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    10 August 2022, Volume 36 Issue 04
    Oil and Gas Exploration
    Natural Gas Exploration Prospect of the Platform Marginal Zone of the Fourth Member of Sinian Dengying Formation in Southeastern Sichuan Basin
    SUN Ziming, BIAN Changrong, ZHANG Rongqiang, SUN Wei, WU Chongyang, LIN Juanhua
    2022, 36(04):  979-987.  DOI: 10.19657/j.geoscience.1000-8527.2022.194
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    The platform marginal zone of the Sinian Dengying Formation on both sides of Mianyang-Changning extensional trough is an important exploration target for natural gas in Sichuan Basin. Since Anyue natural gas field, located in the platform marginal zone of Dengying Formation on the eastern side of the extensional trough, was discovered at the core of central Sichuan paleo-uplift, more and more attention has been paid to the deep to ultra-deep platform marginal zone of Dengying Formation on the south and north side of the paleo-uplift. However, it is unclear about its distribution, geometrical features and hydrocarbon accumulation conditions of the platform marginal zone of Dengying Formation and exploration potential, especially in southeastern Sichuan Basin. Therefore, the platform marginal zone of the fourth member of Dengying Formation in the southern slope of central Sichuan paleo-uplift and its adjacent depression was systematically studied by using the latest seismic and drilling data in southeastern Sichuan Basin. It was shown that the distribution direction of the platform marginal zone of the fourth member of the Dengying Formation extends from NE to NNW from south to north, and shows the characteristics of gentle slope platform marginal zone, which is significantly different from those in the central Sichuan paleo-uplift and its northern slope to depression. There exist three sets of source rocks developed in the Sinian Doushantuo Formation, the third member of Dengying Formation and the Cambrian Qiongzhusi Formation, which laid the sound resource basis for large and medium-sized oil and gas fields. Reservoir has a good quality. The traps are mainly lithologic traps, developed in large numbers, and have good self-sealing characteristics in the updip direction. There are three kinds of accumulation assemblages of “lower generation and upper reservoir, side generation and side reservoir, and upper generation and lower reservoir”. Two sets of regional cap rocks, Qiongzhusi Formation shale and Middle-Lower Cambrian gypsum rock, provide a good preservation condition for hydrocarbon accumulations. All of the above mentioned indicate that there are good exploration prospect and great potential for natural gas in the platform marginal zone of the fourth member of the Dengying Formation in southeastern Sichuan Basin.

    Geochemical Characteristics of Natural Gas and Hydrocarbon Charging History of the Tugeerming Area in the Eastern Kuqa Depression
    LIU Yang, LI Xianqing, ZHAO Guangjie, LIU Mancang, DONG Caiyuan, LI Jin, XIAO Zhongyao
    2022, 36(04):  988-997.  DOI: 10.19657/j.geoscience.1000-8527.2022.197
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    The oil and gas geological conditions in eastern Kuqa Depression are complex. The origin of natural gas, the time and history of oil and gas charging are disputed, which hampers regional oil and gas exploration. Based on the analyses on carbon isotope composition of natural gas, fluid inclusion petrography and homogenization temperature, and integrating the sedimentary/ burial history and tectonic evolution, the geochemical characteristics of natural gas and hydrocarbon accumulation process at Tugeerming area (eastern Kuqa depression) are revealed. The results show that methane is the main natural gas component at Tugeerming, with its content ranging from 75.56% to 90.11% and the dryness coefficient from 0.79 to 0.93. The δ13C1 (-35.73% to -33.80‰) and δ13C2 (-26.41‰ to -25.30‰) values suggest that the genetic type of natural gas is mature coal-derived gas. There are two types of inclusions in the Jurassic sandstone reservoirs at Tugeerming, i.e., yellow liquid hydrocarbon inclusions and bluish-white fluorescent gas-liquid hydrocarbon inclusions and gray gas-liquid hydrocarbon inclusions. This indicates two oil and gas charging stages at Tugeerming: (1) 13 Ma to 7 Ma crude oil charging, and (2) 2.6 Ma natural gas charging. In the Lower and Middle Kangcun Formation, the crude oil formed by source rocks at Tugeerming was charged into the wide and gentle anticlinal trap for preservation. In the Upper Kuqa Formation, the Jurassic Kezilenuer and Yangxia Formations developed good source-reservoir assemblage, with natural gas being charged at close distance to form the reservoirs in the Upper Kuqa Formation.

    Inclusion Data Analysis for the Determination of Oil Source and Accumulation Stages in Lucaogou Formation in the Chaiwopu Sag, Junggar Basin
    ZHENG Ruihui, JIN Xiao, ZHENG Duo, LI Jiayang, CHEN Xue, ZHANG Zhihuan
    2022, 36(04):  998-1008.  DOI: 10.19657/j.geoscience.1000-8527.2021.194
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    Hydrocarbon accumulation in the Chaiwopu Sag has been well documented, however the tectonic and sedimentary evolution in the Chaiwopu Sag is complex, and the source of oil and the timing of hydrocarbon accumulation are still controversial. Here, the hydrocarbon source and accumulation of the Lucaogou Formation is discussed through an improved molecular composition of inclusion method, and the fluid inclusions in the Chaiwopu Sag (Junggar Basin). Distribution characteristics of the n-alkanes are dominated by low carbon numbers, and the relative abundance of C21-tricyclic terpane and C27-steranes are higher in the early-charging oil, showing blue fluorescence. The first stage (Early Cretaceous) oil came mainly from the Lucaogou Formation (semi-)deep lacustrine-facies source rocks in the north. Meanwhile, distribution characteristics of the n-alkanes are dominated by high carbon numbers, and the relative abundance of C20-tricyclic terpane or C23-tricyclic terpane and C29-steranes are higher in the second-charging oil, showing yellow-green or yellow fluorescence. The second stage lasted from the end Late Cretaceous to the Early Paleocene, and the oil came mainly from the local Lucaogou Formation shore-shallow lacustrine-facies source rocks.

    Characteristics of Igneous Weathering Crust Reservoir and Its Relation With Oil and Gas Productivity: A Case Study of the Carboniferous Hongshanzui Reservoir, Junggar Basin
    CHEN Jun, WANG Jian, LEI Haiyan, MA Cong, MENG Ying, QI Jing
    2022, 36(04):  1009-1021.  DOI: 10.19657/j.geoscience.1000-8527.2022.204
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    The Hongshanzui oilfield is a typical weathering crust reservoir in the Junggar Basin, and has substantial prospect for exploration. This study uses macro-/micro-lithological and mineral analyses, geophysics, geochemistry and other experimental techniques to comprehensively study the petrological and structural features and controlling factors of igneous rocks at Hongshanzui. The results show that:(1) There are six types of igneous rocks at Hongshanzui: intrusive rocks, subvolcanic rocks, volcanic lava, pyroclastic lava, pyroclastic rock and sed-volcanic pyroclastic rock, among which andesite and tuff are the most developed; (2) Reservoir space combination of igneous reservoir includes primary pore-dissolution pore-level I, dissolution pore-level I /Ⅱ, level Ⅲ and level IV fracture types, with the physical properties deteriorate from level I to IV reservoirs; (3) The weathering crust develops a five-layer structure from top to bottom: hydrolysis zone, leached zone, break-down zone I, break-down zone Ⅱ and the underlying bedrock. The hydrolysis zone on the top is commonly decomposed into a dense soil layer, which can serve as a cap. Besides, the leached zone and the break-down zone I show better weathering and leaching transformation, hence the reservoir has the best physical properties; (4) Different oil and gas productivity wells have a good corresponding relationship with the weathering crust structure, which can guide the division of the dominant zone for the weathering crust igneous rock reservoir and the related productivity prediction.

    Physical Simulation Experiment on Stratification Strike-slip Fault Deformation Mechanism in the Tazhong Uplift
    PENG Zijun, FENG Lei, LUO Caiming, CHEN Shi, SONG Xingguo, LIANG Xinxin, ZHOU Xiaorong
    2022, 36(04):  1022-1034.  DOI: 10.19657/j.geoscience.1000-8527.2022.203
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    The Tazhong uplift, located in the middle of the central uplift belt of Tarim basin, is a key block for oil and gas exploration. Strike-slip faults are well developed in Ordovician carbonate rocks at Tazhong, and the role of reservoir control is obvious. The study on the strike-slip faulting mechanism is very important for oil and gas exploration and development. Strike-slip faults in the Tazhong uplift are featured by typical delamination. To clarify the main controlling factors of delamination mechanism of these strike-slip faults, four groups of physical simulation experimental models were designed. The experimental results show that the formation of strike-slip fault delamination characteristics is mainly related to vertical stratigraphic property changes (delamination) and multi-stage activities (stages). Delamination and staging could form the delamination characteristics of these strike-slip faults. The delamination differential deformation characteristics of the Tazhong strike-slip faults may have caused by the different vertical stratigraphic lithology and multi-stage tectonic activity.

    Quantitative Study on the Uppermost Mesozoic Fault Damage Zones in Northern Bozhong Sag
    CHEN Yuhang, ZHANG Xintao, YU Yixin, YANG Fan, LIU Yongjun, ZHANG Zhen, DING Kang
    2022, 36(04):  1035-1042.  DOI: 10.19657/j.geoscience.1000-8527.2022.202
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    The Bozhong sag is the largest hydrocarbon-generating sag in the Bohai Sea, and the buried hill belt in the northern part of the sag is an important exploration target. The local Mesozoic geology is mainly dominated by igneous rocks, and fractures are important to the formation of igneous reservoirs. Here, we quantified the fault damage zones by using the seismic variance attribute value, established the quantitative relationship between the width and the fault slant distance, and established a contour map of the variance attribute value. Combined with published chart and thin section data, the fault damage zones at the uppermost Mesozoic sequence in the northern Bozhong sag are quantified, verified and analyzed. The results show that the local faults have multiple fault cores, and that the fault systems are complex. The width of the fault damage zones varies from several hundred meters to several kilometers. The fault damage zones have obvious influence on the Mesozoic volcanic rocks, and the degree of influence correlates negatively with the distance from the fault. The quantitative results of fault damage zones based on seismic variance attribute value is in good agreement with the layout pattern of related research and the thin section analysis results in the study area, which demonstrate high feasibility for the quantitative study of fault damage zones.

    Fission Track Dating of Mesozoic-Cenozoic Tectonic Evolution in Ningwu Basin
    HUANG Zhigang, ZHENG Qingrong, REN Zhanli, SUN Erhu, GOU Chaoyang
    2022, 36(04):  1043-1051.  DOI: 10.19657/j.geoscience.1000-8527.2022.198
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    To study the Mesozoic-Cenozoic tectonic evolution of the Ningwu Basin and occurrence conditions of coalbed methane resources, samples were collected from the basin for fission track dating. The obtained fission track ages are of 156~139 Ma (zircon) and 97~47 Ma (apatite). Mesozoic-Cenozoic tectonic evolution of the basin is divided into three stages accordingly: Late Jurassic (156 Ma): granites on both sides of Ningwu basin began to uplift slowly, and the core depression was deposited; late Early Cretaceous (100 Ma): the paleo-temperature of the basin reached its peak, and the source rocks also reached the gas-generation peak; Late Cretaceous-Paleocene (79~59 Ma): rapid uplift erosion occurred. Although there was a short burial later, the region remained uplifted. Since the Late Oligocene (40~30 Ma), the region has been rapidly uplifted to the present position. Uplift erosion of the basin was spatially uneven: uplifting in the northeast was earlier than in the south, and the intrusion uplift and denudation rate on both sides was higher than that in the core. In the Mesozoic, the regional tectonics formed a series of en-echelon complex anticlines and synclines. In the Cenozoic, Indian Ocean plate compression on Eurasia may have formed the Ningwu Basin via strong uplift and thrusting of mountain ranges on both sides, which responded to the regional tectonic events in the North China Craton.

    Diagenesis of Triassic Shale and Its Influence on Reservoir in East Kunlun, Northern Qinghai-Tibetan Plateau
    CHAO Haide, CHEN Jianzhou, WANG Jin, LI Jiqing, WANG Guocang, ZHAO Hongyue, CAI Tingjun, LIU Libo, LI Shengfu, REN Wenkai, QIU Liang
    2022, 36(04):  1052-1064.  DOI: 10.19657/j.geoscience.1000-8527.2022.195
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    As a typical area to study shale gas reservoir characteristics in the east Kunlun (northern Qinghai-Tibetan Plateau), the research on shale diagenesis for the reservoir properties is inadequate with limiting its exploration potential. Based on petrographic observation and experimental analyses including thin section microscopy, cast thin section, scanning electron microscope (SEM) and X-ray diffraction (XRD), we studied the Triassic shale diagenesis and its impact on reservoir characteristics. The results show six types of Babaoshan Formation shale diagenesis: compaction, cementation, clay mineral transformation, metasomatism, dissolution, and thermal maturation of organic matter. Based on indicators such as organic matter maturity, rock pyrolysis peaks, smectite ratio in illite-montmorillonite mixed layer, clay mineral assemblage and pore type, we concluded that the studied shale is in the middle diagenetic stage B-late diagenetic stage. Combined with the influence of diagenetic on reservoir, compaction, cementation and clay mineral transformation can readily reduce porosity, dissolution and thermal maturation of organic matter can increase up porosity, while metasomatism has little effect on porosity.

    Microscopic Pore Structure and Fractal Characteristics From the Carboniferous Xiangbai Formation Shale in Northwestern Guizhou
    JIANG Bingren, DENG Ende, HAN Minghui, MA Zijie
    2022, 36(04):  1065-1073.  DOI: 10.19657/j.geoscience.1000-8527.2022.201
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    To study the microscopic pore characteristics of shale in marine coal-bearing strata, we studied the Carboniferous Xiangbai Formation shale in northwestern Guizhou, and used SEM and N2 adsorption analyses and fractal theory to study its fractal characteristics. We then explore the influencing factors of microscopic pore structure. The results show that four types of pores can be identified (intragranular, intergranular, organic matter and micro-fracture pores), a large number of microfractures and organic matter pores are developed, which have strong hydrocarbon generating ability and good reservoir performance. The adsorption isotherms of N2 show an inverse S-type, indicating that the adsorption isotherms were mainly mesopores. The hysteresis loops formed by adsorption isotherms and desorption isotherms were mainly H2-type thin-necked wide-body ink bottle pores. The specific surface area is large (average 13.20 m2/g), and the total pore volume is large (average 0.015 5 cm3/g). The average pore size is 6.22 nm and the massive development of nano-scale micropores would provide rich reservoir space for hydrocarbon gases. The fractal dimension D of microscopic pore structure of shale samples is larger (average 2.723 2), reflecting strong heterogeneity of pore structure. BET specific surface area shows negative correlation with TOC and quartz content, and positive correlation with fractal dimension. The average pore size has good positive correlation with the quartz content, strong negative correlation with fractal dimension, and moderate negative correlation with clay mineral content. Larger BET specific surface area and smaller average pore size correspond to larger fractal dimension and more complex pore structure.

    Distribution Prediction of High Overpressure in Jurassic Moxizhuang-Yongjin Area, Central Junggar Basin
    HAN Hongwei, LIU Zhen, MA Xinruo, LI Hongmei, HE Yangyang, XU Zeyang
    2022, 36(04):  1074-1086.  DOI: 10.19657/j.geoscience.1000-8527.2022.205
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    Prediction of abnormal formation pressure is a hot issue in oil and gas exploration and drilling engineering. For the areas with low exploration degree and few exploration wells, the unclear pore pressure distribution characteristics would hamper oil and gas exploration and efficient drilling execution. Therefore, the prediction accuracy of pore pressure needs to be improved. In this study, based on the static equilibrium principle of formation pores, a new pore pressure prediction model based on grain stress is established according to the actual geological data and pressure test data of Yong-Mo area in the central Junggar Basin. The results show that: (1) the classical pressure prediction model has defects. The Terzaghi model is not in static equilibrium, and effective stress is not the actual support force of grains, but a man-made physical variable; (2) we established the pore static equilibrium equation by using the grain stress parameters of porous medium. By comparing the prediction of overpressure of drilling wells in the local deep Jurassic sequences, we found that the pressure prediction accuracy based on grain stress is improved; (3) The pressure prediction model only considers the internal dynamic factor (i.e.deposition supercharging), and overpressure origin compensation cannot be ignored. We found that the local tectonic compression in the southern basinal margin has transferred to the basin interior, and formed the overpressure component with regular distribution. The compensation of additional tectonic stress is an effective way to improve the overpressure prediction accuracy.

    Review of the High Natural Gamma Sandstones Associated With Source Rocks in the Chang 73 Submember of the Yanchang Formation, Ordos Basin
    ZHENG Qinghua, LIU Xingjun, ZHANG Xiaolong, WANG Hongjun, LIAO Yongle, AN Erliang, LIU Tao, ZHANG Jianna, ZUO Qin
    2022, 36(04):  1087-1094.  DOI: 10.19657/j.geoscience.1000-8527.2021.185
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    For the high natural gamma sandstones associated with source rocks in the large-scale Chang 73 submember of the Triassic Yanchang Formation in the Ordos Basin, they had long been identified as high-quality source rocks (e.g. oil shales) from conventional well log profiles (e.g.natural gamma ray well logs). Based on core observation, and integrated analyses of well logging, logging, the electron microprobe and numerous actual production data of shale oil, a preliminary research about the definition was proposed. The genesis of these high natural gamma sandstones associated with source rocks in the Chang 73 submember was discussed, along with the correlation between its development and testing effect of shale oil of the Chang 7 Member. We suggest that they are narrow and broad types can be divided in the Chang 73 submember in the Ordos Basin, and that their highly radioactive genesis maybe related to deep hydrothermal sedimentation. It is newly found that there is a close correlation between their development and testing effect of shale oil of the Chang 7 member. This study has important theoretical and practical significance for the large-scale and efficient exploration and development of shale oil in the Chang 7 Member in the Ordos Basin.

    Diagenesis and Diagenetic Facies of Upper Wuerhe Formation in the Shawan Sag
    YU Jingwei, LUO Gang, LI Bin, PAN Tuo, YU Haitao, KUANG Hao, CHU Xu, ZHANG Xiaotong
    2022, 36(04):  1095-1104.  DOI: 10.19657/j.geoscience.1000-8527.2022.206
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    The Permian Upper Wuerhe Formation is a key exploration target zone in the Shawan Sag, which is a typical lithologic reservoir. Fewer studies were dedicated to the diagenesis of Upper Wuerhe Formation, which hinders deeper exploration. The data of slice, physical property, SEM and electromagnetic spectrum, combined with lithologic analysis and reservoir reserve characters, were applied to analyze the diagenetic types and facies. The results show that the diagenetic types comprise compaction, cementation and resolution. According to the diagenetic phenomena and characters, we concluded that the diagenetic evolution of Upper Wuerhe Formation has already been in the middle diagenetic stage B. Based on the intensity and typical phenomenon diagenesis, the diagenetic facies could be divided into five types, including the strong compaction tight, strong compaction-medium resolution, medium-strong compaction-calcite cementation-weak resolution, medium-strong compaction-mixed-layer illite cementation-weak resolution, and the medium-strong compaction-zeolite cementation-weak resolution digenetic facies. Combined with the Fisher typical discriminant, the diagenetic facies were built on discriminant functions to analyze the diagenetic facies distribution patterns, which would provide a foundation for deeper exploration.

    Enrichment Patterns and Main Controlling Factors of Source Rocks in the Permian Pingdiquan Formation, Eastern Junggar Basin
    FAN Yan, WANG Xulong, XIANG Caifu, WANG Qianjun, LIU Jia, LIAO Jiande, XU Huaimin
    2022, 36(04):  1105-1117.  DOI: 10.19657/j.geoscience.1000-8527.2022.196
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    To determine whether effective source rocks are developed in the eastern Junggar Basin is crucial to oil and gas exploration in the Junggar Basin. Through geochemical analysis, ΔlgR method and integration of logging and seismic data, we identified and evaluated the source rocks of the Permian Pingdiquan Formation in the eastern Junggar Basin (Zhundong), and delineated the source rock spatial distribution by combining with seismic facies. The results show that the source rocks of the Pingdiquan Formation are mainly dark mudstone, and the abundance of organic matter is medium to high. The mud and shale of semi-deep lacustrine facies is the high-quality source rocks, which is enriched in the Pingdiquan Formation (2nd member). On the plane, the source rocks are concentrated in the Kalamali piedmont zone in the north and the Bogda piedmont zone in the south, separated by the Qitai uplift. The source rock abundance in the southern and northern zones is divided by secondary sags, characterized by high TOC (>1.5%) in the west and low TOC (0.5% to 1.5%) in the east. The zoning and block characteristics are controlled by two systems and fault activities of the North Tianshan and East Junggar island arcs. Paleosalinity analysis of lake water during the depositional period shows that the northern belt is a small divided depression, while the southern belt is a connected rift basin. The results suggest that oil and gas exploration in the northern belt should be conducted from west to east, while in the southern belt should have equal importance from east to west.

    Thermal and Paleoenvironment Evolution of the Fengcheng Formation of Permian in Mahu Depression, Junggar Basin
    JIANG Zhongfa, JIANG Mengya, CHEN Hailong, LIU Longsong, WANG Xueyong, BIAN Baoli, LI Na
    2022, 36(04):  1118-1130.  DOI: 10.19657/j.geoscience.1000-8527.2021.182
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    Several exploration wells were recently drilled into the thick hydrocarbon source rock of Fengcheng Formation in the southern slope of Mahu Depression in the Junggar Basin, which brings an opportunity to reveal the source rocks there. This study collected data from five key exploration wells in the southern and northern Mahu Depression, and obtained the following findings: (1) the Fengcheng Formation source rocks are widely distributed in Mahu Depression, and the northern and southern Mahu Depression geochemical parameters show that the source rocks are of II-type and high-quality; (2) based on current geothermal, pyrolysis, biomarkers and group compositions, the Fengcheng Formation source rocks around the Mahu Depression entered mature and highly-mature stage at below 4,350 m and 4,800 m, respectively, and have entered the oil generation peak widely; (3) integrating multiple biomarker parameters, the Fengcheng Formation source rocks in northern Mahu Depression were deposited in a saline and reducing environment, and the source rocks of the Fengcheng Formation (2nd member) in southern Mahu Depression were deposited in a saline and semi-reducing environment, whilst the 3rd member (also in southern Mahu Depression) were deposited in a brackish and semi-reducing environment, and adsorbed more terrigenous organic matter. Paleoenvironment of the local Fengcheng Formation is featured by salinization (early) and desalinization (end), and the degree of salinity and reduction in the north is higher than that in the south. This study provides a theoretical basis for the subsequent exploration and deployment of tight oil and shale oil for the Fengcheng Formation in Mahu Depression.

    Saturation Calculation Model With Variable Rock-Electrical Parameters for Tight Sandstone Reservoirs: A Case Study of the Shihezi Formation (8th Member) in Western Sulige Gas Field
    LU Junhui, ZHANG Xiaoli, YANG Zhen, LI Yajun, WANG Xiaolin, ZHAO Xi
    2022, 36(04):  1131-1137.  DOI: 10.19657/j.geoscience.1000-8527.2021.183
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    Tight sandstone reservoirs are one of the major regions for oil and gas exploration. Due to the characteristics of low porosity and permeability, complex pore structure, and strong heterogeneity in rock electrical parameters, logging interpretation process for tight sandstone reservoirs is different from that of conventional reservoirs. When interpreting tight sandstone reservoirs with the Archie formula, strong heterogeneity would lead to changes in the rock electrical parameters a, b, m and n with different reservoirs. In this study, a saturation model is established by using the variable rock electrical parameters for the tight sandstone reservoir in the Shihezi Formation (8th member) in the western Sulige gas field. According to the rock-electrical experiment on 25 cores, we found that the relationship between cementation coefficient m and lgϕ is a quadratic function, the relationship between m and lithology coefficient a is a power function, and the irreducible water saturation Swb has major influence on the saturation index n. Therefore, based on the analysis of porosity, irreducible water saturation and pore structure index, the saturation model with variable rock electrical parameters is established by integrating the various influence factors. The results show that the accuracy of this method is higher than that of the traditional Archie formula, which is effective for interpreting complex pore structure sandstone reservoirs.

    Ore Deposits
    Sulfur and Lead Isotopic Compositions of Zebuxia Pb-Zn Deposit in Tibet:Implications for the Sources of Ore-forming Material
    DU Baofeng, ZHANG Rongzhen, YANG Changqing, LI Shanpo, TAN Heyong, ZHU Hongyun
    2022, 36(04):  1138-1145.  DOI: 10.19657/j.geoscience.1000-8527.2022.04.16
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    Zebuxia Pb-Zn deposit in Tibet is located in the western part of the north Gangdean metallogenic belt,and it occurs in the Dianzhong Formation of Paleogene. Based on analysis of the metallogenic geological conditions,this paper studies systematically the composition characteristics of sulfur and lead isotope in the ore minerals and discusses the sources of the ore-forming materials. The results have shown that the composition of sulfur isotope in ore sulfides has a narrow variation range from -0.6‰ to 2.7‰ and a tower distribution features,which indicates relatively concentrate and presents a characteristic of sulfur from magmatic origin,and may be related to the lots of granite porphyry or concealed granite. The lead isotopic composition of ore sulfides is stable and should belong to ordinary lead. According to the μ values range from 9.61 to 10.0 and the tectonic evolution diagram of lead isotopic,it can be concluded that the ore lead mainly derived from upper crust. Combined with regional diagenesis-metallogenic event and geological characteristics of Zebuxia Pb-Zn deposit,the ore-forming materials probably came from the magma formed by partial melting of the upper crust in the period of main collisional setting in Tibetan orogenic belt.

    Age-dating of Sulfide Re-Os in Quartz Vein-type Copper Deposits in Longwei Area, Guangxi and Its Significance
    FU Song, LI Shehong, MA Wenen, JIANG Chao, XIE Zhuolin, WU Jinming, HU Xuhan, ZHANG Zitong
    2022, 36(04):  1146-1154.  DOI: 10.19657/j.geoscience.1000-8527.2022.04.17
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    There are a large number of quartz vein-type copper deposits exposed in northwest Dayaoshan, Guang- xi,but there is a lack of research on the age of related mineral deposits. To solve this problem, the paper selects pyrite and chalcopyrite in quartz vein-type copper deposits in Jinxiu Longwei area for Re-Os isotopic age-dating research. It is concluded that the isochron age of pyrite is (417±25) Ma (MSWD=0.92), which belongs to Caledonian period; the isochron age of chalcopyrite is (243±18) Ma (MSWD=0.45), which belongs to Indosinian period. Pyrite crystallization is obviously earlier than chalcopyrite, and whether there are metallogenic events in Caledonian period needs further study. In combination with rock mineralogical analysis, we think that the mineralization in the copper deposits in Longwei area experienced the processes of pyrite crystallization, pyrite fragmentation and copper-bearing hydrothermal solution filling and metasomatism in Indosinian period, and finally consolidated into mine. The metallogenic time of copper deposits in Longwei area was determined in the research, which provided evidence for the existence of metallogenic hydrothermal event in Indosinian period in the northwest of Dayaoshan.

    Geochemistry and Water Resources
    Genesis and Geological Significance of Late Archean Syeno-monzogranite in Western Shandong Province
    YANG Fan, CHEN Yuelong, YU Yang
    2022, 36(04):  1155-1172.  DOI: 10.19657/j.geoscience.1000-8527.2022.04.18
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    The Western Shandong is located in the east of North China Craton, which is an important area to study the Archean evolution.Petrology, geochemistry and zircon U-Pb dating and Hf isotopic composition were studied on the syeno-monzogranite in the southwest of Western Shandong Province.The syeno-monzogranite is characterized by calc-alkaline and peraluminous affinities.Zircon U-Pb dating shows that the syeno-monzogra-nite emplaced at~2 540 Ma to~2 530 Ma.Zircon Hf isotopic compositions show that they were primarily molten by TTG rocks of~2.70 Ga, and there is recycled ancient crustal component. The mixing calculation results under constraints of isotopic and trace element compositions confirm that the primary magma of syeno-monzogranite is composed of the mixing of 97% of the juvenile TTG crustal material after partial melting and 3% of metamorphic supracrustal rocks after partial melting.Combined with previous studies, we propose that the syeno-monzogranite was formed in an extensional tectonic environment.The late Neoarchean magmatism in Western Shandong was related to slab rollback.The upwelling of asthenosphere caused by the rollback provided heat source for the formation of this group of rocks.

    Geochemical Characteristics and Source Analysis of Heavy Metals in Soils of Eastern Yinan, Shandong Province
    LIU Tong, LIU Chuanpeng, KANG Pengyu, ZHAO Xiufang, DENG Jun, WANG Kaikai
    2022, 36(04):  1173-1182.  DOI: 10.19657/j.geoscience.1000-8527.2022.04.19
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    In order to present the status of soil heavy metal pollution in Yinan County, Shandong Province, 4,779 surface soil samples were collected systematically in this area, and the concentration of Cd, Hg, Pb, As, Cr, Ni, Cu, Zn and pH value were analyzed. The geochemical characteristics of heavy metals and possible sources have been discussed by geostatistics, multivariate statistics, spatial analysis and other analysis methods. The results show that the Hg mean value in soil is slightly higher than the background value of surface soil in Linyi city, and the respective mean values of the other seven elements are equivalent to that of Linyi. Compared with the screening value of GB 15618—2018 (soil environmental quality risk control standard for soil contamination of agricultural land), the concentration over-standard rate of eight heavy metal elements in the research area is low. But the exceeding standard multiple of the maximum value is large, that shows local point and small pieces are seriously polluted. The concentration of 8 kinds of elements in the research area shows a three-step decline from west to east. The high concentration of Cd, Pb, Zn and As in the soil are mainly controlled by natu-ral source, parent rocks, superimposed different degrees of industrial and mining transportation and agricultural activities. Cr and Ni are almost completely controlled by parent rocks. Hg and Cu are controlled mainly by the mining and smelting activities of Yinan Jinchang and Tongjing gold mine, followed by industrial and traffic emissions, agricultural manure and pesticide application.

    Stable Isotope Characteristics of Geothermal Water and Calculation of Geothermal Reservoir Temperature in the Erdaoqiao Area of Kangding in Sichuan Province
    JIANG Zhe, ZHOU Xun, CHEN Binghua, TAO Guangbin, LI Zhuang, CAO Ruwen, SUI Liai
    2022, 36(04):  1183-1192.  DOI: 10.19657/j.geoscience.1000-8527.2022.04.20
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    In order to study the stable isotope characteristics of geothermal water and geothermal reservoir temperature in the Erdaoqiao area near Kangding in Sichuan, five hot springs including the Erdaoqiao hot springs (SC107 and SC107-2), Kangbarenjia hot spring (SC107-3), the flowing hot water well (SC107-4) and spouting hot water well (SC107-5) are investigated. The Yalagou fault and the Yala river valley control the occurrence of the hot springs in the study area. The water temperature of the hot springs in the study area ranges from 33.2 ℃ to 46 ℃, and pH value, from 6 to 6.5. The hot springs are of medium-low temperature. The stable isotope compositions of hydrogen and oxygen of the hot springs indicate that the hot water in the study area is of meteoric origin. Based on the altitude effect and temperature effect, the elevations of the recharge areas of the hot springs are estimated to be about 3 000-4 500 m, and the temperature of the recharge areas range from -3.5 ℃ to -0.3 ℃, indicating that the hot springs may be recharged partly by snow-melting water. The Na-K-Mg triangular diagram shows that the hot water in the study area is the unmature water, so it is impossible to calculate the temperature of geothermal reservoirs with the cation geothermometry. The temperature of the geothermal reservoir in the study area ranges from 65 ℃ to 75 ℃ by using the SiO2 geothermometry, multi-mineral saturation index method and Fix-Al method. The hot springs in the study area are recharged by precipitation and snow-melting water at the eastern part of the Paoma mountain and the western part of the Nongge mountain. The groundwater flows along the Daxue mountain-Nongge mountain fault and the Paoma mountain fault and undergoes a deep circulation. After heated by heat flow, the thermal groundwater rises and emerges as hot springs in the Yala River valley and near the Yalagou fault.