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    23 June 2019, Volume 33 Issue 03
    Ore Deposits and Petrology
    Calcite Sm-Nd Isochron Age of the Dashui Gold Deposit in West Qinling Orogenic Belt and Its Implications
    LI Linji, LI Tangji, WANG Dan
    2019, 33(03):  469-475.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.01
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    The Dashui gold deposit is located at the southern margin of West Qinling orogenic belt. Gold mine-ralization has close relationship with silicification, decarbonation and calcitization. Silicification is mainly chara-cterized by quartz or chalcedony replacing (dolomitic) limestone; residual debris of limestone or dolomitic limestone is commonly observed in quartz; natural gold exists in quartz grains or fractures, which indicate that the silicification, carbonation, and gold mineralization are synchronous. The veinlet-mesh-vein gold-bearing calcites of the ore-forming stage are mainly distributed at the edge of the silicification-decarbonation alteration zone or near the fractures, indicating the crystallization of calcite is coeval with the gold mineralization or a little later. The Sm-Nd isotopic system of eight gold-bearing calcite samples from this deposit was studied. The 147Sm/144Nd values and 143Nd/144Nd values of these calcites range from 0.069 489 to 2.243 873, and 0.511 673 to 0.514 369, respectively. All calcite samples fell on one line and yielded a precise Sm-Nd isochron age of (189.4±1.4) Ma with a MSWD=1.8. This age can represent the time of gold mineralization of the Dashui gold deposit. In addition, the mineralization age of the Dashui gold deposit is coincident with the intrusion of granodiorite magma, which is related to the Qinling Orogeny. What's more, rare earth elements geochemistry, Co/Ni ratios of pyrite and H-O isotope of calcite from previous studies also suggest that the source of ore-forming materials has close relationship with this granodiorite magmatism. Thus, the calcite Sm-Nd isochron age presented in this study provides chronological evidence to the argument that the gold mineralization of the Dashui gold deposit has a genetic relationship with the granodiorite magmatism.

    Formation Environment and Genesis of the Lifang Barite Deposit in Fujian Province
    LUO Kun, LI Dungpeng, WANG Liyuan, XIAO Aifang, KONG Lingtian, WANG Zhiqi
    2019, 33(03):  476-486.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.02
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    For the purpose of understanding the genesis of the Lifang barite deposit in Fujian Province and the source of its metallogenic materials, this thesis has conducted a study on the main elements, rare earth elements, trace elements and sulfur isotope of the barite single mineral in the deposit. The results indicate that the barite single mineral is characterized by rich Al2O3, SiO2 and TFe2O3, relatively low ΣREE with rich LREE, a positive δEu anomaly and a negative δCe anomaly, and rich Ba, Rb ,Nb, Th, P and deficient K and Zr. The average of all midpiece δ34S is greater than 32.6‰, and only one main peak is displayed in the histogram. The genetic diagram of the barite single mineral, ΣREE-La/Yb respectively indicate barite single mineral form from hydrothermal sedimentation and sedimentary rocks contributing to most of its barium content. The ratios of SiO2/Al2O3, MnO/TFe2O3, U/Th, etc.indicate alkalescent-alkaline oxidizing environment. The ratios of (La/Ce)N, Al/(Al+Fe), etc. indicate continental margin environment. This thesis concludes that the Lifang barite deposit was formed by hydrothermal sedimentation in a continental margin environment with sedimentary rocks contributing to most of its barium content and Cambrian seawater being the major source of sulfur; this formation process is accompanied by a relatively large terrigenous input.

    Zircon U-Pb Age,Geochemical and Tectonic Significance of Early Cretaceous Namtso Rhyolite in Tibet,China
    WEI Yongfeng, XIAO Qianru, LI Youbo, LUO Wei, RAN Jie, LIN Meiying
    2019, 33(03):  487-500.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.03
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    The Namtso rhyolite is located in the southern margin of the North Gangdese Belt. It belongs to the Woronggou Formation and overlies the Middle-Late Jurassic Lagongtang Formation along an angular unconformity.The rhyolite is LA-ICP-MS zircon U-Pb dated to be Early Cretaceous(120-112 Ma). The rocks are characterized by high SiO2, Al2O3 and K2O, and low TiO2, MgO and CaO, A/CNK=0.94-1.91(average 1.16). The rhyolite is high-K calc-alkaline and peraluminous. The chondrite-normalized patterns show a gently right-inclining ((La/Yb)N=1.49 to 11.08) “V” shape and weakly negative Eu anomalies(δEu= 0.12 to 0.55). The elements of Rb, K, Th, Ta, Ce, Zr and Hf are enriched, while Nb and Ba, Sr, P and Ti are strongly depleted, suggesting a crustal inheritance. The geochemistry can be compared with the Duoni Group felsic volcanic rocks. The Namtso rhyolite does not have the characteristics of typical island arc rhyolites, but mimics those of collisional felsic volcanic rocks. We considered that during the middle Early Cretaceous(ca.120 Ma), a major tectonic event may have occurred in the North Gangdese Belt, i.e., subduction of Neo-Tethys Ocean in the Bangong Lake and Nujiang River region had ended, and the continent-continent collision in the Gangdese and Qiangtang region had begun. During the collision, the lower crust may have thickened and partially melted, forming the Namtso rhyolite.

    Geochemical Characteristics and Tectonic Significance of Ordovician Intrusions in Bayanbulak, Xinjiang,China
    LIU Xiang, GONG Xiaoping, LIU Yangyang, WANG Zhe, FENG Jun, LIU Shijie, HAN Bingjun, QI Rui
    2019, 33(03):  501-513.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.04
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    The Bayinbuluk area is located in the multi-stage composite continental arc in the Middle Tianshan Complex. Our study found that the Ordovician intrusions include mainly quartz diorite, granodiorite and monzogranite. Zircon U-Pb dating yielded Middle Ordovician ages (462.7±6.2 Ma, 463.4±2.8 Ma, 471.5±5.9 Ma) intrusions, and geochemical analysis shows metaluminous and calc-alkaline affinities. Chondrite-normalized REE patterns show clear right-inclining pattern and negative Eu anomalies. Trace element analysis results show large ion lithophile element (LILE) enrichments and high field strength element (HFSE) depletions. Geochemical characteristics indicate that the intrusions were formed in a subduction-collisional setting, and the magma may have been derived from a crust-mantle mixed source. Comprehensive analysis suggests that the South Tianshan ocean basin started to subduct northward in the early Middle Ordovician, which may have been related to the regional dextral movement. Magmatism in the Middle Tianshan shows a gradual eastward migration and expansion.

    Geochemistry
    Geochemical Characteristics and Influence Factors of Lead in the Soils of the Pearl River Delta Plain, China
    GUO Siyu, HOU Qingye, ZONG Qingxia, TANG Zhimin, WEI Bin, PANG Shiqi
    2019, 33(03):  514-524.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.05
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    This paper took the Pearl River Delta plain in Guangdong Province as the study area. We collected 102 surface soil samples from paddy fields and analyzed their physico-chemical parameters and Pb geochemical fractions.The main aims were to investigate the geochemical characteristics and to discuss the influence factors of total Pb contents and mobility fraction Pb contents in the soils. The results showed that the average value of total Pb contents in the soils was 46.47 mg/kg, which was slightly higher than the background value of soil Pb in Guangdong Province (36 mg/kg), indicating a certain accumulation trend. From northwest land sedimentary environment to south sea-land interaction sedimentary environment, the elements contents in the soils normally increased. Soil Pb were mainly composed of residual and Fe-Mn oxidation fraction with weak mobility. The factors affecting total Pb contents in the soils are aluminum oxide(Al2O3),potassium oxide (K2O),thallium(Tl),molybdenum(Mo). The factors controlling the mobility fraction of Pb are total Pb contents, pH, organic matter contents, cation exchange capacity (CEC), phosphorus(P), iron oxide(TFe2O3) and manganese (Mn). Among these factors, pH is the most important factor controlling the mobility of soil Pb.

    Arsenic Input Flux in Farmland Soil of 9 Counties in the Middle East of Guangxi
    CHEN Xue, YANG Zhongfang, CHEN Yuelong, YANG Qiong, WANG Lei, WEI Xueji
    2019, 33(03):  525-534.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.06
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    The input fluxes of As in farmland soil of 9 counties in the middle east of Guangxi were studied.By integrating various factors, the authors took the atmospheric wet and dry depositions, fertilizers and irrigation water as As inputs.Calculation results show that the atmospheric wet and dry depositions and the fertilizers fluxes are about the same, which of the average fluxes are 9.92 g/(hm2·a) and 7.83 g/(hm2·a), while the irrigation water flux is much higher,which of the average flux is 14.98/g/(hm2·a).They contribute 30.31%, 23.92% and 45.77% of As in soil respectively. Their proportions are somewhat different among 9 counties of the study area.The irrigation and fertilizers in 6 counties are dominant, and the proportion of atmospheric wet and dry depositions is higher in the other 3 counties.Therefore, the irrigations is the main input way of As in the study area.Adequate attention should be paid to the water quality controlling.Ignoring the outputs, it is estimated that the As content in farmland soil may increase by 0.01 mg/kg due to the present average flux of arsenic.The proportion of annual As increment in farmland soil is very small, so outside-sourced As will cause little change in As distribution in soil in a short time.The soil of the study area has low pH value and high iron oxides content, so the bioavailability of As is low when it is imported into farmland soil.

    Structural Geology and Stratigraphy
    Lithology of Likou Group from Around the Anhui-Jiangxi Boundary, South China: Implications for Post-orogenic Collapse of Supercontinent Breakup
    ZENG Yan, YU Xinqi, LIU Xiu, HU Jun, LIU Mengyan, WANG Zishen
    2019, 33(03):  535-550.  DOI: 10.19657/j.geoscience.1000-8527.2019.002
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    The Likou Group comprises a volcanic-sedimentary succession distributed to the north of the Qimen-Qiankou-Shexian fault zone near the boundary between Anhui and Jiangxi, South China. It is the upper part of Neoproterozoic epimetamorphic basement in the eastern part of the Jiangnan orogen. Interbedded basalt from the Dengjia and Pulin formations have Continental Arc Basalt (CAB)-like REE distribution ((La/Yb)N=2.97-4.47) and trace-element patterns. The Dengjia and Pulin Formation basalts have Rittmann Index of 0.029-2.203 and 4.304-6.538, respectively, suggesting comagmatic products of different stages. The Dengjia, Pulin and Xiao’anli formations of the Likou Group have clear boundary surfaces and probably continuous rock formation, and therefore can be merged into one formation (still named Dengjia Formation). The Pulin and Xiao’anli formations represent the upper and top parts of the newly-defined Dengjia Formation, respectively. Basalt from the Dengjia Formation is dated to be (804.2±7.4) Ma by high-precision LA-ICP-MS U-Pb zircon dating. The zircons from interbedded basalt have initial176Hf/177Hf ratios of 0.281,837 to 0.282,076, εHf(t) of -15.9 to -7.0, and two-stage Hf model ages of 2.16 to 2.68 Ga, indicating a magmatic source with significant ancient crustal input. The results may reflect that the intermediate stage of rifting had ended, and the magmatism had progressed to the earth surface. Sedimentary characteristics of the Likou Group indicate that the Neoproterozoic rift basin in the eastern part of the Jiangnan orogen was a passive rift basin, which was controlled mainly by subduction rollback, and the Rodinia plume activities may have also made significant impact to the tectonic evolution. We suggest that the rifting was resulted from the interactions between plate subduction and Rodinia superplume.

    Structural Features of Late Mesozoic Kouquan Fault Zone, Northern Shanxi Province
    LUO Xiaohua, YANG Minghui, JIA Chunyang, LI Zhanyuan, LEI Zhibin, ZHANG Shaohua
    2019, 33(03):  551-560.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.08
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    Kouquan Fault Zone is located in the western part of the Trans-North China Orogen, North China Craton, and shows a unique thrusting style and complex Late Mesozoic structural evolution. This study focuses on the Late Mesozoic structural segmentation and mechanism, based on field observation, structural modeling and apatite fission track dating. The results show that: (1) Kouquan Fault Zone nappe thrusted from southeast to northwest, and the displacement is stronger in the south than in the north of the fault zone. The hanging-wall comprises Archaean gneiss, while the footwall comprises Cambro-Ordovician, Permo-Carboniferous and Jurassic sequences. (2) Kouquan Fault Zone is featured by segmentation and the main structural style is a typical triangular zone with over two sets of décollement sequences. The lower décollement sequence is Archaean, Cambro-Ordovician and Carboniferous, but the upper décollement sequence is the Lower Cambrian Mantou-Maozhuang Group or the underlying Archaean gneiss. (3) The formation of Kouquan Fault Zone may be associated with the NW-directed compression led by the Late Jurassic subduction of the Izanagi plate. Apatite fission-track simulation suggests that the earliest thrusting of Kouquan Fault Zone occurred in the Late Jurassic to Early Cretaceous (147.1±6.0 Ma).

    Genesis and Tectonic Significance of Quartz Sandstones in the Southern Subzone of Tethyan Himalayas: A Case Study on the Paleocene Jidula Formation in Gamba Area, Southern Tibet
    LIU Qingshan, WEI Yushuai, ZHANG Baosen, PAN Wanying
    2019, 33(03):  561-573.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.09
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    The Tethyan Himalayas is the main tectonic unit of the northern Indian passive margin. Compared to other similar tectonic units, there are many suites of special quartz sandstones, implying that the terrigenous supply capacity had changed overtime. Tectonic setting and significance of these quartz sandstones are yet to be clear. In this paper, the quartz sandstones (Jidula Formation) in Gamba of the Tethyan Himalayas were analyzed for their detrital compositions, paleocurrent, heavy minerals and detrital zircon ages. Sedimentology and provenance characteristics of these quartz sandstones, their formation and tectonic significance were discussed. According to sedimentary facies analysis, in the Early Paleozoic Gamba area belonged to the Indian passive continental margin of the Neotethys. Littoral facies dominate and show a change from shallow shelf to continental facies. Sandstone lithofacies suggest that the terrigenous clastic material of the Jidula Formation comprises mainly quartz sandstone with very high maturity, and the paleocurrent direction was near NNE. Detrital zircon dating results suggest that the detrital zircon ages of the Jidula Formation coincide with those from the Early Cretaceous Degan Plateau. It is suggested that the formation of quartz sandstones (Jidula Formation) was led by the sudden increase of terrigenous clastic supply in the northern Indian plate margin and the tectonic uplift of the passive continental margin, which was in turn caused mainly by the formation of the Deccan large igneous province (LIP). We concluded that the origin of the quartz sandstones is related to the reactivation of stable cratons caused by the up-doming of the Deccan LIP on the northern Indian plate margin.

    Study of the Radiolarian Fauna from Kaduo in Zedang of Southern Tibet and the Geological Significance
    MA Xuesong, LI Guobiao
    2019, 33(03):  574-586.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.10
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    The Yarlung-Zangbo Ophiolite Zone has long been considered as the lithospheric residual of Neo-Tethys, jointly with the marine stratum within the Yarlung-Zangbo Suture Zone, recorded the evolution of the Neo-Tethys and the collision between India Plate and Eurasian Plate. Moderate preserved Mesozoic radiolarian fossils have been found from the Kaduo Chert, near the southwest of the Zedang of southern Tibet. And 39 radiolarian species belonging to 31 genera have been identified preliminary. Four radiolarian assemblages have been recognized as follows in ascending: Alievium longispineum-Transhsuum maxwelli assemblages (Late Bathonian-Early Callovian), Hsuum maxwelli-Triactoma mexicana assemblages (Late Callovian-Oxfordian), Holocryptocapsa hindei-Hiscocapsa grutterinki assemblages (Late Barremian-Early Aptian) and Hemicryptocapsa polyhedra-Obeliscoites giganteus assemblages (Late Albian-Cenomanian). The radiolarian assemblages in the Kaduo chert can provide an important micropaleontological evidence for the formation time constrain on the Zedang ophiolite and the evolution of the Neo-Tethys Ocean.

    Characteristics and Origin of Oncolite from Changping Formation in the Series 2 of Cambrian in Western Beijing
    BAI Ying, LUO Ping, LIU Wei, XU Anna, ZHAO Zhenyu, WANG Shan, GONG Jiyao
    2019, 33(03):  587-597.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.11
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    Oncolite, a main kind of microbialite, has long attracted much scientific attention. Until now, uncertainties remain on the distribution model, sedimentary environment, microbial characteristics and formation mechanisms of oncolite. In the western suburbs of Beijing, the Dingjiatan section contains well-preserved Cambrian sequences. Controlled by the 4th order sea-level change and hydrodynamic characteristics, the EHST of Changping Formation, Cambrian deposits in subtidal-lagoon environments, including three sets of oncolites with different shapes. The first set of mm-scale oncolite is scattered in the lower part of EHST, whose envelope contains plenty of mud debris, sand-/bio-clastics. The second set of (sub-)cm-scale oncolite concentrates in the middle part of EHST. Axiolitic oncolite has obvious core, and its envelope includes light/bacterial/bioclastic/coated lamina. The third set of cm-scale oncolite is distributed in the upper central part of EHST, with obvious core and envelope of many light lamina and few bacterial lamina. Microscopic identification results show that the oncolite envelope consists of light and dark lamina. Their different ultra-/micro-structures stand for various forms of interactions between microbial mats and sedimentary environment. Through studying the formation environment, this microbial set is related to the biological extinction, although that may not have been decisive.

    Milankovitch Cycles of the Changxing Formation of Upper Permian in Western Guizhou Province
    WANG Yan, YUAN Xuexu, GUO Yinghai, SHEN Yulin
    2019, 33(03):  598-603.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.12
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    Spectral analysis was conducted on the natural gamma ray logging data from the Changxing Formation of the wells Pan 1, Weining 1, Nayong 1 and Zhijin 1 in western Guizhou. Major Milankovitch sedimentary cycles are identified, and the stable periods are extracted using the filtering method for the contrasts of well connection. The results show good correlations between spectral peaks and Milankovitch cycles, and it is suggested that the Changxing Formation in the study area has preserved the eccentricity cycle of 123 ka, the obliquity cycles of 45 ka and 35.6 ka, and the precession cycles of 21.2 ka and 17.7 ka. The average stratigraphic thickness of all cycles is 4.59 to 5.73 m, 1.37 to 2.15 m and 0.66 to 0.98 m, respectively. The short eccentricity cycle curve of each well shows that about 18 eccentricity cycles are recorded in the Changxing Formation, which indicate that the diagenesis of the Changxing Formation can be estimated as 2.21 Ma. Based on the well connection contrasts of the short eccentricity cycle layers and the calculated sedimentation rate, it is found that the isochronic contrast effect of the marine facies marker sequence is distinct, which reflects rapid regional transgression, while the change of sedimentation rate may be affected by the sea-level change and the sedimentary supply.

    Sedimentary Environment and Controlling Factors of the Cambrian Xinji Formation, Lushan Area, Western Henan
    ZHENG Deshun, YANG Dongliang, YANG Wentao, LI Yu
    2019, 33(03):  604-614.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.13
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    The Early Cambrian sedimentary and tectonic paleogeographic evolution of the southern North China margin has been a research focus in geoscience. This paper focuses on the Cambrian Xinji Formation (Shimengou Lushan, western Henan) to analyze the sedimentary environment and its controlling factors via conventional sedimentological techniques (such as field profile observation), microscopic observations and grain-size analysis. We found that the Xinji Formation in the study area comprises a marine terrigenous clastic sequence, and the lithologies are featured by the transitional deposition from conglomerate to sandstone and mudstone. Sedimentary environment of the Xinji Formation is characterized by shallow marine gravity flow to tidal flat and lagoon and washover fans affected by storms. The grain-size probability cumulative curve of the Xinji Formation sandstones is characterized by steeply-dipping segment (1 or 2 segments) pattern and steeply-dipping abrupt change pattern, and the C-M plot shows that the hydrodynamic mechanism comprises both traction and gravity flow. Sedimentary environment of the Xinji Formation is closely related to the paleogeography, paleostructure, paleolatitude, and paleoclimate of the southern North China margin, which included an active continental margin, low latitude, rising global sea level, and medium to relatively high temperatures. The study of sedimentary environment and its controlling factors of the Xinji Formation has important significance for understanding the evolution of Early Cambrian sedimentary basins and lithofacies paleogeography of the southern North China margin.

    Geochemical Characteristics and Paleoclimatic Implications of the Upper Permian and Middle-Lower Triassic Strata in Southern Ordos Basin
    TAN Cong, YUAN Xuanjun, YU Bingsong, LIU Ce, LI Wen, Cui Jingwei
    2019, 33(03):  615-628.  DOI: 10.19657/j.geoscience.1000-8527.2019.001
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    To explore the paleoclimate evolution of the terrestrial Permian-Triassic system, mudstone samples were collected from the Permian Shiqianfeng Formation (P3s) and the Triassic Liujiagou (T1l), Heshanggou (T1h) and Zhifang (T2z) formations in the Shichuanhe section of Tongchuan (Shaanxi Province) in the southern Ordos Basin. The samples were analyzed for their mineralogy, petrology, and geochemistry. The paleosalinity, paleoredox and paleoclimate evolution were studied by the major-trace elements, total organic carbon (TOC), and carbon and oxygen isotopes. It is shown that the geochemical and carbon-oxygen isotope compositions near the P/T boundary had changed greatly. Fluctuation of climatic and environmental chemical indicators reflects the paleo-climatic/-environmental changes in the Ordos Basin from the Late Permian to the Middle-Late Triassic. It is shown that the Shiqianfeng Formation was deposited in a fluvial-deltaic environment that was relatively reduced, and that the paleoclimate was relatively warm and humid. The purplish-red clastic rock of the Lower Triassic Liujiagou and Heshanggou formations were deposited in shallow water, hot and arid fluvial-deltaic environment under strongly oxidizing conditions.During the deposition of the Middle-Triassic Zhifang Formation, the water level rose and chemical transfer was enhanced, and the depositional environment may have been semi-arid/-humid and reducing. Carbon isotope evidence shows that the P/T boundary in the terrestrial Ordos basin has significant negative δ13CPDB features, which are comparable with the global marine P/T boundary. This indicates that major geological events such as abrupt climate changes and mass extinctions were also recorded in the North China continental P/T boundary, consistent with the marine stratigraphic record.

    Petroleum Geology
    Characteristics and Significance of Organic Sulfur Compounds in the Crude Oils from the Dongpu Sag
    XU Tianwu, LI Sumei, ZHANG Hongan, ZHANG Yunxian, WU Jianxun, SHI Quan, CHEN Xiangfei, JI Hong, WAN Zhonghua
    2019, 33(03):  629-642.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.15
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    Heteroatomic compounds in saline lacustrine in the Dongpu Sag are weakly documented. ESI FT-ICR MS combined with GC/MS were utilized to reveal sulfur compounds in the saline and freshwater lacustrine oils in the sag. Abundant sulfur compounds were detected and dominated by S1 and O1S1 class species. It was observed that the saline lacustrine oils are relatively enriched in S1 species while the freshwater lacustrine oils are abundant in O1S1 species, indicating the ratio of O1S1/S1 is indicative of organofacies of source rocks. The saline lacustrine immature oils are composed of mainly sulfur compounds with carbon number to be C27-C35 and C40,which is coincide with the carbon number of steroids, hopanoids and β-carotane, suggesting micro-organisms such as algas and bacterium as well as chromatophore to be important organic matter inputs when source rocks deposited. With increasing maturity, the DBE (double bond equivalent) values increased whereas the carbon number range of alkyl substitued decreased, and several relevant parameters were suggested to be maturity indicative. The saline immature oils are dominated by sulfur compounds with relatively low thermal stability, suggesting degradation of S-containing kerogen and/or sulfurous macromolecule under low temperature is one of the most important genetic mechanisms of immature oils in the area studied.

    Controls of the Degree of Order of Dolomite on the Physical Properties of Lacustrine-facies Diamictitic Carbonate Reservoirs:A Case Study of the Yingxi Area in the Qaidam Basin
    DU Jiangmin, WANG Qingchun, NIE Wancai, LUO Chuanyou, LI Zheng, SHENG Jun
    2019, 33(03):  643-652.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.16
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    To study the physical properties and main controlling factors of the Oligocene lacustrine-facies diamictitic carbonate reservoirs in Yingxi area, we have conducted systemic analyses on the petrology and mineralogy, physical properties, pore structure, degree of order of dolomite, formation mechanism of the disordered dolomite and its influence on the reservoir physical properties. It is suggested that the Oligocene reservoirs in the Yingxi area is mainly of low porosity and ultra-low permeability, and its pore development is mainly controlled by the dolomite content in the rocks. The degree of order of dolomite likely plays an important role in controlling the physical properties of the rocks. Our results also show that: (1) the well-log porosity is positively correlated with the dolomite content of the rocks, but negatively correlated with the clay content; (2) when the dolomite content is 100%, the molecular structure of the ordered dolomite suggests that its porosity should be 13% in the ideal model. In the correlation diagram of the measured porosity (via the helium gas method) versus the dolomite content, most of the data points are distributed near the ideal pattern line; (3) the intercrystal pores above the ideal pattern line are expanded, some are enlarged by the support of clastic particles, and some by weak dissolution; whereas the intercrystal pores below the ideal pattern line are mostly filled with pyrite or other material; (4) a few rock samples have relatively high dolomite content but smaller porosity. They are mainly composed of dolomite with low-/zero-degree of order. With the same dolomite content, the higher the degree of order is, the better developed are the pores.

    Application of Multiscale X-CT Imaging Digital Core Technique on Observing Micro-pore Structure of Carbonate Reservoirs
    SHENG Jun, YANG Xiaojing, LI Gang, XU Li, LI Yanan, WANG Jingru, ZHANG Caiyan, CUI Haidong
    2019, 33(03):  653-661.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.17
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    In this paper, we analyzed two types of core samples from porous carbonate reservoir via X-CT imaging to better constrain their microscopic pore structural features. The two sample types are namely the double porosity medium with fracture development and single porosity medium with no fractures. Three dimensional (3D) digital cores of different levels are established via the multi-scale X-CT scanning imaging technology, using the maximal ball algorithm and the method for pore and throat size correction, and consequently the digital cores nanoscale pore network model in carbonate reservoirs are extracted and established. Finally, the 3D pore network model is used to simulate the reservoir physical parameters, mercury injection curves and the pore and throat distribution curves, and the results are compared with those generated by the conventional high-pressure mercury injection method. The results show that the porosity and permeability parameters obtained by using the digital core technology are smaller than the actual measurements. The simulated mercury injection curves and pore throat distribution curves are in good agreement with those obtained by the laboratory mercury intrusion experiment, demonstrating that this technique is reliable. Digital core technology has clear strengths in directly and quantitatively described the micro-pore structure of carbonate reservoirs.

    Shale Reservoir Characteristics of Cretaceous Madongshan Formation of Well Guye 1 in Liupanshan Basin
    MA Fenghua, PAN Jinli, ZHANG Yong, MA Xiaojuan
    2019, 33(03):  662-671.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.18
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    Shale samples from the Cretaceous Madongshan Formation (Fm.) (Well Guye 1) in the Liupanshan Basin were used for reservoir characterization via core logging, thin section petrography, X-ray diffraction (XRD), scanning electron microscope (SEM) imaging and isothermal adsorption. The results show a variety of lithologic facies, such as shale, argillaceous carbonates, dolomite, carbonate-/dolomite-bearing or calcareous/dolomitic mudstone. In particular, the carbonate-/dolomite-bearing mudstone have higher TOC contents than the other rock types. The shale reservoir, with characterizing low porosity and low permeability of the Madongshan Fm., have a low clay content and relatively high feldspar and carbonate mineral contents. Optical microscopic and SEM petrographic observations reveal four kinds of microfractures (i.e.stratiform, stockwork, dissolution and intergranular fractures) and three kinds of pores (i.e.intergranular, dissolved and intergranular pores). The dissolved pores are filled by carbonaceous material, calcite, dolomite, plagioclase, illite and gypsum. The pore and fracture sizes vary mainly from 2 to 10 μm, and locally from 10 to 33 μm. Isothermal adsorption shows that CH4 adsorption capacity of the Madongshan Fm. shale is between 0.96 and 4.6 m 3/t (average 2.29 m3/t). The Langmuir pressure is between 1.27 and 2.21 MPa (average 1.74 MPa). It is suggested that the Madongshan Fm. shale has a strong gas storage capacity but is difficult to be desorbed. To summarize, the Madongshan Fm. shale is a potential good oil and gas reservoir, characterizing by its abundance of pores and fractures, low poisson ratio, high brittleness, relatively good gas storage ability and readiness in development.

    Optimization of Fracture Layout of Muti-fractured Horizontal Well in Xinchang Gas Field
    BU Tao
    2019, 33(03):  672-679.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.19
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    The Xinchang gas field is a multi-layer tight sandstone gas reservoir with abnormally high pressure and poor reservoir properties. The gas well producing reserves are low. To significantly improve the well production rate, the gas reservoir was mostly developed by fractured-horizontal wells. Therefore, it is important to evaluate the influence of fracture parameters and their combinations on the multi-stage fractured-horizontal wells, and to provide a theoretical basis for the scientific and efficient development of gas reservoirs in the next stage. This work used the Xinchang gas field as an example. By using the numerical simulation method, the effects of fracture parameters on gas well productivity have been studied, including the non-uniform fracture length and its spacing, the scale of fracturing and the number of fractures, the correlations of fracture length and spacing, and the match of fracture angle and spacing. The results show that the U-mode fracture length layout is optimal for multi-fractured horizontal wells. The uniform fracture spacing is better than the non-uniform one. Less fractures but longer fracture lengths have higher economic benefits. When the fracture spacing is 0.67-1 times of fracture length, it’s beneficial to improve the productivity of fracturing horizontal wells. Besides, an orthogonal fracture layout perpendicular to the wellbore can also improve the gas wells productivity.

    Hydrogeology
    Characteristics and Formation of the Wangjiazhuang Alkaline Hot Spring in Xiangyun County of Yunnan
    HUO Dongxue, ZHOU Xun, LIU Haisheng, YU Mingxiao, ZHANG Yuqi
    2019, 33(03):  680-690.  DOI: 10.19657/j.geoscience.1000-8527.2019.03.20
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    The Wangjiazhuang hot spring is located in the Liuchang Township in Xiangyun County of Yunnan, China. The water samples YMD10-1 (from the Wangjia geothermal well) and YMD10-2 (from the Julong hot spring well) range in TDS from 1.49 to 1.65 g/L. The cation and anion are predominated by Na+and $HCO_{3}^{-}$ and the hot water is of HCO3-Na type. The pH values of the water samples are 10.8 and 7, respectively. Because of the high $p_{co_{2}}$ in the YMD10-2 sample, the pH value measured in the field is lower than expected. The pH values measured in laboratory are 8 and 7.6, respectively, which are mainly affected by the diffe-rence in $p_{co_{2}}$, resulting in changes in the carbonate compositions in the water samples. δ 2H and δ 18O data of the hot water samples indicate that the hot spring is of meteoric origin. The recharge altitude of the hot water is estimated as 2 845-2 865 m, the temperature of the geothermal reservoir as 89-92 ℃, and the depth of the groundwater circulation as approximately 3 808-3 898 m. The age of the hot spring is estimated as 319-447 a with the 226Ra-222Rn method. After receiving recharge from infiltration of precipitation in the surrounding mountain areas, the groundwater undergoes deep circulation and is heated by heat flow, and flows up along the fault zone through the Quaternary sediments and emerges on the lad surface. The alkalinity of the hot spring is attributed to the reaction of feldspar with water and CO2, resulting in high concentrations of $HCO_{3}^{-}$, and hydro-lysis of $HCO_{3}^{-}$ in solution possibly consumes H+ to produce OH-. The Wangjiazhuang hot spring is used to produce alkali by local people due to high contents of Na+, $HCO_{3}^{-}$ and $CO_{3}^{2-}$ in the hot water.