Welcome to visit Geoscience!

Table of Content

    10 June 2023, Volume 37 Issue 03
    Petrology and Petrogeochemistry
    Detrital Zircon U-Pb Age and Hf Isotopes and Their Geological Significance of the Nenjiang River Floodplain Sediments
    LIANG Qiankun, CHEN Yuelong, WANG Shanhui, YU Yang, YANG Fan
    2023, 37(03):  529-546.  DOI: 10.19657/j.geoscience.1000-8527.2022.036
    Asbtract ( 122 )   HTML ( 19)   PDF (6291KB) ( 98 )  
    Figures and Tables | References | Related Articles | Metrics

    In this study, we conducted LA-(MC)-ICP-MS U-Pb dating and Hf isotope analysis on detrital zircons from the Nenjiang River floodplain sediments. The results show that the U-Pb ages of 293 detrital zircons can be divided into four major groups, i.e., 2,300-1,746 Ma, 363-331 Ma, 316-260 Ma, and 252-86 Ma. Mesozoic detrital zircons account for 80.9% of the total amount, indicating strong magmatism in the source region during this period. The relative outcrop size of strata (of different ages) is different in the basin: Jurassic-Cretaceous (~72%), Carboniferous-Permian (~13%), Triassic (~8%), Precambrian (~5%), and Cambrian-Silurian (~1%). The Hf isotope composition may reflect the formation and evolution of continental crust in the Nenjiang River catchment. Continental crust in the Nenjiang River basin is mainly produced by juvenile crust formation. The ca. 1,200-400 Ma period likely represents a major continental growth event in NE China, which formed 98.8% crustal components of the present crust, which may be related to the Paleo-Asian Ocean development and subduction. During ca. 400-100 Ma, the Nenjiang Basin may have experienced intense intra-continental crustal recycling. Furthermore, using the formula of recycling ratio, the remelting vs. juvenile crust ratios have been calculated. The Mesozoic zircon have a low remelting ratio and contain about 70% juvenile crust. This phenomenon is related to the partial melting of mantle material caused by subduction of the Mongol-Okhotsk Ocean and Paleo-Pacific Ocean.

    Petrogenesis and Tectonic Significance of the Late Triassic Nanmulin Intermediate-felsic Magmatic Rocks in the Gangdese Batholith, Southern Tibet
    HAN Fei, SONG Yuanbao, ZHANG Wei, LI Daoling, HUANG Yonggao, LI Yingxu, JIA Xiaochuan, YANG Xuejun, YANG Qingsong, SONG Xubo, LU Liu
    2023, 37(03):  547-561.  DOI: 10.19657/j.geoscience.1000-8527.2023.011
    Asbtract ( 95 )   HTML ( 7)   PDF (9258KB) ( 82 )  
    Figures and Tables | References | Related Articles | Metrics

    The initial Neo-Tethyan evolution in the Lhasa block is an important part for the reconstruction of the Tethys space-time framework. Due to the lack of research objective, its understanding needs to be deepened. The Nanmulin granodiorite and quartz diorite are located in the central Lhasa block. We conducted systematic zircon LA-ICP-MS U-Pb dating and whole-rock geochemical analyses for determining the petrogenesis and source region of these rocks. The results provide new constraints for the early Neo-Tethyan evolution. Zircon U-Pb dating shows that both lithologies were formed in the Late Triassic, with the granodiorite emplaced at (214.3±1.1) Ma and the quartz diorite at (206.1±1.3) Ma. Geochemically, these rocks have Rittmann index (σ) of 1.79-4.71 and are calc-alkaline. They are peraluminous with Al2O3 varying from 15.01% to 17.57%,and A/CNK=0.76-1.12. Moreover, the granodiorite has high SiO2(61.87%-73.72%, average 65.76%) and high K (up to 4.25%) and low Mg#(31-46, average 41). Rb, U, K, Pb and LREEs are enriched and Nb, Ta, Ti and HREEs are depleted, suggesting arc-related or crust-like geochemical affinities. Rb/Sr (0.05-5.50, average 2.54) values suggest that their parental magmas were crustal sourced. The granodiorite and quartz diorite have high (La/Yb)N values (average 12.05), with no clearly negative Eu anomalies (δEu=0.57-1.01, average 0.73). In summary, these data indicate that the Nanmulin intermediate-felsic rocks are I-type formed by the partial melting of juvenile crust. We propose that the northward subduction of the Neo-Tethyan was initiated before Late Triassic, which was before the formation of the newly-discovered Late Triassic Be-RB±(Nb-Ta) rare metal mineralization.

    Zircon U-Pb Isotopic Geochronology,Bulk Geochemistry and Their Geological Significance of the Quartz Monzodiorite from the Taibaihe Region in the South Qinling Orogen
    WANG Ruiting, LI Qingfeng, QIN Xishe, ZHANG Bin, WANG Bowen, JI Yuefei
    2023, 37(03):  562-572.  DOI: 10.19657/j.geoscience.1000-8527.2023.013
    Asbtract ( 100 )   HTML ( 19)   PDF (7090KB) ( 137 )  
    Figures and Tables | References | Related Articles | Metrics

    In order to ascertain the formation time, petrogenesis, magma source and tectonic setting of the intermediate rocks in Taibaihe area of South Qinling, zircon U-Pb geochronology and geochemistry of the quartz monzodiorite have been studied in the thesis. The results of LA-ICP-MS zircon U-Pb gechronology show that the 206Pb/238U weighted mean age of quartz monzodioirte is (216.8±2.2) Ma (MSWD=1.15,n=20), indicating that it was formed in the Late Triassic. According to the lithogeochemistry studies, the quartz monzodioirte belongs to the aluminum unsaturate and high potassium calc-alkaline series. This suite of rocks are rich in LILE (such as K, Rb) and HFSE (such as Zr, Hf), and relatively depleted in Nb, Ta, P, and Ti. The quartz monzodiorite is rich in LREE and poor in HREE, with slightly negative Eu anomalies. The magma source has the characteristics of crust-mantle mixed molten. Based on the tectonic evolution of the South Qinling Orogen, we consider that the Taibaihe quartz monzodioirte may be formed in the syn-collisional to post-collisional stage of the orogeny, belonging to the product of same homologous magmatism activity as Xiba granites. According to the previous studies of regional magmatism, tectonic activity and mineralization, and the new work of magmatic-metallogenic ages modification in our study, it is considered that the metallogenic age of Fengtai ore cluster region is Late Triassic.

    Record of Mesozoic Collision Orogeny on the Eastern Section of the West Kunlun Orogen: Evidence from Geochronology and Geochemistry of the Triassic Wenquan-Shenglidaban Granitic Intrusions, Xinjiang
    LU Hao, LIU Huan, HU Feng, WANG Haibo, WANG Chao, KONG Xiangchao
    2023, 37(03):  573-585.  DOI: 10.19657/j.geoscience.1000-8527.2022.022
    Asbtract ( 264 )   HTML ( 7)   PDF (6485KB) ( 67 )  
    Figures and Tables | References | Related Articles | Metrics

    Many Triassic intrusive rocks are emplaced in Wenquan-Shenglidaban area in the eastern section of the West Kunlun orogen. The lithology mainly includes medium-/fine-grained monzogranite, which records the Mesozoic tectonic evolution of the orogen and provides chronological constraints for the metallogenic age of gold, mercury, antimony and other metals in this area. In this study, detailed analyses on the petrology, whole-rock chemistry and zircon U-Pb geochronology of the Lower Triassic Adamupa lower series granites are presented. The results show that the Wenquan-Shenglidaban granite was emplaced at (203.3±1.4) Ma, indicating a product of the Late Triassic magmatic activity. The rocks have SiO2, Na2O, K2O and A/CNK of 74.41%-76.78%, 2.70%-3.81%, 3.93%-5.01% and 1.00-1.25, respectively, indicating that the granites are peraluminous high-K calc-alkaline with low total rare earth element contents. The granites are rich in light rare earth elements and negative Eu anomaly (δEu=0.39), and are relatively rich in Rb, Th and U, but depleted in Ba, Nb, Sr, and Ti. This indicates that the granites are crustal-derived S-type. Combined with the regional tectonic evolution, the Atamupa granite was likely formed in the post-orogenic stage. It is probably a post-collisional granite sourced by the partial melting of the subducted metamorphic clastic rocks into the lower crust. The resulted magma then ascended and emplaced at upper crust and the granites was formed.

    Geochronology, Geochemistry and Geological Significance of Tuanbaoshan Metamorphic Rocks in Haiyan, Qinghai Province
    WANG Xiangwei, ZHANG Baotao, YANG Haoqiang, HAN Jinguo
    2023, 37(03):  586-598.  DOI: 10.19657/j.geoscience.1000-8527.2021.149
    Asbtract ( 129 )   HTML ( 5)   PDF (7076KB) ( 58 )  
    Figures and Tables | References | Related Articles | Metrics

    The Tuanbaoshan metamorphic rocks (Hualong Group) are widely distributed in eastern South Qilian (Haiyan County, Qinghai Province). To deepen our understanding on the local metamorphic rocks and their geological significance, analyses of petrography, geochronology and geochemistry were conducted on the least-altered samples. The obtained weighted average ages ((2,047±30) Ma and (755±13) Ma) indicate that the formation age is Late Proterozoic. The average chemical content of the rock: SiO2 accounts for 62%, FeO accounts for 4.79%, Fe2O3 accounts for 6.44%, MgO accounts for 3.46%, and the average total amount of rare earth elements is 476×10-6. The rocks right-inclining chondrite-normalized REE and flat HREE patterns, weak Eu anomalies and LREE enrichment. The metamorphic rocks are rich in high field strength elements (HFSEs, e.g., Th, U, Ce, Zr, and Hf), but depleted in lithophile elements (e.g., Ba, P, and Ti). Comprehensive geochronological and geochemical characteristics suggest that protoliths of the local metamorphic rocks are mainly felsic sandy mudstone, and the protolithic formation environment may have been continental arc associated with the Rodina supercontinent breakup.

    Geochronology, Geochemistry and Geological Significance of the Huatugou Intermediate-acid Intrusions at Qimantag, Xinjiang
    MA Decheng, XI Zhen, GAO Guangming, LI Huan
    2023, 37(03):  599-612.  DOI: 10.19657/j.geoscience.1000-8527.2022.041
    Asbtract ( 116 )   HTML ( 7)   PDF (7241KB) ( 109 )  
    Figures and Tables | References | Related Articles | Metrics

    The Qimantag in East Kunlun orogen has strong magmatic activity from the Silurian to Devonian, and its formation is related to oceanic lithosphere subduction orogeny and collision-post-collision orogeny. In this paper, zircon U-Pb chronology and whole-rock major and trace element geochemistry are carried out on the Hua-tugou granodiorite in Qimantag, and the petrogenesis and tectonic background are discussed. LA-ICP-MS zircon U-Pb dating of the granodiorite is (396.5±4.6) Ma, which is the product of Early-Middle Devonian magmatic activity. The whole-rock SiO2 content is 63.01%-74.70%, showing characteristics of high K2O (1.53%-4.01%), Na2O (2.16%-3.80%) and Al2O3 (12.95%-14.48%), Mg# is 17.01-61.23, belonging to calc-alkaline and high-K calc-alkaline series. The chondrite-normalized REE patterns are moderately right-dipping and smooth, with negative Eu anomaly (δEu=0.48-0.72). Trace element spider diagram shows that the rocks are enriched in large ion lithophile elements (LILEs), such as Rb, Th, La, Ce and light rare earth elements (LREEs), and is depleted in Nb and Ta, Ba and other high field strength elements (HFSEs), belonging to I-type granite. Combined with the magmatic age, geochemical characteristics and regional tectonic evolution, we considered that the granodiorite is the partial melting product of orogenic crustal materials (especially accretionary crustal materials), mixing with some mantle-derived material, and experienced fractionation of feldspar and other minerals during the magma evolution. The tectonic regime may have been a compression-extension transition from syn-collisional to post-collisional setting.

    Identification and Significance of Early Cretaceous Highly Fractionated Alihe Granites, Northern Great Xing’an Range
    XU Liming, LIU Tao, ZHENG Jilin
    2023, 37(03):  613-626.  DOI: 10.19657/j.geoscience.1000-8527.2021.053
    Asbtract ( 139 )   HTML ( 8)   PDF (7461KB) ( 48 )  
    Figures and Tables | References | Related Articles | Metrics

    There are voluminous Mesozoic granitic rocks in the Great Xing’an Range. In this study, zircon U-Pb geochronology and geochemistry of the Alihe granites in the northern Great Xing’an Range were analyzed, and were compared with the Mesozoic granites in the northern, middle and southern Great Xing’an Range and South China. The petrogenesis and tectonic setting of the Alihe granites were then discussed. Zircon U-Pb dating on two granite samples yielded Early Cretaceous ages (134.6±1.5 Ma and 134.4±1.0 Ma). The Alihe granites are mainly composed of monzogranite, syenogranite, and alkali-feldspar granites, which contain few mafic mi-nerals and miarolitic cavities. Alaskite and aplite were found in the field investigation route and pegmatite veins were found on the granitic pluton margin. Chemically, these plutons are peraluminous (A/CNK=1.01-1.11) and show high contents of SiO2 (73.63%-77.81%), alkalis (Na2O+K2O=7.78%-8.97%), and DI (91.71-96.80), and low Ca and Mg contents. They are also enriched in Rb, Th, U, K, but depleted in Nb, Ta, P, Ti. The varying Zr/Hf and Nb/Ta ratios resemble highly-fractionated granites in South China. Integrating geological and geochemical data, we suggested that the Alihe plutons are highly fractionated I-type granites, which were formed in a post-orogenic extension setting after the Mongolia-Okhotsk Ocean closure.

    Geochronology and Geochemistry of the Intermediate-basic Dikes in the Beishan Area, Inner Mongolia: Implications for Tectonic Evolution of the Northern Margin of the Tarim Plate
    XUE Zhongkai, FAN Baocheng, HUANG Haoqing, TANG Weidong, GE Zhanlin, LI Pengwei, HU Jianhui, YANG Xiaoqi, GUO Yongchao, LI Kong
    2023, 37(03):  627-644.  DOI: 10.19657/j.geoscience.1000-8527.2022.089
    Asbtract ( 95 )   HTML ( 15)   PDF (13710KB) ( 121 )  
    Figures and Tables | References | Related Articles | Metrics

    The formation age and genesis of the altered intermediate bedrock dike in the Laodonggou gold depo-sit (Ejin Banner, northern margin of Tarim terrane) provide a window to study the gold mineralization constraints and the Paleo-Asian Ocean evolution. In this study, a series of gold ore-related diabase dike and altered diorite porphyrite dike samples were collected from the Laodonggou ore section II, on which we conducted LA-ICP-MS zircon U-Pb dating, Hf isotope and whole-rock geochemical analyses. The results showed that the emplacement of diabase dikes and diorite porphyrite dikes occurred in the Early Permian (286.5±1.7 Ma) and Middle Triassic (243.2±1.1 Ma), respectively, and such age sequence is consistent with the observed field crosscutting relationship. According to the characteristics of diorite porphyrite dikes interlaced with gold orebo-dies, the gold mineralization is suggested to be slightly after 243 Ma. Zircon εHf(t) value of the diabase dikes ranges from -3.67 to 0.97, and the whole-rock element composition shows that the rocks are peraluminous calc-alkaline. This indicates that the magma source region contains both Neoproterozoic juvenile crustal components and Mesoproterozoic ancient crustal components. Altered diorite porphyrite dike εHf(t)=-0.07 to -4.76, and the whole-rock element composition is the peraluminous K-rich basalt series (K-rich characteristics affected by the potassic alteration in the mining area), indicating that the magma is mainly derived from the Mesoproterozoic crustal melting. Based on the Late Paleozoic to Early Mesozoic tectonic evolution in the northern margin of the Tarim block, we proposed that the Late Carboniferous-Early Permian paleo-oceanic basin subduction in the Beishan region may have led to partial melting of the mantle wedge, and that the magma may have ascended into shallow faults and cooled to form diabase dikes. In the end Early Permian, the Beishan region entered an intracontinental tectonic stage, and post-orogenic extension occurred in the Middle Triassic. This likely resulted in the decompression and melting of Mesoproterozoic crustal materials, and magma emplacement along crustal faults to form diorite porphyrite dikes.

    Ore Deposits and Geochemical Prospecting
    Geochronology and Tectonic Setting of the Lamasu Cu Deposit in Northern Xinjiang: Evidence from In-situ LA-ICP-MS Garnet U-Pb Dating
    WANG Xiaotong, LIU Jun, YANG Yan, HE Juncheng
    2023, 37(03):  645-661.  DOI: 10.19657/j.geoscience.1000-8527.2023.003
    Asbtract ( 141 )   HTML ( 5)   PDF (10155KB) ( 71 )  
    Figures and Tables | References | Related Articles | Metrics

    Garnet, as a typical altered mineral in skarn deposits, is suggested to be an important mineral for obtaining accurate ore-forming age. There are abundant skarn Cu deposits in the Chinese Western Tianshan, yet the actual skarn Cu ore-forming ages remain controversial. This limits sufficient understanding of skarn Cu ore genesis and metallogenic dynamic background in the Chinese Western Tianshan. To obtain accurate metallogenic age of skarn Cu deposits in the Chinese Western Tianshan, we selected garnet from the Lamasu Cu deposit for systematic geochemical and geochronological study by Electron Probe X-ray Micro-Analyzer (EPMA) and LA-ICP-MS U-Pb dating. According to the hand-specimen and petrographic characteristics of the garnet minerals, the Lamasu deposit has three types of garnets, including red-brown, light-brown and yellow-green garnets. These garnets belong to the andradite-grossularite series, and occur as andradite (56.96%-85.09%) with minor grossularite (14.33%-43.85%). Three types of garnets yielded LA-ICP-MS U-Pb weighted average ages of (389.1±2.0) to (387.0±2.3) Ma, indicating that the Lamasu Cu mineralization occurred during the Middle Devonian subduction of the northern Tianshan oceanic crust.

    Regional Geochemical Data Analysis Using Isometric Log-ratio Transformation and Mixture Distribution
    LI Zhu, ZHANG Dehui, YANG Fan, LIU Xiangchong
    2023, 37(03):  662-673.  DOI: 10.19657/j.geoscience.1000-8527.2023.009
    Asbtract ( 118 )   HTML ( 9)   PDF (12589KB) ( 129 )  
    Figures and Tables | References | Related Articles | Metrics

    Regional geochemical exploration data are typical compositional data. Isometric log-ratio transformation (ILR) produces an orthonormal basis of geochemical data, which can eliminate the data closure effect and account for the data compositional nature. However, it is still difficult to interpret ILR-transformed variables. To make ILR transformations easier to understand, geological knowledge and data-driven methods are used to construct the interpretable ILR-transformed variables. This method was applied to extract geo-information from stream sediment geochemical data in the central and southern Da Hinggan Mountains, Inner Mongolia, northern China. Based on these geological information and hierarchical cluster analysis, sequential binary partition was constructed among the Sn, W, Cr, and Ni concentrations, and expressed as variables b1, b2 and b3 by ILR transformation. Furthermore, the expectation-maximization (EM) algorithm modified by a minimum message length criterion (MML) was employed to investigate the variables mixture distributions.The ILR-transformed variables follow either a bi-normal or tri-normal distribution, which were interpreted as fingerprints inherited from mafic magmatic, Sn-W hydrothermal, and later geological processes. The high-average subpopulation of b1, b2 and b3 variables of ILR transformation corresponds to the anomalies of W-Sn metallogenic system, and four areas were predicted to have high Sn-W prospecting potential. This study shows that the ILR transformation and MML-EM algorithm are promising tools to effectively extract geo-information from geochemical data and delineate anomalies.

    Characteristics of Structural Superimposed Halo and Deep Prospecting Prediction of Yongxin Gold Deposit, Duobaoshan Area,Heilongjiang Province
    LI Chenglu, FU Anzong, XU Wenxi, YUAN Maowen, LIU Baoshan, YANG Wenpeng, ZHAO Ruijun, ZHAO Zhonghai
    2023, 37(03):  674-689.  DOI: 10.19657/j.geoscience.1000-8527.2023.012
    Asbtract ( 187 )   HTML ( 7)   PDF (8511KB) ( 114 )  
    Figures and Tables | References | Related Articles | Metrics

    The Yongxin gold deposit is one of the major prospecting achievements in recent years in the periphery of the Duobaoshan ore concentration area in Heilongjiang Province. It is the first discovered large-scale epithermal-type gold deposit related to the Nenjiang-Heihe mélange belt. The orebody has dip angle of 20°-30°, strictly controlled by structures, and extends over 400-meter long and nearly 1,600-meter deep. Deep exploration shows that the orebody is obviously thinner and the grade is lower. To further clarify the mineralization potential at depth and guide future exploration, the tectonic superimposed halo samples were taken in different exploration lines of the mining area for geochemical analyses. The geochemical statistical analysis shows that the element assemblage at Yongxin comprises Au, Ag, Pb, Mo, W, Bi, Mn and Te, among which Au is the most direct and important indicator for the formation of gold orebodies and Ag-Te is an important associated element. Based on the axial distribution characteristics of the inner, middle, and outer zone anomalies of each indicator element in the orebody, the axial zoning sequence of orebody halo at Yongxin is established: Sb-As-Hg → Ag-Au-Te-Pb-Zn-Cu → (Bi)-Mo-Mn-Co. Among them, Sb-As-Hg are the frontal halo indicator elements, Ag-Au-Te-Pb-Zn-Cu are the near-ore indicator elements, Mo-Mn-Co are the terminal halo indicator elements. The orebody axial characteristics show that the frontal-terminal halo coexists in the margin of orebody, indicating possible existence of orebody in deep structures. According to the prediction mark of tectonic superimposed halo and geological mark, a concealed ore prediction target and a favorable ore-forming site are proposed on the horizontal projection map. The targets are located between No. 205 and 225 exploration lines, whilst the favorable ore-forming sites are located between No. 235 and 245 exploration lines. Both show the coexistence of frontal and terminal halo in the middle and lower parts of the orebody, and the anomalies of frontal and near-ore elements are obviously stronger than those of the terminal halo elements. This indicates that the orebody extends downward significantly, which shows that it is worthy of further deep exploration.

    Geochemical Characteristics of Stream Sediments and Prospecting in the Middle Reach of the Nalinggele River, Qinghai Province
    ZHANG Wei, AN Maoguo, WANG Zhipeng, YANG Qi, CHEN Huaixin, MA Xiaofeng, ZHI Chenglong, XING Qitao, PEI Changshi, WANG Na, LIU Ming
    2023, 37(03):  690-707.  DOI: 10.19657/j.geoscience.1000-8527.2022.042
    Asbtract ( 96 )   HTML ( 11)   PDF (6460KB) ( 111 )  
    Figures and Tables | References | Related Articles | Metrics

    The middle reach of the Nalinggele River in Qinghai Province is located in the Qin-Qi-Kun ore domain and the Variscan Qimantag Dulan Fe-Co-Cu-Pb-Zn-Sn-W ore belt in the eastern Kunlun mineral province. Over ten metal deposits/prospects have been discovered in/around this area, with good prospects for gold, iron, lead, zinc, copper, and nickel exploration. This study is based on the new 20-element analysis on stream sediment samples, and statistical analysis of element distribution and characteristic parameters to summarize the enrichment and dispersion regularities, element assemblage characteristics, and their relationship with metallogenic conditions. The results show that Pb, Bi, and Zn are significantly enriched in the Baishahe Formation, with a high mineralization index. Cu, Cr, Ni, Co, and V are significantly enriched in the Tanjianshan Group. The high-temperature Indosinian felsic magmatic activity could provide sufficient heat for the metal remobilization (e.g., Cu, Pb, Zn)in the formation. The skarn belt formed by contact metamorphism and metasomatism between the strata and the Indosinian felsic magma represents a favorable site for skarn-type Cu, Pb, Zn polymetallic mineral exploration. In combination with the geological conditions and geochemical characteristics of mineralization, a total of 39 geochemical comprehensive anomalies have been delineated, and 5 prospects have been defined. Among them, the Yemaquan-Niukutou-Heishan Cu-Au-Sb and the Ketihar-Hongweishan Cu-Co-Ni-V polymetallic prospects can be regarded as the key Cu polymetallic metallogenic prospect zone in the region with relatively high metallogenic potential. This study provides a reference for the optimization of multiple non-ferrous metal mineral target areas in the region, resource potential evaluation, and further geological exploration work.

    Geochemical Characteristics of River Sediment and Ore Prediction in the Malashan Area of the Karakoram Region
    LIANG Dong, HUA Bei, ZHAO Dehuai, WU Hao, WAN Shengnan, TAN Chaoxin, ZHAO Xiaojian, YANG Zhipeng
    2023, 37(03):  708-721.  DOI: 10.19657/j.geoscience.1000-8527.2023.019
    Asbtract ( 81 )   HTML ( 8)   PDF (14321KB) ( 94 )  
    Figures and Tables | References | Related Articles | Metrics

    Metallogenic conditions in the Melashan area of Karakoram are superior.However, the lack of basic geological research has restricted prospecting breakthroughs in this area.This study starts with stream sediment geochemical survey, and compares with the local background distribution characteristics of elements.The discrete elemental distributions show that Mo, Pb, Sb, As, Cu and Zn are highly enriched and unevenly distributed.The element distribution characteristics in various geological units indicate that elements such as lead and zinc are enriched in the upper section of Shenxianwan Formation, Longshan Formation and Tielongtan Formation, which is conducive to Pb-Zn mineralization.The element association regularity shows that the Bi, Zn, Pb, Sb and As assemblage indicates hydrothermal sulfide activity, the Cu, Mo and Ag assemblage indicates copper polymetallic mineralization anomaly, and the Au (W, Mg) assemblage indicates gold mineralization anomaly, and consequently 29 geochemical anomalies are delineated.Based on the regional geological characteristics and anomaly verification results, two level-I mineral prospect areas, four level-II mineral prospect areas, and one level-III mineral prospect area are divided.Besides, and three A-level prospecting targets, six B-level prospecting targets, and four C-level prospecting targets are delineated.Four lead-zinc deposits and four copper-polymetallic deposits were newly discovered.The comprehensive anomalies of Cu, Pb, Zn and Ag ore-metals correspond well with the Middle Jurassic Longshan Formation and the Upper Cretaceous Tielongtan Formation, which are favorable host for stratabound hydrothermal copper-lead-zinc deposits.The comprehensive Pb-Zn anomaly correspond well with the Middle-Lower Permian Shenxianwan Formation, which is a favorable host for low-temperature hydrothermal lead-zinc deposits.

    Experimental, Applied and Environmental Geochemistry
    Discussion on Spot Size and Energy Density Effects on Zircon U-Pb Dating Precision
    HU Ziqi, ZHANG Dexian, LIU Lei
    2023, 37(03):  722-732.  DOI: 10.19657/j.geoscience.1000-8527.2023.040
    Asbtract ( 108 )   HTML ( 2)   PDF (4858KB) ( 67 )  
    Figures and Tables | References | Related Articles | Metrics

    LA-ICP-MS, an effective method for zircon U-Pb dating, is the most commonly used technology in geochronological studies. In the LA-ICP-MS zircon U-Pb dating process, the spot diameter and energy density are two important factors that can affect the dating precision. Zircon standard 91500 and GJ-1 are selected as both standards and unknown samples, respectively, and the effects of spot size and energy densities on the LA-ICP-MS U-Pb dating were determined. We aim to optimize the LA-ICP-MS zircon U-Pb dating method, improve the analysis accuracy, and provide reference for other laboratories to carry out similar research work. The results show that with fixed energy density when the ablation beam spot increases from 25 to 65 μm, the relative error (RE) between the measured age results and the recommended values of zircon 91500 and GJ-1 decreases continuously (RE=0.61%, 0.41%, 0.13%, and 0.08%, respectively), i.e., increasing the beam spot diameter can reduce RE and improve the dating precision. Under fixed beam spot diameter (35 μm) with energy density below or equal to 3.5 J/cm2, as the energy density increases, the relative error between the measured age results and the recommended values gradually decreases (RE=8.69%, 3.48%, 3.95%, 4.16%, and 0.41%, respectively), and the dating precision gradually increases. However, when the energy density is over 3.5 J/cm2, the energy density increase can lead to a significant increase in the denudation rate, and the fractionation effect in the depth direction increases greatly. The relative error between the measured ages and recommended values increases (RE=2.40% and 0.83%, respectively), and the dating precision decreases. Therefore, in the actual test, considering the sample size and the need to preserve the integrity of the sample, choosing reasonable energy density and beam spot size can effectively improve the dating precision.

    Redox Sensitive Trace Element Compositions of the Shuinan Formation Black Shale in the Laiyang Sag: Controlling Factors of Organic Matter Enrichment
    WANG Xuxue, ZHANG Xiangyu, LI Shoujun, ZHANG Jiahao, ZHANG Zhenyu
    2023, 37(03):  733-744.  DOI: 10.19657/j.geoscience.1000-8527.2021.153
    Asbtract ( 178 )   HTML ( 2)   PDF (7945KB) ( 79 )  
    Figures and Tables | References | Related Articles | Metrics

    The geochemical characteristics of mudstone and shale in the saline lake basin are of great significance to the formation conditions and sedimentary environment of saline Source rock. To reconstruct the redox conditions and explore the controlling factors of organic matter enrichment in the Lower Cretaceous Laiyang Group of the Laiyang Sag, redox sensitive elements (RSEs, such as Mo, Cr, Zn, Cu, Ni, Co, V, As, U and Th) and total organic carbon (TOC) of mudstone and shale from this Group were analyzed. The results show that TOC content of mudstone in the Wawukuang and Zhifengzhuang Formations is relatively low, and that RSEs are not obviously enriched. TOC content of Shuinan Formation black shale increases sharply, and RSEs are enriched significantly, suggesting a weakly reducing environment. TOC content of the Longwangzhuang and Qugezhuang Formations decreases rapidly, and the RSE content is low, suggesting an oxidizing environment. Organic matter enrichment in the Shuinan Formation black shale is likely related to a combination of paleoclimate, paleoproductivity, paleosalinity and redox factors, among which paleoclimate is the main controlling factor of paleoproductivity, paleosalinity and redox conditions.

    Geochemical Characteristics of Cadmium, and Ecological Risk Assessment of Soil in Dongdagou Area,Baiyin City,Gansu Province
    HAN Baohua, DUAN Xingxing, HE Junlin, ADILAI Saitiniyazi, WANG Cuicui, DONG Yue
    2023, 37(03):  745-757.  DOI: 10.19657/j.geoscience.1000-8527.2023.025
    Asbtract ( 108 )   HTML ( 4)   PDF (2147KB) ( 93 )  
    Figures and Tables | References | Related Articles | Metrics

    Baiyin is an important non-ferrous metal province in China. Historically, unscientific and unreasonable mineral resource development and agricultural production activities have breached the heavy metal standards in Baiyin city and its surrounding areas. The controlling factors of bioavailability and ecological risk prediction of heavy metals have always been of great interest in biogeochemical behavior research. In this study, we investigated the contamination of root soil and corn seeds in/around the Dongdagou irrigation area (Baiyin city), analyzed the changes of key soil indicators in 2007 and 2018 in the local agricultural concentration area, and evaluated the ecological risks in the corn growing area. The local soil Cd content (average 17.48 mg/kg, maximum 51.1 mg/kg) exceeds the standard in some areas. The relative Cd content in different forms is carbonate state>ion exchange state>iron and manganese oxidation state>humic acid state>strong organic state>residue state≫water-soluble state. Factors such as high pH alkaline soil and low Cd accumulation of Cd-tolerant corn varieties limited the Cd bioavailability in the soil, and the exceedance rate of corn seeds is only 8.8%. There is certain Cd pollution in the local corn concentrated planting area, but it has been effectively controlled. Over half of the points of pH, Corg and CaO content that constrain the Cd bioavailability show an increasing trend, which imply that the risk will remain low for the coming future. To better control the areas with higher Cd content than the standard, we recommended to continue to choose low Cd accumulation of Cd-tolerant corn varieties for planting, and to harvest the seeds at maturity as animal feed or develop the corn seed resource industry. We also proposed to conduct recycling of other parts, especially the roots as restoration parts, to achieve reduction while restoration.

    Impacts of Cadmium Concentration in Rhizospheric Soil of Corn on Bacterial Communities: A Case Study from Silong Town, Baiyin City, Gansu Province
    HU Yonghao, DUAN Xingxing, XIA Zhaode, HAN Baohua
    2023, 37(03):  758-766.  DOI: 10.19657/j.geoscience.1000-8527.2023.029
    Asbtract ( 88 )   HTML ( 3)   PDF (3781KB) ( 29 )  
    Figures and Tables | References | Related Articles | Metrics

    To explore the response of bacterial communities of corn in rhizospheric soil to Cd pollution, we utilized the Illumina MiSeq high throughput sequencing platform, and conducted 16S rDNA amplification analysis on four groups of soil samples with different levels of Cd pollution from Silong Town (Baiyin City, Gansu Pro-vince). The results showed no significant difference in the Chao1 and Shannon indices of soil bacterial samples from these four groups of Cd-polluted samples (p>0.05), indicating that the pollution effect is insignificant. The bacterial abundance of the four sample groups is similar, and the dominant communities are largely the same, i.e., (phylum level) Proteobacteria, Bacteroidetes, Acidobacteria, Chloroflexi and Planctomycetes, and (dominant genera) are Ohtaekwangia, GP4, GP6, Nitrospira and Gemmatimonas. The Ohtaekwangia and Gemmatimonas have high stress resistance, and their relative abundance increases with increasing soil Cd content. In contrast, GP4 and GP6 have low stress resistance, and their relative abundance decreases with decreasing soil Cd content. Cadmium pollution can cause changes in bacterial diversity in the soil, but there is no simple linear relationship between bacterial diversity and Cd content. With increasing Cd content in the environment, soil bacterial diversity generally increases first and then decreases. Soil samples with intermediate pollution level have the highest bacterial diversity.

    Strontium in Soil-crop Migration and Enrichment Discussion on the Standard of Strontium Enrichment in Crops:A Case Study from the Shihe Area in Gushi, Henan
    WANG Dongxiao, YUAN Dezhi
    2023, 37(03):  767-777.  DOI: 10.19657/j.geoscience.1000-8527.2023.024
    Asbtract ( 224 )   HTML ( 4)   PDF (4917KB) ( 123 )  
    Figures and Tables | References | Related Articles | Metrics

    By systematically collecting and analyzing soil and crop samples in the Shihe river basin of Gushi (Henan Province), and conducting geochemical evaluation of land quality, we identified regional soil Sr geochemical characteristics, influencing factors, and migration and enrichment mechanisms in soil and crops, i.e., residue state>strongly organic bound state>ion-exchange state>ferromanganese oxidation state>humic acid bound state>carbonate bound state>water-soluble state account for 98%. Strontium exists primarily in the soil in an insoluble stable form. In a weakly acidic environment, the insoluble Sr-bearing minerals (SrSO4 and SrCO3) hydrate and hydrolyze to form water-soluble Sr(HCO3)2 and SrCl2, which are absorbed and utilized by plants to facilitate Sr migration in soil and crops. The Sr-rich standard for peanut, wheat, corn, rice, and other crops was proposed by comparing the Sr content of related crops (domestic and international), i.e., the lower limit is 0.65 mg/kg for Sr-rich rice, and 1.08 mg/kg for Sr-rich peanut, wheat, and corn. According to this Sr content standard, our wheat and peanut (and some rice) samples are Sr-rich. Our results provide a new reference for the development of Sr-rich land resource and Sr-rich agricultural products in the Shihe river basin.

    Geochemical Characteristics of Heavy Metals in Soils and Soil Quality Evaluation of Green Food Production in the Yongqing County of Beijing-Tianjin-Hebei Region
    HU Qinghai, WANG Xueqiu, HAN Zhixuan, CHENG Xiaomeng, WU Hui, TIAN Mi, LIU Futian, SUN Binbin, CHEN Weiming, DU Xuemiao, LIU Bin, CUI Xingtao
    2023, 37(03):  778-789.  DOI: 10.19657/j.geoscience.1000-8527.2023.015
    Asbtract ( 123 )   HTML ( 5)   PDF (6586KB) ( 103 )  
    Figures and Tables | References | Related Articles | Metrics

    To ensure food safety in the Beijing-Tianjin-Hebei region, the Yongqing County (Langfang City, Hebei Province) was selected as the research area. A total of 412 surface and 410 deep soil samples were collected to determine the concentration of eight heavy metals, i.e., As, Cd, Cr, Cu, Hg, Ni, Pb and Zn. Meanwhile, the enrichment factor and potential ecological risk were used to evaluate the degree of heavy metal pollution and ecological risk. The results showed that the average concentrations of eight heavy metals in surface (deep) soil in Yongqing region are As 9.44 mg/kg (8.93 mg/kg), Cd 0.16 mg/kg (0.10 mg/kg), Cr 64.4 mg/kg (62.3 mg/kg), Cu 24.6 mg/kg (20.7 mg/kg), Hg 0.41 mg/kg (0.20 mg/kg), Ni 27.7 mg/kg (27.7 mg/kg), Pb 20.7 mg/kg (18.2 mg/kg) and Zn 72.8 mg/kg (57.5 mg/kg), respectively. The spatial distribution of heavy metal concentration shows a pattern of high in the southwest and low in the northeast. Based on the enrichment factor (EF), the eight heavy metals could be divided into three categories: (1) Hg (2.18) is strongly influenced by human activities; (2) Pb (1.14), Cu (1.22), Zn (1.29) and Cd (1.63) are controlled by natural geological background and human activities; (3) Ni (1.01), Cr (1.05) and As (1.09) are mainly controlled by natural geological background. Results of the environmental quality assessment showed that the local soil is largely safe to use, and the risk area is only 1.1 km2, accounting for 0.14% of the total area. The area that meets the evaluation standards for green food production is about 756.62 km2, accounting for 99.43% of the total area. Among them, the area of irrigated land, dry land, orchards in accordance with the standard accounted for 98.94%, 99.29% and 99.59% of the total area of their respective land categories. In terms of ecological risk, the soil comprehensive ecological risk index of the local dryland, irrigated land and orchard agricultural land is largely low, accounting for 95.63%, 77.37% and 98.35%, respectively. Only dry land (0.13 km2) and irrigated land (0.03 km2) have a few higher ecological risk areas, which deserve further ecological evaluation. In conclusion, although heavy metal contents in some areas at Yongqing are affected by human activities, most areas have low ecological risk. In this study, the area that meets the evaluation standards for green food production and low comprehensive potential ecological risk is determined as the most suitable for large-scale green food production. This area is 669.12 km2, accounting for 87.93% of the total area. Our results provide a scientific basis for local production, planting and planning management of green agricultural products.

    Source Analysis and Spatial Distribution of Heavy Metals in Soil from Typical Open-pit Coal Mines in the Gobi Desert, Xinjiang
    DUGUER Weiwei, SHI Haitao, XING Hao, LOU Xuecong, HU Hongli, BULONG Bate
    2023, 37(03):  790-800.  DOI: 10.19657/j.geoscience.1000-8527.2023.041
    Asbtract ( 190 )   HTML ( 4)   PDF (6091KB) ( 87 )  
    Figures and Tables | References | Related Articles | Metrics

    Identifying the sources and spatial distribution characteristics of heavy metals in soil of typical opencast coal mines in Gobi desert is crucial in accurately judging and formulating soil pollution control programs. However, systematic research is still weak inadequate. In this study, 266 soil samples were systematically collected around typical coal mines in the Xinjiang Gobi Desert. Soil As, Cd, Co, Cu, Cr, Hg, Ni, Pb, Zn contents and pH values were measured. By using descriptive statistical, correlation, cluster and principal component analyses and other multivariate geostatistical analysis methods,the soil heavy metal compositions were analyzed and the heavy metal source preliminarily identified. We used the absolute principal components-multiple linear regression receptor model(APCS-MLR) and inverse distance weighting method to quantify the contribution rate of each pollution source and the heavy metal spatial distribution patterns. The results show that:(1) The average soil pH is 8.31 in the study area, the contents of nine elements were lower than the threshold for agricultural and construction land, and also below the soil heavy metal background in Xinjiang. From the functional partitions, only the As, Cd, Cu, Ni and Pb contents in the waste sewage discharge area are higher than the Xinjiang background; Cr,Ni, Zn, Co, Cu, As and Cd have moderate or high correlations, Cd and Pb have moderate correlations, and Hg has weak correlations with the other eight elements. (2)Cr, Ni, Zn, Co, Cu, As and Cd have moderate or high correlations, Cd and Pb have moderate correlations, and Hg has weak correlations with the other eight elements.(3)The cluster analysis results divide the soil heavy metals into three categories: Cr-Ni-Zn-Co-Cu-As, Cd-Pb, and Hg. (4) Source analysis results show that the main heavy metal sources of local soil are parent material (50.902%), waste water and coal dust (31.507%).

    Geochemical Genes for the Weathering of Dolomite at the Shangmanggang Gold Deposit Area in Luxi, Yunnan, SW China
    ZHANG Gaixia, SUN Jinjiajie, GONG Qingjie, JIANG Biao, YAN Taotao
    2023, 37(03):  801-812.  DOI: 10.19657/j.geoscience.1000-8527.2022.087
    Asbtract ( 223 )   HTML ( 5)   PDF (2408KB) ( 55 )  
    Figures and Tables | References | Related Articles | Metrics

    Geochemical gene is a new technique to classify and trace geological materials. The current research focuses on testing the gene steady properties and traceability of soils from the weathering of magmatic and (minor) carbonate rocks. Two weathering profiles developed on dolomite in the Shangmanggang gold deposit at Luxi (Yunnan Province, SW China) were investigated for the steady properties of geochemical genes, including lithogenes (LG01 and LG03), metallogene (MGAu and MGW), and REE (rare earth element) genes (REEG01 and REEG02). The geochemical results indicate that the dolomite was totally leached during the pedogenetic stage, followed by the soil evolution stage. Chemical weathering indices of CIA (chemical index of alteration) and WIG (weathering index of granite) were used to quantify the degrees of weathering, however the CIA may indicate the weathering degrees of the provenance sediments of dolomite. Therefore, WIG is better than CIA to determine the weathering degrees of carbonate rocks. Based on the results of heredities and inheritances of geochemical genes on weathering products, the parent rocks may have been geochemically homogeneous. The dolomite and its weathering products are classified as the intermediate-like compositions on felsic similarities of lithogenes, as anomalous gold-mineralized samples on mineralization similarities of gold metallogene, similar to the upper continental crust on REE genes. Although the anomaly materials classified on mineralization similarities of gold metallogene are not necessarily gold ores, they have likely the potential to offer ore-forming materials. The mineralization similarity of gold metallogene can be used to determine whether a weathering-type deposit was formed on the parent rock, which offers new insight or technique on tracing the provenance of ore-forming materials.

    REE Geochemistry and Its Environmental Significance of Subsurface Black Soil from Northwestern Arongqi, Songnen Plain Black Soil District
    DU Guanxin, YAN Baiquan, SUN Yu, QIAN Cheng, QIN Tao, ZANG Yanqing
    2023, 37(03):  813-820.  DOI: 10.19657/j.geoscience.1000-8527.2022.098
    Asbtract ( 157 )   HTML ( 3)   PDF (1659KB) ( 39 )  
    Figures and Tables | References | Related Articles | Metrics

    Formation of black soil in Northeast China has long been a research focus in the academia, but anthropological activities have influenced the study of surficial black soil to varying degrees. At present, there is a paucity of research on the underground black soil. In this study, the black soil from drill-cores at Arongqi of the Songnen Plain was sampled for REE geochemical analysis. Distributions of ΣREE, HREE and LREE elements of the deep black soil layer were analyzed by geostatistics. Combined with the Ce anomaly, Eu anomaly, (La/Yb)N, (La/Sm)N, (Gd/Yb)N, Al2O3 vs. TiO2 diagram and Ceanom, the provenance and formation environment of the black soil are discussed. The results show that the subsurface black soil at Arongqi have high ΣREE content (avg. 141.45 mg·kg-1). The right-inclining chondrite-normalized patterns show LREE enrichments, with weak negative Eu and strong negative Ce anomalies. The average (La/Yb)N =7.58, (La/Sm)N=1.14, and (Gd/Yb)N=3.54, indicating that the HREEs and LREEs are highly fractionated, and the LREE fractionation is stronger than that of HREE. The δEu and Al2O3/TiO2 diagram indicate that the subsurface black soil was sourced from the nearby Cretaceous felsic-intermediate magmatic rocks. The Ceanom >-0.1 (mean 3.9)suggests an anoxic environment.

    Tourism Geology
    Sedimentary Characteristics of Late Quaternary Loess in Hexigten Global Geopark and Its Paleoclimatic Implications
    LIU Xiaohong
    2023, 37(03):  821-833.  DOI: 10.19657/j.geoscience.1000-8527.2023.071
    Asbtract ( 213 )   HTML ( 17)   PDF (12425KB) ( 161 )  
    Figures and Tables | References | Related Articles | Metrics

    Loess has various paleoclimatic indicators, among which the particle size and magnetic susceptibility are important objects for paleoclimate research, and detailed studies on loess layers in different regions can faci-litate global climate change comparison and climate cycle division. Taking the Holocene Sanyixiang loess profile and the Upper Pleistocene Tuchengzi loess profile of Hexigten Global Geopark as an example, the loess samples were subjected to 14C dating, photoluminescence dating, grain size and magnetic susceptibility analyses. The regional paleoenvironmental change since the Late Quaternary was reconstructed, which provided a new and strong evidence for studying the climate types in northern China. The 14C dating on the Sanyixiang profile yielded 2.32 ka, 9.05 ka, 9.94 ka and 11.27 ka, whilst the OSL dating on the Tuchengzi profile yielded 21.5 ka, 23.5 ka, 43.9 ka, 53.4 ka, which show that the Sanyixiang and Tuchengzi profiles are Late Quaternary. The Sanyixiang and Tuchengzi profiles are young and old, respectively, forming a relatively complete loess sequence. The study shows that coarse silt(16-63 μm) was a major course-size component in the loess-paleosol deposition, accounting for 61.45%-62.4%, followed by sand(>63 μm) and clay(<4 μm). Based on stratigraphic features and grain-size curve, the Hexigten area underwent cold-hot, dry-humid cycles and at least four summer monsoon intensifying events. The grain size and magnetic susceptibility records of the Sanyi-xiang/Tuchengzi loess profiles are basically similar to those of the Luochuan profile of the loess plateau, with coarser grain size and lower magnetic susceptibility during the glacial period. Meanwhile, the magnetic susceptibility of the interglacial or interglacial step increases significantly, and the grain size becomes significantly smaller, indicating that the paleoenvironmental evolution of the two places was controlled by the East Asian monsoon intensity in a glacial-interglacial timescale.

    Important Geoheritages of Dali Nor Area in Hexigten UNESCO Global Geopark and Implications for the Dali Lake Evolution
    ZHANG Xiangge, ZHANG Xujiao, WANG Yifan, LIU Xiaohong, TIAN Nan, WANG Lingyue, HE Zexin, Aruhan , Tana
    2023, 37(03):  834-844.  DOI: 10.19657/j.geoscience.1000-8527.2023.076
    Asbtract ( 80 )   HTML ( 26)   PDF (13531KB) ( 104 )  
    Figures and Tables | References | Related Articles | Metrics

    Lakeshore landforms are not only indicators of the lake evolution in conjunction with sedimentation, but also serve as beautiful landscapes with high scenic value, making them important geoheritages. The Dali Nor area of the Hexigten UNESCO Global Geopark in Inner Mongolia preserves many geoheritages formed under the lacustrine influence, which are indicative of lake evolution and climate change. This study focuses on various lake erosion landforms, including lake caves, lake notches, lake pillars, and lake cliffs, which represent paleo-lake surfaces, as well as beach ridges, lake terraces, river landforms, and periglacial landforms. By measuring profiles in the field and comparing them with lakeshore sediments and sediment core DL04, we determined the lake-level changes and summarized the evolution process of Dali Lake since the Holocene. The lake erosion landforms indicate that the Dali Lake had four distinct high lake levels: 1,303 m, 1,296 m, 1,288 m, and 1,277 m, while the lake deposit landforms imply that they were mainly developed at the height below 1,280 m. In addition, the continuous development of the Hao Lai River, known as the “world’s narrowest river”, represents the lake water decline. Diatomaceous sediments and ice-wedge pseudomorphs imply lake expansion and recession events. This research provides a valuable reference for reconstructing the lake evolution in monsoon marginal zones.