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    26 December 2019, Volume 33 Issue 06
    Petroleum Geology
    Distribution and Application of Nitrogen and Oxygen Containing Compounds in the Saline Lacustrine Oils from the Dongpu Sag
    LI Sumei, XU Tianwu, SHI Quan, ZHANG Yunxian, WU Jianxun, KE Changwei
    2019, 33(06):  1137-1150.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.01
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    Heteroatomic compounds in saline lacustrine in the Dongpu Sag are weakly documented. ESI FT-ICR MS combined with GC/MS were utilized to reveal oxygen and nitrogen compounds in the saline lacustrine oils and source rocks in the sag. Abundant NO compounds were detected and dominated by N1, O1 and O2 class species. It was observed that the relative abundance of the N1 and O1 species increased with increasing maturity, while the contents of O2 species decreased with increasing maturity. It was also observed that there is an apparent increase in the condensation degree and a decrease in the carbon number of the N1, O1 and O2 species with increasing of maturity. Several indices including DB15+/DBE14--N1 having a good relationship with calculated vitrinite reflection (Rc). Oil-oil and oil-source rock correlations based on-ESI FT-ICR MS showed that, the majority of the saline lacustrine oils in the northern Dongpu Depression was sourced from the relatively mature source rocks. It was proved that nitrogen and oxygen containing compounds have a good application prospect in maturity evaluation, source rock and hydrocarbon migration tracing.

    Tectonic Sedimentology Characteristics of Continental Rift Basin: Case Study from Fulongquan Fault Depression of Songliao Basin
    WANG Hongyu, LI Ruilei, ZHU Jianfeng, XU Wen
    2019, 33(06):  1151-1162.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.02
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    Tectonic sedimentology not only concerns with the controlling effects of tectonic background conditions on the basin’s formation and evolution, but also the feedback relationship between tectonism and sedimentation in the basins. Evolution of continental rift basin is often accompanied by frequent tectonic activities and complex sedimentation processes. Tectonic sedimentology can reveal the characteristics of complex tectonic-sedimentary evolution of continental rift basins. Based on seismic, logging and regional geotectonic data, this work studied the structural and sedimentary evolution of the Fulongquan fault depression in the Songliao Basin. We also analyzed the feedback relationship between tectonism and sedimentation. Consequently, the sedimentary evolution regularities in the half-graben lacustrine basin and its controlling factors were discussed. The study shows that during the evolution of Fulongquan fault depression, volcanism had likely significant effects on the basin shape in the initial rifting phase. Distribution features and growth rate of the boundary faults played a primary role in the evolution of the basin configuration. With the stable paleoclimate environment during the rifting period, tectonics is the primary controlling factor of the stratigraphic sequence and sedimentary characteristics of the lacustrine rift basin development. The fault development features determined the ancient basin landform, which further affected the types and distribution patterns of basin sedimentary system. The regional tectonic uplift and fault block tilting are the main factors of the unconformity development in the half-graben basin.

    Sandbody Type and Distribution Characteristics of Shallow-Water Delta in Shaximiao Formation, Xinchang Gas Field, West Sichuan
    GAO Yang, HU Xiangyang, ZENG Daqian, ZHAO Xiangyuan, JIA Ying, YU Qingyan, WANG Yongfei
    2019, 33(06):  1163-1173.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.03
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    Reservoir heterogeneity is commonly determined by sandbody type and distribution characteristics. Sandbody sedimentary processes can be reflected by vertical sequences, while its spatial distribution can be described by comprehensive logging and seismic survey. In shallow-water delta plain of the Shaximiao Formation, trunk distributary channel (vertical accretion), secondary channel (lateral accretion/aggradation) and the overbank sandbody are developed. Proximal distributary channel (lateral accretion), distal distributary channel (aggradation), estuary bar (progradation) and the sheet sand are developed in the deltaic front. Trunk channels in the delta plain are commonly thicker than 10 m and 600 to 1,800 m wide. The sandbodies can be vertically stacked and laterally stacked in an equal horizontal level, exhibiting a blanket-shaped distribution. Secondary channel sandbodies are mostly located at the lateral edge of the channel and distributed sporadically due to the cutting, with an average thickness of 7.5 m and poor physical properties. Proximal distributary channels are 4 to 8 m thick and 500 to 1,200 m wide. The sandbodies are vertically stacked (misplaced) and laterally stacked in an unequal horizontal level, exhibiting a belt-shaped distribution. Distal distributary channel is 2.5 to 6 m thick and 200 to 700 m wide, exhibiting a shoelace-shaped or isolated distribution pattern. Estuary bar is less developed and often overprinted by channels. Reservoir heterogeneity in the delta plain lies in its physical property difference of two different types of channel sandbodies, while in the deltaic front lies in the labyrinth distribution of sandbody of different origins.

    Internal Dissolution and Pore Structural Evolution of Oolitic Dolomite
    XIE Shuyun, LEI Lei, JIAO Cunli, HE Zhiliang, BAO Zhengyu, MA Jiayi, ZHANG Dianwei, PENG Shoutao
    2019, 33(06):  1174-1187.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.04
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    Secondary pores formed by dissolution under surface and burial conditions are very important sites for carbonate reservoirs. To explore the pore erosion mechanism and its controlling factors, the dissolution experiments of oolitic dolomite in 0.2% acetic acid environment were carried out with one oolitic column sample. The experimental temperature and pressure were of 40-160 ℃ and 10-50 MPa, respectively. Continuous sampling was conducted to measure the Ca2+ and Mg2+ contents in the solution. Pore images before and after the dissolution reactions were obtained by CT imaging. Fractal and multifractal methods were used to quantify the pore heterogeneity in two-dimensional (2D) and three-dimensional (3D) space. The results show that the [Ca2++ Mg2+] concentration of oolitic dolomite was the lowest at the beginning of the dissolution experiment, and then increased steadily and reached the maximum at 120 ℃ and 40 MPa, and subsequently decreased slowly with the dissolution window from 70 ℃ to 120 ℃. The 2D/3D spatial distribution of micro-pore structure has multifractal characteristics. This implies that the dissolution reduced the irregularity and singularity of the pores. These results are of great theoretical and practical significance to understand the dissolution effect on the pore structures, and the pore dynamic evolution in carbonate reservoirs under near-surface or deep-burial conditions.

    Reservoir Characteristics and Influence Factors of Gravel Sandstone:Case Study of Upper Triassic Karamay Formation in Hongshanzhui Area
    YAO Zongquan, YU Xinghe, YUE Hongxing, , ZHOU Lihua, WANG Jin, GAO Yang
    2019, 33(06):  1188-1198.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.05
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    To search for effective reservoirs, data of the core, reservoir physical properties, thin-section, SEM and mercury test results from the Upper Triassic Karamay reservoirs of Hongshanzui area were compiled and analyzed, and the reservoir features and controlling factors were discussed. The results show that the reservoirs are mainly lithic arkose and feldspathic litharenite, and that the component maturity is low. The controlling factor analysis suggests that the sedimentary elements (matrix content, lithic and formation of gravel sandstone) are the internal reason. The matrix content is inversely related to physical properties, tractive current is better than flooding current, and the debris current is the worst. Diagenesis (compaction, cement, dissolution) is the external reason. Compaction results in poor pore structure of gravel sandstone. Cementation is destructive in both rich-matrix and containing-matrix conditions, but protective in poor-matrix ones. The four kinds of reservoirs were divided based on the characteristics and controlling factors, and the favorable reservoir distributions were plotted. The reservoir property is likely better in the inner zone of the fan delta than the external zone, whereas the plain is the worst.

    Reservoir Pore Structure and Property Characteristics of Lulehe Formation in the Q6 Area, Kunbei Oilfield
    WANG Hongmin, DAN Mengqian, WANG Chunping, ZANG Xinxin, CHEN Jinghua, GUO Delong
    2019, 33(06):  1199-1207.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.06
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    Lulehe Formation (E1+2) is the main hydrocarbon-bearing sequence in Q6 area of Kunbei Oilfield, but the inadequate understanding in the reservoir characteristics (especially pore structure and physical properties) has seriously hindered the oilfield development. Reservoir pore structure and properties characteristics in this area were studied by using the cores, thin sections, scanning electron microscope (SEM), mercury intrusion and experimental analysis, with the aim to clarify the controlling factors of reservoir properties. The Lulehe Formation comprises mainly conglomerate and feldspar-(lithic) sandstones with low composition maturity. Reservoir pore types include primary/secondary pores and fractures, with the primary inter-granular pores accounting for 70.3%. The pore throat is mainly narrow and tubular, and the pore diameter is mainly of 20 μm to 40 μm; According to the shape of mercury intrusion curve, the pore structures are divided into four types (I to IV), and the pore structure is mainly Type II and Type III. Reservoirs in the Lulehe Formation are of ultra-low porosity and low permeability with good pore-permeability correlation. Reservoir properties are controlled by the lithology, sedimentary facies and diagenesis. The reservoir properties of unequal grains and fine conglomerates, distributary channel and estuary dam microfacies are better. Compaction and cementation have worsen the reservoir properties, whereas dissolution and fracture have improved the reservoir properties.

    Development Features and Controlling Factors of Carboniferous-Permian Carbonate Caves in Donglan-Fengshan Area, Guangxi
    XIAO Sha, GAO Zhiqian
    2019, 33(06):  1208-1219.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.07
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    Secondary porosity generated by dissolution of carbonate rocks are high-quality reservoirs for oil and gas, and provide favorable conditions for hydrocarbon accumulation and migration. To study the controlling factors of karst development, we analyzed the Carboniferous-Permian carbonate dissolution characteristics in Donglan-Fengshan area (Guangxi Province). Under the optical microscope, rock types identified include crystalline limestone and granular muddy limestone. The pore types are mainly intergranular dissolved pore, intragranular dissolved pore, intercrystalline pore and micro-fractures. The study shows that the major controlling factors on the cave development in the study area are tectonics, rock-fabrics, fluids properties, climate and paleogeomorphology. Among these factors, tectonics controlled the size of the caves. Larger caves are better developed along/around major structural zones. Moreover, large beds of limestone contribute the basic material for dissolution. Skeletal granular limestone with high mechanical strength can readily develop large caves. Difficulty of dissolution increases when the rocks are more muddy or recrystallized. Acidic fluids, humid climate and karst slope are favorable conditions for karst development in the study area. All in all, tectonics is the prime controlling factor in karstic cave development.

    Geochemical Characteristics of Paleo-fluid in Tight Sandstone from Cretaceous Reservoir in Keshen Large Gas Field, Kuqa Depression
    SUN Kexin, LI Xianqing, WEI Qiang, LIANG Wanle, ZHANG Yachao, LI Jian, XIAO Zhongyao
    2019, 33(06):  1220-1228.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.08
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    To study the geochemical characteristics of paleo-fluids and hydrocarbon charging in tight sandstone reserviors of the Keshen large gas field, we analyzed the fluid inclusion petrography, homogenization temperature, salinity, oil inclusion abundance via quantitative fluorescence technique on the Bashenjiqike Formation sandstone in the gas field. The study shows that there were two generations of hydrocarbon inclusions: bright-blue fluorescence oil inclusions and gray-black gas ones. Homogenization temperatures of coeval aqueous inclusions show two peaks at 130-140 ℃ and 150-160 ℃, with corresponding paleo-salinity of 16%-10% and 12%-4%. This indicates two stages of hydrocarbon fluid filling, in which the high-intensity natural gas was charging since 2.5 Ma. The abundance of oil inclusions ranges from 2.1% to 13.4%, QGF index ranges from 2.2 to 9.6, QGF-E intensity are from 20 pc to 38 pc. These results reveal a weak light-oil filling in the formation of the Keshen large gas field.

    Geological-Geophysical “Gradual Prediction” Method for Up-dip Pinch-out Sandstone of Zhujiang Formation, Huizhou Area, Pearl River Estuary Basin
    RUI Zhifeng, LIN Changsong, GUO Jia, DU Jiayuan, DING Lin, LI Xiao
    2019, 33(06):  1229-1240.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.09
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    Up-dip pinch-out sandstone reservoir is an important rock reservoir type, and its characterization and description is a key to evaluate up-dip pinch-out traps. Within the third-order sequence, which is mainly composed of deltaic front deposition, the geological-geophysical “gradual prediction” method (to describe the up-dip pinch-out deltaic sand-bodies) has great significance to delineate and explore up-dip pinch-out sandstone reservoirs. This method consists of five parts: (1) Based on third-level sequence identification, high resolution sequence stratigraphic division technology is used to establish the high-resolution (fourth-order) sequence stratigraphic framework; (2) Use seismic sedimentologic technology to describe the planar sedimentary facies distributions under high-frequency sequences; (3) Based on geological models, spectral imaging technique is used to delineate the distributions of the pinch-out zone; (4) Facies-controlled reservoir inversion is conducted to (semi)-quantitatively delineate the sand-body pinch-out line; (5) According to different sedimentary characteristics of sand-bodies, a forward modelling is performed to extrapolate the pinch-out lines.

    Hydrocarbon Generation Conditions and Regional Comparison of the Lower Jurassic Kangsu Formation in Washixia Sag, Tarim Basin
    ZHANG He, JIANG Zhenglong, LI Yajun, LIANG Shuang, FU Wenkai
    2019, 33(06):  1241-1251.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.10
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    The Southeast Depression of the Tarim Basin has not seen much breakthrough in oil and gas exploration due to the hydrocarbon source conditions. Currently, the Jurassic Yangye and Kangsu formations have been suggested to have hydrocarbon generation potential. Based on field geological surveys, section survey, sample collection and geochemical test are completed. Combined with the drilling and sample analysis data from the wells Ruocan 1, Ruocan 2 and Qiedi 1, we discuss the lithology, spatial distribution characteristics and geochemical features of the source rock of the Lower Jurassic Kangsu Formation in the Washixia Sag, SE Tarim Basin. The source rocks are mainly dark mudstone and carbonaceous mudstone with a thickness of about 60 to 140 m (25% of the formation). Organic abundance of well Ruocan 1 and Hongliugou Old Coal Mine is relatively high, and the organic carbon contents of dark mudstones and carbonaceous mudstones are 1.2% to 4.4%, and 5.0% to 39.6%, respectively. The types of kerogen are Ⅱ2 to Ⅲ, which are mainly in the low-mature to mature stage. Compared with the sedimentary source rocks in the same period of the basin periphery, hydrocarbon potential of the source rocks in the Washixia Sag is lower than that in the Kuche Depression in the northern Tarim Basin, but higher than that in the Kuzigongsu Section of the Kashi Sag (SW Tarim Basin). Therefore, we consider that the Washixia Sag has higher hydrocarbon potential, especially for the deep concave area southeast of well Ruocan 1, and the piedmont subsag around Hongliugou Old Coal Mine-Qigeleke.

    Shale Gas Enrichment Conditions in the Third Member of Shahejie Formation in Qingshui Subsag, Liaohe Depression
    MAO Junli, ZHANG Jinchuan, DING Jianghui, SHANG Can, CHEN Shijing, SU Zexin
    2019, 33(06):  1252-1262.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.11
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    Controlled by tectonic movements, the shale subsidence-sedimentation center of the Sha 3 member of the Qingshui subsag in western Liaohe depression has a clear NW to SE migration trend. The (semi)-deep lake facies that are under-compensated for sedimentation also migrate synchronously. From the basinal center to land, the sedimentary types of deep lake-semi-deep lake-shallow lake-fan delta were developed during the Sha 3 member deposition in the Qingshui subsag, and the types I, Ⅱ and Ⅲ kerogen were formed, respectively. Accordingly, the brittle mineral (such as quartz and feldspar) contents in the shale increases gradually, while the clay contents decrease. This phenomenon reflects that the sedimentary facies control the organic geochemical conditions and mineral composition of the shale. Under the control of deep-major faults, sedimentary profile of the shale exhibits a wedge shape, which thins toward the west. The TOC gradually decreases from the maximum at the center, and the vitrinite reflectance (Ro) varies from 0.5% to 2.0%. All these geological conditions are favorable for shale oil and gas formation. At the end of the Dongying Formation deposition, the Sha 3 member in the Qingshui subsag has further subsided, and the thermal evolution maturity increases. Under the current burial depth, the shale is generally in the stage of hot mature oil generation. The burial depth can locally reach the highly matured stage and produced a large amount of natural gas. This makes shale gas as the main state 500 m ahead of time, forming a hydrocarbon generation pattern of “gas down and oil up”. The Sha 3 shale is mainly in stage B of the middle diagenetic stage, and a large number of lineated flaky illites occur. When the shale burial depth is over 4,000 meters, the ratio of illite-smectite mixed layer is below 15%. A variety of pore types is developed, and associated with clay minerals such as pyrite and illite. The shale porosity varies from 0.7% to 3.5% and pore diameter (8 nm to 35 nm) accounts for the largest total volume. The high-precision gas content test results show that the gas content of the Sha 3 shale in the Shuangxing 1 well is generally between 1.6 m3/t and 5.44 m3/t. With increasing diagenetic fractures in the shale reservoir, the shale gas content increases continuously. The shale gas content per unit of TOC increases with upwelling depth. Both the total gas and adsorbed gas contents have good linear relationships with TOC, but the increasing rate of total gas content is higher than that of the adsorbed gas. This is closely related to the thermal evolution of organic matter and presence of dissolved natural gas. Organic matter has a variety of types, and oil and gas symbiosis. The shale gas content is high, gas down and oil up, which formed a typical shale gas enrichment model of the Qingshui subsag.

    Classification of Hydrocarbon Accumulation Phases of Yanchang Formation in Southern Ordos Basin
    LIU Runchuan, REN Zhanli, MA Kan, ZHANG Yuanyuan, QI Kai, YU Chunyong, REN Wenbo, YANG Yan
    2019, 33(06):  1263-1274.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.12
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    The timing of hydrocarbon accumulation of Yanchang Formation in the southern Ordos Basin is determined, according to the fluid inclusion characteristics and hydrocarbon generation history of source rock and oil maturity. Characteristics of fluid inclusions (under microscope and UV fluorescence) suggest two generations of hydrocarbon inclusions. The first generation comprises yellow or aquamarine liquid hydrocarbon inclusion under fluorescence microscope. These fluid inclusions are low in abundance, and the accompanied saline inclusions homogenized at 100~110 ℃. The second generation includes mainly gas and liquid hydrocarbon inclusions, the former is colorless or light-yellow under polarized light and bright blue under fluorescence. Its abundance is high, and the accompanied saline inclusions homogenized mainly at 130~140 ℃. Integrated with salinity and density analyses, we suggested a one-phase and two-stage model for the major accumulation of hydrocarbons in the Yanchang Formation. Considering the basin thermal evolution history of southern Ordos basin: the first hydrocarbon charging stage occurred in the middle of Early Cretaceous (ca. 125 ~ 115 Ma), whilst the second stage occurred in the late of Early Cretaceous (ca. 97 ~ 105 Ma). These two oil and gas filling stages indicate that the oil and gas accumulation occurred in the Early Cretaceous.

    Petrology and Ore Deposits
    Geochemistry and Their Implications for Mineralization of Disuga Indosinian Porphyry in Zhongdian, Yunnan, China
    PAN Yanning, DONG Guochen, LI Xuefeng, WANG Peng, SUN Zhuanrong, DONG Pengsheng, LI Huawei
    2019, 33(06):  1275-1285.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.13
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    Disuga Indosinian porphyry, proved as quartz diorite porphyry, is located at the north of the eastern-porphyry belt in Zhongdian island arc. Influenced by subduction of the Ganzi-Litang Ocean, both porphyries from Disuga and Pulang super-large porphyry copper deposit, are products of the same magmatic activity in the late subduction. Studies on major element compositions show that Disuga quartz diorite porphyries contain normal SiO2 but high Al2O3 and alkali (K2O +Na2O) contents. The porphyries are also enriched in large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs).Light and heavy rare earth elements are highly fractionated in these porphyries,and they are enriched in LREEs but depleted in HREEs.Compared with 38 chemical data of Pulang ore-bearing quartz diorite porphyries, Disuga quartz diorite porphyries have lower SiO2 and Y, higher ∑REE and (La/Yb)N ratio, but similar MnO and Al2O3/(CaO+Na2O+K2O) ratio. In diagrams of SiO2-Al2O3/(CaO+Na2O+K2O) and Y-MnO for ore-bearing and baron porphyries, Disuga porphyries data were ploted in the same area as Pulang. In addition, Disuga porphyries have obvious anomalies of geophysical survey, geochemical prospecting and remote sensing images, which can serve as mineralized indicators. The local denudation predicted was less than the porphyry emplacement in depth, which was more favorable to the ore preservation. The above results indicate that Disuga porphyry intrusion has the potential to hold a certain large scale porphyry copper deposit.

    Geochemical Features and Genesis Analysis of the Zhongba Scaly Graphite Deposit in Sichuan Province
    XIA Jinsheng, SUN Li, XIAO Keyan, WANG Junzhu, CHEN Xian, CUI Ning
    2019, 33(06):  1286-1294.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.14
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    The Zhongba scaly graphite deposit, one of the important graphite deposits in China, with a proved reserve of 15.55 million tons, located on the western margin of central Xikang-Yunnan axis. The study on the geological and geochemical features could be used to help define the genesis of the deposit. Through the field and microscopic observation combining with major and trace elements analysis,the graphite ore bodies are hosted in white mica quartz schist of Datian Formation, Huili Group in Pre-Sinian system in the form of layers and lens. The average grade is 12.19%. Big flake graphite (>0.15 mm) occupies 67% of the total graphite while the small to mediate ones occupies 33%. The graphite-bearing metamorphic rock is rich in SiO2 with poor CaO and LOI. The high field strength elements vary little in the ore. Ni/Co value varies from 15.92 to 41.04 indicating oxygen poor or anaerobic environment. The total REE content is relatively high with high differentiation degree. Light REE content is higher than that of HREE with negative Eu and Ce value. The test results of graphite δ13C is from -27.64% to -28.44%, and the average is -28.14%, indicating the causes of graphite is the organic carbon. So, the Zhongba deposit is a regional metamorphic scaly graphite deposit of organic carbon origin.

    Applied Geochemistry
    Reserve Estimation, Spatiotemporal Distribution and Its Influencing Factors of Soil Organic Carbon in Fujian Province, China
    WANG Wenjun
    2019, 33(06):  1295-1305.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.15
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    Based on achievement of multi-purpose regional geochemical survey (1∶250 000) in Fujian pro-vince, reserve estimation and average density of soil organic carbon were calculated in seven different focus using unit soil carbon calculation method. Comparison was made by the computation result above, the second soil census result of Fujian, result of other regions in China, and the result of the typical areas of China. The results showed that the reserve and average density of topsoil(0-0.2 m) organic carbon were 427.5 Mt and 3 446.8 t/km2, respectively. The middle soil (0-1.0 m) was 1 495.0 Mt and 12 052.9 t/km2, respectively. The deep soil (0-1.5 m) was 1 986.8 Mt and 16 017.5 t/km2, respectively. It was higher than the average level in the typical areas of China and had higher organic carbon reserves and carbon density. Furthermore, the average density of soil organic carbon increased with the increase of altitude, and was higher in inland areas than in coastal areas. In recent 30 years, the organic carbon storage of topsoil was decreased. The main influencing factors of topsoil organic carbon density distribution can be consider as geomorphic landscape, climate, vegetation, soil texture, physical and chemical properties of soil, ecosystem stability, human activities, etc.

    Study on Features of Water Soluble Hydrocarbon Components and Carbon-hydrogen Isotopes of Methane in the Kaixinling-Wuli Permafrost Region on the Northern Margin of Qiangtang Area
    WANG Jinshou, LU Zhenquan, WANG Fuchun, CHEN Jing, XUE Wanwen, ZHANG Zhiqing
    2019, 33(06):  1306-1313.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.16
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    Several cold springs bear water soluble alkanes along the concealed faults in the Kaixinling-Wuli permafrost region on the northern margin of Qiangtang area. Based on analyses of the water soluble hydrocarbon components, stable carbon-hydrogen isotopes of methane, the genesis of the water soluble alkanes was studied. The results showed that the methane (CH4) volume fraction ratio in the water soluble hydrocarbon components reached as high as 99.83%-99.96% in the Kaixinling-Wuli permafrost region, accompanied by a small amount of ethane (C2H6), propane (C3H8), trace amounts of ethylene (C2H4) and propylene (C3H6). In water soluble hydrocarbon, methane δ 13CPDB values range in -46.5‰ to -55.1‰ with δDVSMOW values of -281.0‰ to -342.0‰ in the Kaixinling permafrost area. In water soluble hydrocarbon, methane δ 13CPDB values are -47.8‰ to -58.9‰, and δDVSMOW values are -339.0‰ to -346.0‰ in the Wuli permafrost area. These features indicate that in water soluble hydrocarbon, methane is of organic origin, but the gas origin is relatively complex. Methane mainly belongs to microbial gas, secondarily pyrolysis gas, mixed with a small amount of oil-associated gas, discriminated by the genesis diagrams of δ13CCH4-δDCH4 vs. δDCH4 and δ13C1 vs. C1/ (C2+C3). It is inferred that methane is mainly originated from the hydrocarbon gases or sub-microbial gases, decomposed from the organic matters under the action of microorganisms, in connection with the coal-bearing hydrocarbon source rocks in Nayixiong Formation of the Late Permian. Gas condition implies that at depths from 200 to 500 meters, it is conducive to form methane hydrate with microbial gas in this permafrost region.

    The Analysis of Stability and Abnormal Reproducibility of Geochemical Exploration of Natural Gas Hydrate in Qilian Mountain
    ZHOU Yalong, YANG Zhibin, ZHANG Fugui, ZHANG Shunyao, SUN Zhongjun, WANG Huiyan
    2019, 33(06):  1314-1324.  DOI: 10.19657/j.geoscience.1000-8527.2019.06.17
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    Based on the repeated experimental results of geochemical exploration over the known natural gas hydrate of Muli area in Qilian Mountain, the stability and anomaly reoccurrence of soil acid hydrocarbon, top-air, fluorescence spectrum, carbonate and other indexes were studied and discussed. The results prove that although there are some differences in the characteristic values, such as the maximum value of the contents of different geochemical exploration indexes, the data fluctuation characteristics and data structure are relatively consistent. The results of the previous two measurements of top air methane, acid hydrocarbon, fluorescence spectrum and carbonates are related, and the paired T-test shows no obvious difference in data variation of above indexes, while the index data have good stability statistically. Geochemical anomalies of top-air methane, acid hydrocarbon, fluorescence spectrum and other indicators have similar spatial distribution characteristics over known natural gas hydrate mining areas in the study area, which indicates that the geochemical anomalies has good stability and reproducibility, while the abnormal pattern of heavy hydrocarbon of top-air and the variation of abnormal intensity of carbonates reflects that the anomalies has better reoccurrence with worse stability.