51	52.62	39.29	0.96	0.25	0.32	3.71	0.23	0.09	0.82	0.23	0	98.54
3#-D1	75.59	55.83	35.86	0.77	0.11	0.29	2.06	0.11	0.05	1.28	0.21	0	96.58
8#-J1	56.06	50.12	41.47	1.71	0.41	0.12	0.77	2.89	0.05	0.43	0.05	0.01	98.05

样品编号	样品种类	(La/Lu)_N	(La/Sm)_N	(Gd/Lu)_N	富集类型	δEu	δCe	δCe/δEu	(Gd/Gd)_N^*	(Y/Ho)_N	TiO₂/Al₂O₃
2#-M1	煤	0.70	0.88	0.99	H	0.68	1.10	1.61	1.17	0.85	0.038
2#-M2	煤	0.91	0.84	1.29	M-H	0.78	0.96	1.24	1.17	0.91	0.041
2#-M3	煤	0.85	0.91	1.16	M-H	0.76	0.95	1.26	1.21	0.89	0.034
2#-M4	煤	0.96	0.91	1.28	M-H	0.79	0.95	1.21	1.23	0.91	0.035
3#-M1	煤	0.32	0.80	0.60	H	1.01	0.94	0.93	1.07	0.87	0.031
3#-M2	煤	1.58	0.99	1.86	L-M	0.82	0.99	1.22	1.28	0.79	0.032
3#-M3	煤	1.07	0.94	1.42	L-M	0.85	0.96	1.12	1.23	0.85	0.039
3#-M4	煤	1.07	0.95	1.39	L-M	0.85	0.95	1.11	1.21	0.86	0.037
8#-M1	煤	1.27	1.12	1.42	L	0.86	0.90	1.05	1.35	0.97	0.038
8#-M2	煤	1.26	1.04	1.54	L	0.89	0.94	1.05	1.32	0.93	0.021
8#-M3	煤	1.23	1.06	1.50	L	0.91	0.90	0.99	1.35	0.97	0.033
8#-M4	煤	0.78	0.73	1.27	M-H	1.01	0.91	0.90	1.28	0.95	0.017
8#-M5	煤	0.74	0.54	1.66	M-H	1.00	0.93	0.92	1.28	0.94	0.019
8#-M6	煤	0.67	0.49	1.54	M-H	1.00	0.95	0.96	1.29	0.97	0.016
9#-M1	煤	0.55	0.82	0.86	H	0.95	0.91	0.96	1.19	0.98	0.036
9#-M2	煤	0.78	0.63	1.29	M-H	0.96	0.94	0.98	1.26	0.94	0.028
9#-M3	煤	0.76	0.55	1.32	M-H	0.93	0.93	1.00	1.24	0.94	0.015
9#-M4	煤	0.61	0.73	1.03	M-H	0.87	0.90	1.03	1.18	0.94	0.029
9#-M5	煤	1.32	0.68	2.02	L-M	0.98	0.92	0.94	1.31	0.91	0.019
9#-M6	煤	0.81	0.56	1.61	M-H	0.93	0.98	1.05	1.19	0.82	0.044
9#-M7	煤	1.07	0.74	1.62	M	0.93	0.95	1.02	1.25	0.85	0.029
9#-M8	煤	0.88	0.67	1.54	M-H	0.90	0.96	1.06	1.19	0.84	0.046
2#-D1	顶板	1.02	0.98	1.23	M	0.65	1.15	1.78	1.25	0.83	0.021
2#-D2	泥岩	1.46	1.67	1.25	L	0.99	0.95	0.96	1.20	0.80	0.036
3#-J1	泥岩	1.23	1.37	1.18	L	0.78	0.95	1.22	1.17	0.76	0.095
3#-D1	泥岩	1.35	1.46	1.20	L	0.87	0.96	1.11	1.22	0.81	0.058
8#-J1	夹矸	1.31	1.14	1.40	L	1.00	1.01	1.02	1.34	0.86	0.018