(1)开采过程中水合物分解速率是一个升高—降低—波动升高的过程,水合物分解产生的气体有一部分通过上盖层溢出。
(2)开采初期水合物分解产生的甲烷气体在地层中累积,导致水合物分解速率降低。开采后期由于“气穴现象”导致水合物分解速率发生波动,但总体水合物分解速率逐渐加快。
(3)开采初期井口抽出的大部分是水,由于气体不能被及时抽出而在地层中富集,导致地层中气体饱和度逐渐增大。开采后期地层中饱和度降低,井口产气速率增大,地层中甲烷气体的饱和度降低。
(4)水合物的分解过程同时发生在水合物层的上部、下部和水平方向,在井口附近会产生一个低温区,表明井口附近水合物分解较快。体系的压力波传递速度较快,在开采过程中整个体系压力迅速趋于一致。
参考文献:
[1]Sloan E D, Koh C A. Clathrate Hydrates of Nature Gases
[M]. Third edition. Boca Raton: CRC Press,2007: 53-55, 537-552.
[2]Alexei V M. Global estimates of hydratebound gas in marine sediments: how much is really out there?[J].EarthScience Reviews, 2004, 66(3): 183-197.
[3]Moridis G J, Reagan M T. On the performance of class 2 and class 3 hydrate deposits during coproduction with conventional gas
[J]. Offshore Technology Conference, 2008,Doi:10.4043/19435-MS.
[4]祝有海,张永勤,文怀军,等. 青海祁连山冻土区发现天然气水合物[J]. 地质学报,2009,83(11):1762-1771.
[5]吴能友,杨胜雄,梁金强,等. 南海神狐海域天然气水合物成藏系统初探[J]. 天然气工业, 2007, 27(9): 1-6.
[6]邓希光,吴庐山,付少英,等. 南海北部天然气水合物研究进展[J]. 海洋学研究, 2008, 26(2): 67-74.
[7]吴时国,姚根顺,董冬冬,等. 南海北部陆坡大型气田区天然气水合物的成藏地质构造特征[J]. 石油学报, 2008, 29(3):324-328.
[8]姚伯初. 南海天然气水合物的形成和分布[J]. 海洋地质与第四纪地质, 2005, 25(2):81-90.
[9]Moridis G J, Collett T S, Dallimore S R,et al. Numerical studies of gas production from several CH4, hydrate zones at the Mallik site, Mackenzie Delta, Canada[J]. Journal of Petroleum Science and Engineering,2004,43(3): 219-238.
[10]Riedel M, Bellefleur G, Mair S,et al. Acoustic impedance inversion and seismic reflection continuity analysis for delineating gas hydrate resources near the Mallik research sites, Mackenzie Delta, Northwest Territories, Canada[J].Geophysics, 2009, 74(5): 125-137.
[11]Acharyya S K. Comment on: “Mobility of arsenic in West Bengal aquifers conducting low and high groundwater arsenic. Part I: Comparative hydrochemical and hydrogeological characteristics” by Bibhash Nath, Doris Stuben, Sukumar Basu Mallik, Debashis Chatterjee, Laurent Charlet[J].Applied Geochemistry,2009, 24(1): 184-185.
[12]Tomaru H, Fehn U, Lu Z L ,et al. Halogen systematics in the Mallik 5L38 gas hydrate production research well, Northwest Territories, Canada: Implications for the origin of gas hydrates under terrestrial permafrost conditions[J].Applied Geochemistry,2007, 22(3): 656-675.
[13]Collett T S. Results at Mallik highlight progress in gas hydrate energy resource research and development[J]. Petrophysics,2005, 46(3): 237-243.
[14]Yousif M H, Li P M, Selim M S,et al. Depressurization of naturalgas hydrates in Berea sandstone cores[J]. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 1990, 8(1/2): 71-88.
[15]Kono H O, Narasimhan S, Feng Song, et al. Synthesis of methane gas hydrate in porous sediments and its dissociation by depressurizing[J]. Powder Technology, 2002, 122(2): 239-246.
[16]Ji C, Ahmadi G, Smith D H. Natural gas production from hydrate decomposition by depressurization[J].Chemical Engineering Science, 2001, 56(20): 5801-5814.
[17]Tonnet N, Herri J M. Methane hydrates bearing synthetic sedimentsexperimental and numerical approaches of the dissociation[J]. Chemical Engineering Science, 2009, 64(19): 656-675.
[18]Grover T, Moridis G J. Analysis of reservoir performance of Messoyakha gas hydrate field
[J]. SPE Annual Technical Conference and Exhibition,2008:49-53.
[19]Moridis G J, Reagan M T. Interrelationship of dissociating oceanic hydrates and global climate: Methane hydrate response to rising water temperatures[J]. Geochimica et Cosmochimica Acta, 2009, 73(13): 905-915.
[20]Tang L G. Control mechanisms for gas hydrate production by depressurization in different scale hydrate reservoirs[J]. Energy & Fuels, 2007, 21(1): 227-233.
[21]Moridis G J,Reagan M T.Evaluation of the gas production potential of marine hydrate deposits in the Ulleung Basin of the Korean East Sea[J]. SPE Journal,2009,14(4):759-781.
[22]Moridis G J, Kowalsky M B, Pruess K.TOUGH+HYDRATE v10 Users Manual: A Code for the Simulation of System Behavior in Hydratebearing Geologic Media
[M]. Berkeley, California: Lawrence Berkeley National Laboratory University of California, 2008:1-300.
[23]Moridis G J, Kowalsky M. DepressurizationInduced Gas Production From Class 1 and Class 2
[M].California: Lawrence Berkeley National Laboratory, 2006:50-160. |