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现代地质 ›› 2013, Vol. 27 ›› Issue (5): 1219-1224.

• 油气成藏机理 • 上一篇    下一篇

苏北地区古生界页岩等温吸附特征

刘小平1,2,董谦2,董清源2,潘继平3,丁卫星4,章亚2,孙雪娇2   

  1. 中国石油大学(北京)油气资源与探测国家重点实验室,北京 102249
  • 收稿日期:2013-06-15 修回日期:2013-07-20 出版日期:2013-10-17 发布日期:2013-10-31
  • 作者简介:刘小平,男,副教授,博士,1971年出生,矿产普查与勘探专业,主要从事石油地质教学和研究工作。Email:liuxiaoping@cup.edu.cn

Characteristics of Methane Isothermal Adsorption for Paleozoic Shale in Subei Area

LIU  Xiao-ping1,2, DONG Qian2,  DONE Qing-yuan2, PAN Ji-Ping3, DING Wei-xing4, ZHANG Ya2,SUN Xue-jiao2
  

  1. State Key Laboratory of Petroleum Resources and Prospecting ,China University of Petroleum,Beijing 102249
  • Received:2013-06-15 Revised:2013-07-20 Online:2013-10-17 Published:2013-10-31
  • Supported by:

    中国石油大学(北京)科研基金资助项目(KYJJ2012-01-36);全国油气资源战略选区调查与评价专项"全国页岩气资源潜力调查评价及有利区优选项目”( 2009GYXQ15)

摘要:

页岩含气量是评价页岩含气性的最重要指标,对资源量预测具有重要意义,而吸附气含量在页岩气中占有重要比例,因此评价页岩吸附能力显得十分重要。通过对苏北地区古生界3套层系泥页岩样品在一定温度下的甲烷等温吸附实验,获取页岩等温吸附特征曲线,分析了影响页岩吸附气量的主要因素。模拟实验结果显示,苏北古生界泥页岩饱和吸附气含量 V在 1.18~4.85m/t之间,平均2.89m/t;兰氏压力 P范围为2.01~4.24MPa,平均为2.67MPa。各层系吸附能力存在一定差异,以幕府山组、大隆组和龙潭组页岩吸附能力最强,五峰组—高家边组和孤峰组页岩吸附能力较弱。影响泥页岩吸附性能的主要因素描述如下:(1)有机碳含量大小直接影响饱和吸附气含量,有机碳越高,其饱和吸附气含量越大。(2)在有机碳含量、成熟度相近、压力相同的情况下,粘土含量高的页岩,吸附气含量高;在有机碳含量较低的页岩中,伊利石的吸附作用至关重要,伊利石含量高,吸附气含量相对高。(3)随着压力升高,吸附气含量逐渐增加,当压力增大到一定程度以后,吸附气量达到饱和,页岩吸附气含量达到饱和时所需要的最小压力(临界压力)会随着TOC的增大而减小。本次实验未发现有机质成熟度与饱和吸附气含量之间具有明显的相关性。

关键词: 页岩, 吸附气含量, 影响因素, 古生界, 苏北地区

Abstract:

The shale has content is one of the most important indicators to evaluate shale reservoirs,and of great significance to forecast reserves. As adsorbed has content plays an important proportron in shale has content the evaluation of adsorptive capacity in shale reservoirs is very necessary.Through methane isothermaladsorption experiments of Paleozoic shale samples from three different sets of strata in Subei Area,the shale isothermal adsorption curves are obtained to analyze the main affecting factors of adsorption gas contents in shale reservoirs.  The results show that the saturated adsorption(VL)are 1.18-4. 85 m3/t with an average of 2. 89 m3/t,and the Langmuir pressure constant(PL)are2.01一4. 24 MPa with an average of 2. 67 MPa.The adsorption capacity varies among these three different sets of shale strata.  Mufushan,Dalong and Longtanformations have much more adsorption gas contents than Wufeng-Gaojiabian and Gufeng formations. The main affecting factors of adsorption gas contents are concluded as follows:(1)TOC directly affects the maximumadsorption gas content,the higher the organic carbon,the greater the maximum adsorption gas content;(2)with similar values of the organic matter content,organic maturity and the same pressure,the shale with high clay contents adsorbs more gas;in the shale with low organic carbon,illite plays a vital role in the adsorption, and the adsorbed gas contents is relatively high in those shales with high contents of illite;(3)the recruired minimum pressure(critical pressure)making shale saturated with adsorbed gas will decrease with the increase of TOC.The experiments  also  show  that the organic maturity has no obvious relation with the  saturated adsorbed gas contents.

Key words: shale, adsorbed gas content, affecting factor, Paleozoic, Subei Area

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