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现代地质 ›› 2005, Vol. 19 ›› Issue (4): 634-638.

• 环境工程 • 上一篇    

地下水中三氯乙烯-苯酚的好氧共代谢的实验研究

王雪莲,杨琦,甘小莉,尚海涛,万力   

  1. 中国地质大学水资源与环境学院,北京100083
  • 收稿日期:2005-03-09 修回日期:2005-09-19 出版日期:2005-04-20 发布日期:2005-04-20
  • 作者简介:王雪莲,女,博士研究生,1974年出生,环境工程专业,主要从事水资源和环境工程方面的研究。
  • 基金资助:

    国家自然科学基金项目(40102027)

Experimental Study on Trichloroethylene Aerobic Cometabolic Degradation with Phenol in Groundwater

WANG Xue-lian, YANG Qi, GAN Xiao-li, SHANG Hai-tao, WAN Li   

  1. School of Water Resources & Environment, China University of Geosciences, Beijing100083, China
  • Received:2005-03-09 Revised:2005-09-19 Online:2005-04-20 Published:2005-04-20

摘要:

以苯酚作为三氯乙烯(TCE)降解的共代谢基质,用瓦勃氏微量呼吸测压仪(简称瓦呼仪)作为测试手段,分析了经苯酚驯化后的混合微生物对苯酚、TCE的降解特性;并讨论了以苯酚作为共代谢基质时TCE降解的可能性。实验结果表明:未驯化的活性污泥不能降解TCE; 经苯酚驯化后的活性污泥,当TCE的质量浓度为50 μg/L时其降解效果较好,TCE的氧化率达3369%;TCE的质量浓度为100 μg/L时其降解效果较差,其氧化率仅为3.2%;苯酚和TCE共代谢降解时,苯酚的存在促进了TCE的降解,当苯酚质量浓度为40 mg/L、TCE质量浓度为50 μg/L时共代谢降解效果最好,TCE的氧化率为79.11%。

关键词: 三氯乙烯, 苯酚, 活性污泥, 瓦呼仪, 共代谢降解

Abstract:

The biodegradability of TCE and phenol was studied by the microorganisms acclimated with phenol, and was expressed by oxygen consumption of microorganisms measured with Warburg respirometer.The study also examined the feasibility of TCE degradation using phenol as cometabolic substrate. The results showed that TCE couldn′t be degraded in unacclimated activated sludge. It was also demonstrated that TCE could be efficiently degraded by phenol-acclimated activated sludge at TCE concentration of 50 μg/L and the bio-oxidation ratio was 33.69%, whereas the efficiency was low at 100 μg/L with the ratio of 3.2% only.In presence of phenol and TCE, phenol enhanced TCE transformation rate. When the initial concentrations of phenol and TCE were up to 40 mg/L and 50 μg/L respectively, the maximum cometabolic degradation efficiency of TCE was obtained, up to 79.11% in the study.

Key words: trichloroethylene (TCE), phenol, activated sludge, Warburg respirometer, cometabolic degradation

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