欢迎访问现代地质!

现代地质 ›› 2007, Vol. 21 ›› Issue (Suppl): 12-16.

• 地质学 • 上一篇    下一篇

浙江长兴煤山剖面P/T界线附近石膏的发现及古环境模拟

蔡厚安1,2,梁汉东2,李宝芳1,梅亚青2,张俊2   

  1. 1中国地质大学 能源学院, 北京100083; 2中国矿业大学 煤炭资源与安全开采国家重点实验室,北京100083
  • 收稿日期:2006-10-20 修回日期:2006-12-05 出版日期:2007-08-20 发布日期:2007-08-20
  • 作者简介:蔡厚安,男,博士研究生,1981年出生,能源地质工程专业,主要从事层序地层学研究。
  • 基金资助:

    国家自然科学基金项目(40572020);教育部博士点基金项目(20040290005)

The Discovery of Gypsum Near the P/T Boundary of the Meishan Section in China and Its Simulation Experiment

CAI Hou-an1,2, LIANG Han-dong2, LI Bao-fang1, MEI Ya-qing2, ZHANG Jun2   

  1. 1School of Energy Resources, China University of Geosciences, Beijing100083, China;
    2State Key Laboratory of Coal Resources and Safety Mining, China University of Mining and Technology Engineering, Beijing100083, China
  • Received:2006-10-20 Revised:2006-12-05 Online:2007-08-20 Published:2007-08-20

摘要:

浙江省长兴县煤山剖面已被确定为研究全球二叠纪/三叠纪界线(PTB)的“金钉子”。其25层白粘土和26层黑粘土通常被视为地球化学事件层。宏观矿物研究显示碳酸岩沉积在煤山剖面地球化学事件层序中出现了间断,取而代之的是大量以自形晶石膏为代表的硫酸盐的出现,突出反映在第25层的白粘土中未检出常量碳酸岩矿物。从该层白粘土中分离出石膏晶体进行表征、分析以及进行其生长古环境的模拟实验。结果显示:煤山剖面25层白粘土中的石膏多为自形晶颗粒,部分以石质颗粒或粘土矿物为基质生长。石膏生长古环境模拟实验表明:以24e灰岩和27层灰岩为基质的石膏生长外部环境为具酸性的HSO-4—SO2-4的缓冲溶液,并进而推测当时古海水pH值为1.8~2.2。从而为二叠纪/三叠纪(P/T)界线之交的环境灾变事件的海洋硫酸化理论提供了新的证据。

关键词: 石膏, 古环境, 模拟试验, 煤山剖面, P/T界线

Abstract:

Meishan section, located at Changxing County, Zhejiang Province, has been confirmed as the “Golden Spike”. The geochemical event layer lies on the 25th white clay and the 26th black clay. The macro mineral analysis shows that the sedimentary of carbonate is disconnected in the geochemical event layer, especially carbonate minerals is not detected in the clay of the 25th, which is replaced by a plenty of gypsum. The paper includes the characterization and analysis of the gypsum separated from the white clay and the experiment simulating the ancient environment of gypsum formation. The result shows that most gypsum in the 25th white clay of Meishan Section is automorphic crystal particles and part of them grows on particle of stone or clay mineral. The ancient environment of the gypsum formation may be the buffer solution ofHSO-4—SO2-4and the paper further infers the pH value is between 1.12 and 2.16, which provides  a new evidence for the hypothesis of ocean sulfation near the boundary of Permian and Triassic.

Key words: gypsum, ancient environment, simulation experiment, Meishan section, P/T boundary

中图分类号: