关键词: 中元古代碳酸盐岩, 微生物成因构造(MISS), 微生物席, 甲烷厌氧氧化(AOM), 生烃潜力, 华北地台

Abstract:

The well-preserved Mesoproterozoic succession in the North China Platform consists mainly of three lithological associations including peritidal quartz sandstone, shallow marine and lagoonal dark to black shales, and shallow epeiric carbonates, with a total thickness of up to 8,000 m. In addition to well-documented micro-plants, macro-algae and microbial build-ups, abundant microbially induced sedimentary structures (MISS) and mat-related sediments have been recognized in these rocks. Intensive microbial mat layers and MISS are especially well preserved in carbonates of the upper Gaoyuzhaung (ca 1.6 Ga) and lower Wumishan (ca 1.45 Ga) formations, indicating diversified microbial activities and a high organic production. In these petrified biomats, putative microbial fossils (both coccoidal and filamentous) and framboidal pyrites have been identified. The abundance of authigenic carbonate minerals in the host rocks, such as acicular aragonites, rosette barites, radial siderites, ankerites and botryoidal carbonate cements, suggests authigenic carbonate precipitation from anaerobic oxidation of methane (AOM) under anoxic/euxinic conditions. Warm climate and anoxic/euxinic conditions in the Mesoproterozoic oceans may have facilitated high microbial productivity and organic burial in sediments. While authigenic carbonate cements may record carbonate precipitation from anaerobic methane oxidation, gas blister (or dome) structures and oncolite-like concretions may indicate gas release from active methanogenesis during shallow burial. Bituminous fragments in mat-related carbonates also provide evidence for hydrocarbon generation. Under proper conditions, the Mesoproterozoic mat-rich carbonates would have the potential for hydrocarbon generation and serve as source rocks. On the basis of petrified biomats, a rough estimation suggests that the Mesoproterozoic carbonates of the North China Platform might have a hydrocarbon production potential in the order of 10×10⁸ tons.

Key words: Mesoproterozoic carbonates, microbially induced sedimentary structures, microbial mats, anaerobic oxidation of methane, hydrocarbon-generation potential, North China Platform