Distribution Characteristics of Extractable Organic Matter in Atmospheric PM10  in Beijing

Abstract

Abstract:

PM₁₀ is one of the most important forms of air pollution, and its harmful organic compounds can be absorbed into the human body to result in different diseases, and to impact the human living environment.In the PM10 samples collected in different function zones of Beijing during four seasons of 2005, the extractable organic matter（EOM） was obtained by ultrasonic extraction and separated into saturated hydrocarbon, aromatics, non-hydrocarbons and asphaltenes, the content and distribution of EOM show that the annual average concentration of organic compounds in PM10 was 41.39 μg/m3, being 1.4 times higher than that in cleanliness district Ming Tombs site.The organic pollution level in winter was the most serious,the mass concentration of organic compound in PM10 was 6704 μg/m3, which was 1.2, 2.1 and 4.5 times higher than that in spring, autumn and summer, respectively.The concentration order of organic compositions is non-hydrocarbons,asphaltenes,aromatics and saturated hydrocarbon, indicating that organic pollution of Beijing city mainly results from coal-burning.The concentration of EOM was various in different function zones, presenting industrial or commercial zones>living or traffic zones>cleanliness zone, but during four seasons the variety of EOM was different. The contribution of pollution sources to different percentages of EOM depended on different function zones.

Key words: PM₁₀, extractable organic matter, distribution characteristics, Beijing

CLC Number:

X132

DONG Xue-ling，LIU Da-meng，YUAN Yang-sen，CHE Rui-jun. Distribution Characteristics of Extractable Organic Matter in Atmospheric PM₁₀ in Beijing[J]. Geoscience, 2008, 22(2): 325-332.

References

\[1\]郑晓燕, 刘咸德, 赵峰华, 等.北京市大气颗粒物中生物质燃烧排放贡献的季节特征\[J\].中国科学（B辑）, 2005, 35 （4）: 346-352.
\[2\]Seinfeld J H, Pandis S N.Atmospheric Chemistry and Physics:from Air Pollution to Climate Change［M］.New York：John Wiley & Sons, 1998.
\[3\]谢绍东, 于淼, 姜明.有机气溶胶的来源与形成研究现状\[J\].环境科学学报, 2006， 26（12） : 1933-1939.
\[4\]Heidi Adler, Heli Siren, Markku Kulmala, et al.Capillary electrophoretic separation of dicarboxylic acids in atmospheric aerosol particles\[J\].Journal of Chromatography（A）, 2003, 990: 133-141.
\[5\]刘大锰, 马永胜, 高少鹏.北京市区春季燃烧源大气颗粒物的污染水平和影响因素\[J\].现代地质, 2005， 19 （4）: 627-633.
\[6\]董雪玲,刘大锰, 袁杨森, 等.北京市2005年夏季大气颗粒物污染特征及影响因素\[J\].环境工程学报, 2007， 1（9）: 100-104.
\[7\]李瑞琴, 张增全, 施钧慧, 等.北京地区大气颗粒物中有机物的分析\[J\].环境科学研究, 2001, 14（3）: 21-23.
\[8\]徐殿斗, 淡默, 宋燕, 等.北京大气气溶胶中有机碳及可萃取有机卤素污染物\[J\].中国环境科学, 2005, 25（增刊）:17-21.
\[9\]王玮, 岳欣, 陈建华, 等.北京市交通路口大气颗粒物污染特征研究（Ⅲ） \[J\].环境科学研究, 2005, 18（2）: 44-47.
\[10\]曾凡刚, 李红, 王琪, 等.北京石景山地区大气中有机污染物特征与成因\[J\].环境科学研究, 2001, 14（3）: 17-20.
\[11\]王跃思, 周立, 王明星.北京大气中可形成气溶胶的有机物——现状及变化规律的初步研究\[J\].气候与环境研究, 2000, 5（1）: 13-19.
\[12\]He L Y, Hu M, Huang X F, et al.Seasonal pollution characteristics of organic compounds in atmospheric fine particles in Beijing \[J\]. Science of the Total Environment, 2006, 359: 167-176.
\[13\]He K B, Yang F M, Ma Y, et al.The characteristics of PM25 in Beijing, China［J］.Atmospheric Environment, 2001, 35: 4959-4970.
\[14\]Feng J L, Hu M, Chan C K, et al.A comparative study of the organic matter in PM25 from three Chinese megacities in three different climatic zones［J］.Atmospheric Environment, 2006, 40: 3983-3994.
\[15\]贺桃娥.北京市大气PM10中有机污染特征及来源分析\[D\].北京: 中国科学技术信息研究所, 2003.
\[16\]田健.北京市大气中多环芳烃研究\[D\].北京: 中国科学技术信息研究所, 1998.
\[17\]成玉, 闵育顺, 盛国英, 等.珠江三角洲气溶胶中有机污染物及控制对策\[J\].环境科学研究, 1998， 11（2）: 28-30.
\[18\]彭林, 沈平.兰州市大气飘尘中有机物浓度的变化及其分布特征\[J\].沉积学报, 1996, 14（1）: 156-161.
\[19\]彭林, 梁丽明, 孙建星.太原市大气颗粒物中有机物浓度的分布特征\[J\].沉积学报, 1999, 17（4）: 651-654.
\[20\]Roxanne V, Li Shaomeng.The Pacific 2001 air quality study：synthesis of findings and policy implications \[J\]. Atmospheric Environment, 2006, 40: 2637-2649.
\[21\]Steven G B, Pierre Herckes, Lowell Ashbaugh, et al. Characterization of organic aerosol in Big Bend National Park, Texas\[J\].Atmospheric Environment, 2002,36: 5807-5818.
\[22\]贺桃娥, 邵龙义, 李红, 等.北京市西北城区大气可吸入颗粒物中饱和烃的分布特征\[J\].古地理学报, 2004, 6（4）: 485-492.
\[23\]曾凡刚, 王关玉, 田健, 等.北京市部分地区大气气溶胶中多环芳烃污染特征及污染源探讨\[J\].环境科学学报, 2002, 22（3）: 284-288.
\[24\]金宜英, 田洪涛, 聂永丰, 等.3个城市生活垃圾焚烧飞灰中二恶英类分析\[J\].环境科学, 2003, 24（3）: 21-25.
\[25\]魏爱雪, 徐晓白.环境中邻苯酸酯类化合物污染研究概况\[J\].环境污染治理技术与设备, 2005, 6（7）: 89-93.
\[26\]Rogge W F, Hildemann L M, Mazurek M A, et al.Sources of fine organic aerosol,3.road dust, tire debris, and organometallic brake lining dust: roads as sources and sinks \[J\]. Environmental Science and Technology, 1993, 27（9）: 1892-1904.
\[27\]梁丽明, 彭林, 张春梅，等.烟尘、汽车尾气颗粒物中有机质的成分特征\[J\].中国环境监测, 2000, 16（4）: 47-49.
\[28\]Huang X F, He L Y, Hu M, et al.Annual variation of particulate organic compounds in PM25 in the urban atmosphere of Beijing［J］.Atmospheric Environment, 2006, 40: 2449-2458.
\[29\]曾凡刚, 王玮, 吴燕红, 等.化石燃料燃烧产物对大气环境质量的影响及研究现状\[J\].中央民族大学学报（自然科学版）, 2001, 10（2）: 113-120.
\[30\]刘大锰, 李运勇, 蒋佰坤, 等.北京首钢地区大气颗粒物中有机污染物的初步研究\[J\].地球科学——中国地质大学学报, 2003, 28（3）: 327-332.
\[31\]Rogge W F, Hildemann L M, Mazurek M A, et al.Sources of fine organic aerosol,2noncatalyst and catalystequipped automobiles and heavyduty diesel trucks \[J\].Environmental Science and Technology, 1993, 27（4）: 636-651.
\[32\]沈迪新, 陈宏德, 田群.我国汽车排放控制现状和发展战略的探讨\[J\].环境污染治理技术与设备, 2000, 1（6）: 53-58.
\[33\]袁杨森, 刘大锰, 车瑞俊, 等.北京夏季大气颗粒物中有机污染源的生物标志物示踪\[J\].中国科学院研究生院学报, 2007, 24（5）: 601-611.
\[34\]刘文卿.实验设计\[M\].北京: 清华大学出版社, 2005.

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Distribution Characteristics of Extractable Organic Matter in Atmospheric PM₁₀ in Beijing

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