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现代地质 ›› 2016, Vol. 30 ›› Issue (2): 455-462.

• 环境地球化学与水文地质学 • 上一篇    下一篇

广西武鸣县典型土壤剖面Se的地球化学特征及其影响因素研究

杨琼,侯青叶,顾秋蓓,余涛,杨忠芳   

  1. (中国地质大学(北京)地球科学与资源学院,北京100083)
  • 出版日期:2016-05-02 发布日期:2016-06-15
  • 通讯作者: 余涛,男,副研究员,1979年出生,地球化学专业,主要从事环境地球化学、生态地球化学和土地质量地球化学评估等方面的研究工作。Email:yutao@cugb.edu.cn。
  • 作者简介:杨琼,女,硕士研究生,1990年出生,地球化学专业,主要从事环境地球化学研究。 Email:yangqiong9011@163.com。
  • 基金资助:

    教育部基本科研业务费优秀导师基金项目(2652015447);中国地质调查局地质大调查项目(1212010511218)。

Study of Geochemical Characteristics and Influencing Factors of Soil Selenium in the Typical Soil Profiles in Wuming County of Guangxi

YANG Qiong, HOU Qing-ye, GU Qiu-bei, YU Tao,YANG Zhong-fang   

  1. (School of Earth Sciences and Resources, China University of Geosciences, Beijing100083, China)
  • Online:2016-05-02 Published:2016-06-15

摘要:

以广西武鸣县典型的碳酸盐岩成土剖面和陆源碎屑岩成土剖面为研究对象,研究了不同成土母质在成土过程中Se元素与其形态在垂向上的迁移变化规律及其影响因素。结果表明:碳酸盐岩和陆源碎屑岩在成土过程中,土壤Se含量均继承了成土母质的特点,且前者在表层明显富集,而后者相对较稳定,算术平均值分别为0.55 mg/kg和1.43 mg/kg。前者的水溶性总硒含量高于后者,平均含量分别为3.48 μg/kg和1.81 μg/kg,但均以硒酸态硒为主,其次是亚硒酸态硒和腐殖酸结合态硒。成土剖面上,土壤Se含量及其形态影响因素研究表明,碳酸盐岩成土剖面上,Se的含量与形态主要受土壤TOC含量和pH值影响;陆源碎屑岩成土剖面上,影响Se的含量及其形态的因素较多,土壤pH值、TOC、Al2O3和Fe2O3含量以及土壤质地等均对其有不同程度的影响。

关键词: 成土母质, 土壤剖面, 硒含量, 硒形态, 影响因素, 广西武鸣

Abstract:

In this paper, the typical soil profiles of carbonate rock and terrigenous clastic rock in Wuming County of Guangxi were chosen as our investigative objects. The vertical migration and influencing factors of the selenium chemical speciation in soil formation process were studied. The results showed that the soil selenium content was inherited from the parent materials, with average values of 0.55 mg/kg and 1.43 mg/kg respectively; and the selenium content of the carbonate rock was enriched significantly in the surface soil, but relatively stable in the terrigenous clastic rock. The total water soluble selenium content of the carbonate rock was higher than that in the terrigenous clastic rock, with arithmetic average values of 3.48 μg/kg and 1.81 μg/kg respectively, and they were both given priority to with selenate, followed by selenite and humic acid combined with selenium. The results showed that the contents and chemical speciations of selenium in soil profiles originated from the carbo-nate rock were mainly dominated by the total organic carbon (TOC) contents and pH values, while of which originated from the terrigenous clastic rock were controlled by the pH values, the contents of TOC, aluminum oxide (Al2O3), iron oxide (Fe2O3) and soil texture.

Key words: parent material, soil profile, selenium content, selenium speciation, influencing factor, Wu-ming, Guangxi

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