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    08 May 2019, Volume 33 Issue 02
    Ore Deposits and Petrology
    Geological Characteristics, Metallogenic Age and Genesis of Niumaoquan East Gold Deposit in the Western North Qilian
    FAN Xinxiang, KONG Weiqiong, YANG Zhenxi, ZHAO Jichang, ZHOU Shuming
    2019, 33(02):  251-261.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.01
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    Niumaoquan East gold deposit is located at the intersection area where the North Qilian orogenic belt and the Altun fault converged, which is known as the “Golden Triangle” in Northwest China. Niumaoquan East gold deposit is a newly discovered gold deposit in the area controlled by fragile-ductile faults. The gold ores occurred in EW-striken ductile faults developed in the andesite tuff and andesite lavas of Yingou Group. Gold mineralization apparently was controlled by ductile faults, featured by multistage mineralization. Most of gold was deposited at sulfide-quartz-gold stage. The wall rocks around gold lodes and ores have shown intensive hydrothermal alteration, gold mineralization is mainly related with silicification. Homogenization temperatures of fluid inclusions for the quartz in gold ores are 112-191 ℃, the salinity is 0.35%-7.86% with an average of 4.77%, the density is 0.92-0.96 g/cm3 with the average of 0.95 g/cm3, all of which are showing typical characteristics of epithermal gold deposits. The40Ar-39Ar dating of the sericite collected from wall rocks yields plateau age of (296.7±2.8)Ma corresponding to the inner continental extension stage of the North Qilian belt. The geological characteristics and metallogenic age of Niumaoquan East gold deposit is quite similar with that of Hanshan gold deposit located in nearby area, both of the two deposits are controlled by the same NWW trending of ductile-brittle fault zones, should belong to low-sulfidation epithermal deposit formed in late Variscan period. The discovery of the gold deposit and the study on the genesis are of great significance for guiding regional prospecting.

    The Characteristics of Stable Isotope Geochemistry of Shapinggou Molybdenum Deposit, Anhui Province
    LU Sanming, LI Jianshe, RUAN Linsen, ZHAO Lili, HUANG Fan, WANG Bohua, ZHANG Huaidong
    2019, 33(02):  262-270.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.02
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    Shapinggou molybdenum deposit, Jinzhai County, Anhui Province, is a super large porphyry molybdenum deposit discovered in the Qinling-Dabie metallogenic belt in recent years. The proven reserves of molybdenum resources are 246×104 t. The S, H, O stable isotopes for representative samples from different prospecting line sections at various depths were analyzed in this paper. The sulfur isotopic composition of sulfides in the ore deposit varies in a narrow range from +0.4‰ to +6.2‰. The average value is +3.47‰ within the range of igneous rocks, showing Gaussian distribution in histogram. The source of sulfur is relatively uniform , mainly deep sourced sulfur. The δ18O value of ore-forming fluid inclusions ranges from 0.40‰ to 7.52‰, and δD value of fluid inclusions ranges from -90‰ to -63‰, which suggest that ore-forming fluid for main mineralization resulted from magma. High δ34S and δ18O values correspond to mineralization central zone at various prospecting line sections. Besides, the δ34S and δ18O values have a decreasing tendency from albite feldspar-potassium feldspar-silicified zone, beresitization zone to chlorite-carbonation zone. The above characteristics indicate that the geochemical environment of ore-forming fluid of Shapinggou molybdenum deposit changed from alkaline into acidity during the main ore-forming period. There is no obvious low δ18O effect, the ore-forming occurred in a quite closed environment, and meteoric water with external convection circulation is relatively less involved in the mineralization. The geochemical environment is different from other porphyry molybdenum deposits in the East Qinling district.

    Characteristics and Geological Significance of Alkaline Melano-minerals in Maojiatun Granite, Heilongjiang Province
    QIN Jinhua, LIU Cui, DENG Jinfu, DUAN Peixin, GUO Na
    2019, 33(02):  271-283.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.03
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    Existence of alkaline melano-minerals is of great indicative significance for magmatic evolution processes. The Maojiatun alkaline granite body is located at the southern part of the Little Xing’an range-Zhangguangcai range, which represents the eastern part of the Xingmeng orogenic belt. The intrusion is characterized by the presence of alkaline melano-minerals with high contents of alkali and iron. In this study, we analyzed the mineralogical and EPMA chemical characteristics of the alkaline melano-minerals in the Maojiatun granite. Our study shows that the amphibole is iron magnesium-alumina natrium amphibole, and is featured by being Si, Na and Fe rich, and Ca, Mg and Al poor. The pyroxene is aegirine-augite, which is characterized by having high Si, Na and Fe, and low Ti, Mg, Al and Mn. We have determined that the host rock is alkaline magmatite, and the genetic type is aluminum-type A granite. Maojiatun alkaline granite has low M value, which indicates that it may have come from the remelting of juvenile crust. During crystallization, the magma system may have been under a closed and reducing condition, and there is a distinct zonation of acid and basic rocks from the center to margin of the intrusion. We concluded that the Maojiatun alkaline granite was formed in a late orogenic transition setting.

    Geochemical Characteristics of the Cretaceous Yixian Formation Mudstones in Xiushui Basin of Northern Liaoning and Their Geological Significance
    LI Wenbo, LI Xiaohai, DING Qiuhong, CHEN Shuwang, ZHANG Jian
    2019, 33(02):  284-292.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.04
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    The geochemical characteristics of sedimentary rocks contain a large amount of geological information, which is of great significance for restoring the sedimentary environments and the provenances. Through the analysis on geochemical characteristics such as major, trace elements and REE of mudstone samples of the Yi-xian Formation from Well Xiu-D1, the results show: REE in mudstones are enriched of LREE with a deficit of HREE. The REE patterns incline to the right, with slightly negative Ce anomalies and moderately negative Eu anomalies, indicates stable provenance input from upper continental crust. The acidic intrusive rocks of the Jurassic and Permian in the northeast-east part of the basin have a great affinity with sedimentary strata of the Yixian Formation,so acidic intrusive are highly likely to be provenance of sedimentary strata. The tectonic setting of provenance area is mainly active continental margin. The geochemical indicators such as B, Sr/Ba, LaN/SmN,V/(V+Ni), Fe2+/Fe3+, Cu/Zn and Ceanom indicate that the Yixian Formation was deposited in fresh, deep water with a reductive environment.

    Geochemistry
    Estimation of Background Values and Contamination Characteristics of Heavy Metals in Sediments of the Pearl River, China
    WEI Bin, HOU Qingye, TANG Zhimin, ZONG Qingxia, YAN Shuai, HE Haiyun
    2019, 33(02):  293-304.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.05
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    Estimating the background values and identifying anomalies are very important to discriminate anthropogenic contamination source and assess environmental risk of heavy metals. We collected and analyzed 58 sediment samples from different branches and channels of the Pearl River, China. Based on geochemical and statistical analysis, Al, Fe and Sc were proved suitable for as reference elements. Different methods of obtaining geochemical background values and outliers of heavy metals were presented and compared in this paper. A useful way to estimate the geochemical background values is provided by regression based on the least trimmed sum of squares (LTS), which is a robust statistical approach showing low sensitivity to outliers. Both boxplots of local enrichment factor and regression diagnostic plots turn out to be better for identifying outliers. Results show that contamination varied in the different segments of the Pearl River. The North River and Pearl River channels were contaminated by As, Cd, Cu, Pb and Zn and the East River by Cu, Cr and Ni while there was almost no contamination in the West River. Point source contamination remains a major cause of contamination to sediments. Main sources of heavy metals may be industrial contamination such as mining and electroplating.

    Soil Geochemical Characteristics of Shangqiu Area in Henan Province
    ZHANG Yan, LI Yusong, SHENG Qi, PAN Hanxiang, XIE Yujie
    2019, 33(02):  305-314.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.06
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    Based on the Multi-Purpose Regional Geochemical data of Shangqiu area in Henan Province and on the basis of normal and logarithmic normal tests, we calculated geochemical baseline and background values of 54 elements(indicators) in soil, analyzed enrichment or dilution of main elements in soil, and discussed geochemical characteristics of elements in surface soil. Results show that compared with national values, the geochemical baseline values are generally low. The content of Se is the lowest with only 0.28 times of the national value, while CaO is the highest, which is 1.96 times that of the country. The differences between baseline and background values of most elements(indicators) are not obvious, due to slight hyper-genesis effect and human activities; however, elements including Corg, N, Se, Hg, P, TC are enriched in surface soil because of obvious anthropogenic input. The factor analysis shows that the weathering, leaching and plant rhizosphere enrichment are the main factors affecting the geochemical characteristics of surface soil in the study area.

    Geophysics
    Quaternary Magnetostratigraphy Record in Sediments from Borehole BHS01 in the Bohai Strait
    SUN Jun, YANG Huiliang, HE Lei, CHU Hongxian, LU Yue, LI Panfeng, LIU Changchun, QI Jianghao, QIANG Xiaoke
    2019, 33(02):  315-324.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.07
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    Magenetostratigraphy is an effective method to establish reliable geochronological framework, which is critical for reconstructing long-term history of climatic and environmental changes in the past. A detailed palaeomagenetism study on sediments from borehole BHS01 (121.3 m) which is located in the Bohai Strait has been carried out. The results show that the core from the borehole consists of three normal magnetozones which can be correlated to Brunhes, Jaramillo, Olduvai. The basal age of the core is estimated at about 2.25 Ma by the extrapolation of the sedimentation rate in the Matuyama Chron. The Brunhes/Matuyama boundary was found at the core depth of 46.4 m. Thus, through the comprehensive analysis of lithologic, magnetic and sedimentary rate characteristics, we divide the evolutional process of BHS01 into three sedimentary phases: phaseⅠ(2.25 to 1.46 Ma) mainly develops in a fluvial sedimentation; phaseⅡ(1.46 to 0.78 Ma) is accompanied with a stable lacustrine sedimentation; and phaseⅢ(0.78 to 0 Ma) develops in a marine and terrestrial sedimentation. Our results provide a reliable chronological framework for the borehole, facilitating the stratigraphic division and evolutional process of the Quaternary in the Bohai Strait and its neighboring regions.

    Geophysical Characteristics and Pb-Zn Ore-controlling Structures in Northwestern Guizhou
    WANG Liang, ZHANG Jiawei, XIANG Kunpeng, CHEN Guoyong, HU Congliang, ZHANG Chen
    2019, 33(02):  325-336.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.08
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    Northwestern Guizhou is located in the Wumengshan gravity gradient belt of Sichuan-Guizhou-Yunnan Pb-Zn metallogenic domain. The domain is characterized by complex geological structure and geophysical anomalies, with low degree of research and substantial exploration potential. In recent years, the discovery of the large and super-large Pb-Zn deposits at Wuzhishan and Zhugongtang indicates huge potential of super-large Pb-Zn discovery in this region. Based on surficial geological survey, and regional gravity, aeromagnetic and 1:50k ground magnetic survey, major shallow and deep faults were delineated in this study. The results show the coupling relationship between the Pb-Zn deposits and the inferred deep and shallow faults. The typical ore-controlling fault F1 cut fault F2(in Lizigou, Weining, NW Guizhou) are NW- and NE-trending, respectively. In Yinajia-Xiaomaochang area, the two roughly parallel NE-trending faults (F10, F11) are both ore-controlling. Comprehensive analysis of regional geological data shows out that the deep and shallow faults are the main ore-forming/-hosting and ore-hosting structures, respectively, and the former are permissive to the formation of large to super large Pb-Zn deposits. It is speculated that the area around the major faults (F1-F16) can be a high potential area for Pb-Zn prospecting.

    A New Phase-controlled Reservoir Prediction Technique for Coal-rich Environment in the Pinghu Formation of the Xihu Sag, the East China Sea
    ZHANG Lan, WANG Wenji, HE Xianke, BAO Quan, LI Bingying
    2019, 33(02):  337-344.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.09
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    Although deterministic inversion and post-stack geostatistical inversion have been widely used in re-servoir prediction,they are not very effective in predicting thin reservoirs in complex geological background. In the Xihu Sag, difficulties in exploration and development have been caused by four problems, i.e., large burial depth, complex sedimentary environment, rapid reservoir phase transition and thin coal seams. Based on regional geological modelling and rock physical characteristics, the post-stack geostatistical method is likely better in coal seam prediction. The coal seam is taken as a known geological parameter to constrain the pre-stack geostatistical inversion. Consequently, seismic resolution is enhanced and fine thin reservoirs are delineated. This technique could solve the current poor reservoir prediction in the East China Sea,and facilitates well development. More importantly, the accuracy of reservoir prediction is improved by 15%, and the understanding in the reservoir sedimentation is enhanced, which makes this technique more applicable in other places.

    Developing a Pore Network Construction Algorithm for Computerized Tomography Images of Geomaterials
    REN Xianzhuo, LINDEN Joost van der, NARSILIO Guillermo
    2019, 33(02):  345-356.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.10
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    Pore network model is important in researching for granular or porous media.Many methods have been proposed to construct a pore network, and researchers have put increasing efforts on the image-based methods. This paper presents a pore network construction method based on the medial axis method, as the original method cannot represent the pore center correctly and the coordinates of the axial points are unknown. The improved method proposed in this study represents the pore centers, and the coordinates of all axial points are accessible. After constructing the pore network, the pore volume and throat size can be calculated. Our work also presents an Euclidean distance-based and a watershed-based method to solve the over-segmentation problem.

    Petroleum Geology
    A Review on the Complex Reservoir Sedimentary Characteristics and Low Permeability Formation of the Upper Eocene to Lower Oligocene in the Wenchang B Sag, Pearl River Estuary Basin
    LI Shanshan, PENG Song, CHEN Lin, LI Shengyong, LI Lianyi, LIU Xiaoyan
    2019, 33(02):  357-369.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.11
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    Late Eocene to Early Oligocene tectonic-sedimentary evolution in the Wenchang B sag (Pearl River estuary basin) is highly complex. Multi-phase and multi-source fan delta deposits and braided delta were formed, which were continuously affected by the Zhu Ⅲ south fault activity. This led to the characteristics of frequent vertical overlays and strong lateral reservoir heterogeneity. By studying the tectonic-sedimentary evolution, we analyzed the effect of fault activity time and mechanism and differences in the sedimentary framework, provenance and reservoir distribution. Combining with the complexity of local sedimentation, we analyzed the vertical facial change and the planar distribution regularity of the reservoir. Based on the sedimentary sequence and facial control, we discussed the genesis of low permeability reservoir and evaluated mid-deep formations. The study shows that there are two provenance systems from the Wenchang B sag, the fan delta that presents mélange deposits of acid extrusive volcanic rock (parent rock) in steep-slope zone, and the braided delta that presents traction current deposits of granite (parent rock) in gentle-slope zone.Physical properties of the latter are clearly better because of the source changes, the traction current mechanism, and the weakly compressive tectonic stress.Besides,there are four phases of fan delta along the sag, whose (from bottom to top) provenance change progressed from east to west.We found that both the sedimentary hydrodynamic conditions and the differential activity of the Zhu Ⅲ south fault are important factors for the planar heterogeneity of the reservoir. In the southern zone (with weak fault activities), the fan delta deposits are featured by their wide sedimentary range, the full handling and elutriation, and the low common shale content, which altogether give better physical properties. Consequently, seismic facies differences and detailed contrast analysis of sedimentary facies and lithofacies can be conducted to study the local sedimentation and low-permeability formation mechanism. This allows better constraint of seismic data and the redefinition of deposition mechanism and phase difference, which can significantly influence reservoir properties. Based on this system, we build on previous knowledge to finely recognize and portrait the scope of distribution and evolution characteristics of the deltaic sedimentary system of each deposition stage, and predict the exploration direction of “sweet point” reservoirs.On the basis of the understanding of hydrocarbon accumulation conditions, we successfully guide the discovery of oil and gas exploration and new horizons in the western Pearl River estuary basin, and increase the confidence of continuously expanding the exploration to the northern zone in the mid-deep formation of the Wenchang B area.

    Salt Rhythm Characteristics and Paleoclimatic Significance of Pukou Formation (2nd Member) in Yanghuai Section of Huai’an Salt Basin, Northern Jiangsu
    ZHANG Wenmiao, DING Guosheng, YU Xinghe, WANYAN Qiqi, KOU Yanxia, WU Zijin, SUN Le, FU Chao
    2019, 33(02):  370-378.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.12
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    Salt lake sediments, commonly characterized by its multi-stage formation and continuity, are important in paleoenvironment reconstruction. The salt rhythms of different scales show different paleoclimatic changes in their respective scale. The Pukou Formation is the main saliniferous sequence in the Huai’an basin, and studying the rhythms developed in the rock record can reveal the paleoclimatic characteristics. Based on core observation and mineral composition analysis, we have determined the salt rhythms and the vertical lithological variations. The paleoclimatic indications by the rhythms have revealed short-term paleoclimatic changes. The salt rhythms can be divided into five cycles, and each cycle is identified by a complete sequence of mudstone-glauberite-bearing salt rock-salt rock-glauberite-bearing salt rock. The extensive development of warm saline mineral (e.g.glauberite) indicates the paleoclimate was warm and arid. This study reconstructed the paleoclimate at IV-order rhythm, which was characterized by frequent arid-wet climatic fluctuations, despite dominated by arid climate. The thickness of rhythms generally reflects the fluctuation frequency.

    A Study on the Relationship Between Graptolites and Shale Gas in the Wufeng and Longmaxi Formations in the Sichuan Basin
    WANG Ziyi, GAO Zhiqian, SHI Wenrui, WANG Xingzhi, ZHAO Hongyan
    2019, 33(02):  379-388.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.13
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    Previous research on graptolites mainly focused on stratigraphic division and sedimentary environment analysis, but rarely on the relationship between graptolite and shale gas. Using data from core well analysis, drilling and core logging and experimental analysis, the Ordovician Wufeng Formation in the Sichuan Basin is divided into four graptolites zones (WF1-WF4), whilst the Silurian Longmaxi Formation is divided into nine graptolites zones (LM1-LM9).In the WF2-LM4 zones,TOC contents are high and organic pores are well developed, and thus these zones are favorable for shale gas exploitation. We found that the graptolite evolution and organic matter enrichment have the same depositional environment, and the abundance of graptolites is positively correlated with TOC, organic porosity, and total hydrocarbon content measured by gas. The evolution has a certain contribution to the organic matter content and organic pore formation in the shale, and somehow affects its gas-bearing properties, which is an important factor in shale gas reservoir evaluation. The shale gas formation in the Wufeng and Longmaxi Formations in the Sichuan Basin was likely related to the formation and evolution of graptolites, which has major implications for shale gas reservoir studies.

    Characteristics and Geological Significance of Thick Ignimbrite Beds of Yanchang Formation (Chang 7 Section) in Southeastern Ordos Basin
    XU Feng, ZHU Zengwu, LI Changchun, YANG Zhiguo
    2019, 33(02):  389-400.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.14
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    Ignimbrite interbeds are widely distributed in the high-grade hydrocarbon source rocks in the Chang 7 member of the Yanchang Formation in the Ordos basin. Generally, a single layer is 0.1 to 10 cm thick, occasionally reaching 1 to 2 m. Field geological and microscope petrographic studies at Yaoquzhen (Tongchuan city, southern Ordos basin) have identified a ~14-meter thick lithic crystal ignimbrite with interbedded lensoidal carbonatite. The SiO2 content is of 47.09% to 66.6%, which show that the rocks are primarily intermediate-felsic. Total REE (∑REE) contents are 164.04×10-6 to 245.74×10-6, and the rocks are enriched in LREEs, depleted in HREEs, with right-inclining REE pattern and negative Eu anomalies. LILEs (such as Sr and P) show negative anomalies whereas HFSEs (such as U and Th) show positive anomalies. For the carbonatites, the relatively high SiO2 and simple mineral assemblage suggest a crustal origin, whilst the high Sr and Ba contents show an igneous origin. Based on the geological and petrographic features of the ignimbrite and their distribution characteristics, the Middle-Late Triassic volcanic lithofacies model in the Ordos basin is established and the ignimbrite is likely of volcanic feeder-explosive facies. The ignimbrite was primarily from volcanic arc and had a high-K calc-alkaline magma source. The lensoidal carbonatites may have formed during the extrusion along extensional lithospheric faults resulted from continental collision, with the carbonatites produced directly from low-degree partial melting of the lithospheric mantle, which was intimately related to the evolution of Qinling orogenic belt that was responsible to mountain-basin coupling. The discovery provides a new petrological basis to understand the tectonic evolution of the Mesozoic Ordos basin.

    Structural Features of Unconformities: A Case Study of the Jurassic-Cretaceous Unconformity in Well Yong 1 Area,Junggar Basin
    GUAN Wei, XU Huaimin, LI Han, CHENG Lei, MA Yonghui
    2019, 33(02):  401-411.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.15
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    Well Yong 1 area is located in the Changji Sag of the Junggar Basin. Yanshan Movement had formed the Chemo uplift in the mid-late Jurassic, and it also led to overlapping and erosion of the Xishanyao Formation, forming a series of stratigraphic and lithologic reservoirs. Unconformity structures play an important role in the hydrocarbon migration and accumulation processes. Considering the factors of accumulation, the unconformity structures are divided into three levels: Level I includes cover and unconformity body, Level II divides the unconformity body into overlying strata, unconformity layer and underlying strata, and Level III contains the reservoir-forming elements, including the reservoir, barrier layer, weathered claystone and weathered leaching zone. The vertical unconformity structures are divided by logging data based on lithology, physical properties and petrological characteristics, and these structures in the study area are relatively complete. Through natural gamma ray inversion (based on seismic and well-logging data), the distribution of reservoirs and barriers in the unconformity structural layers are clarified. Thickness of the weathered leaching zone decreases gradually from the upper part to the sag, whereas the weathered claystone thickness increases, yielding a good negative correlation. The unconformity structures control the two most important types of reservoir-cap combinations in this area, i.e. (1) a combination of the overlying strata and the regional cap layer, and (2) a combination of the underlying strata and the weathered claystone.

    Hydrogeology
    Effect of Greenbelt Construction on Groundwater Circulation in Semi-arid Region:A Case Study from Hohhot-Bautou Section of Beijing-Tibet Expressway
    XIA Manhong, DONG Shaogang, ZHANG Tao, LI Yi, WANG Chao, CHENG Yajuan, LI Zhengkui
    2019, 33(02):  412-421.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.16
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    Highway greenbelts can beautify the environment, absorb dust and noise, and conserve water and soil. However, in arid areas with low precipitation, highway greenbelts mainly rely on groundwater recharge, which would have certain impact on regional groundwater resources distribution. This paper takes the Hubao highway greenbelt in the northern part of the Tumochuan Plain as a case study. Based on the analysis of the groundwater recharge characteristics, 3S technology and the Penman formula are used to calculate the transpiration rates under different vegetation coverage along the highway greenbelt. Groundwater recharge and the impact of highway greenbelt construction on the distribution of groundwater resources in the Beijing-Tibet Expressway are then analyzed. The results show that groundwater in the study area comes mainly from lateral recharge of the Daqingshan Mountain. The main discharge is groundwater runoff and transpiration along the greenbelt. During the period of July 2016 to June 2017, the non-vegetation and vegetation covered parts (17% and 83% of the total area, respectively) of the study area has an annual evapotranspiration of 1,006.10 mm. Along the greenbelt, transpiration water consumption is of 2,434.86×104 m3/a, and lateral recharge from the mountain front is of 24,372.16×104 m3/a. The transpiration water consumption of the greenbelt accounts for 10% of the lateral recharge from the mountain, which shows that the construction of highway greenbelts has an important impact on the distribution of groundwater resources.

    Ex-situ Chemical Oxidation Treatment for Non-aqueous Liquid Contaminated Groundwater: A Pilot Study
    SHENG Yizhi, ZHANG Xu, ZHAI Xiaobo, LI Guanghe
    2019, 33(02):  422-430.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.17
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    In this study, a former pesticide plant was selected to test the performance of the ex-situ chemical oxidation technology in eliminating non-aqueous organic contaminants from groundwater. Through laboratory-based experiment, the appropriate dosage of the four oxidants (i.e., potassium permanganate, potassium ferrate, Fenton’s reagent, and sodium hypochlorite) for the pilot-scale study were determined. The results (flow rate: 1.0 m3/h) show distinct variations in removal efficiency of the different oxidants on conventional pollutants and target organic pollutants. In general, the removal efficiency of the four oxidants for medium-and long-chain petroleum hydrocarbons (C10-C36) can reach 20% to 70%, while removal performance is poor (<20%) on chlorinated alkane pollutants. Potassium ferrate and sodium hypochlorite achieved better removal efficiency for phenolic compounds and PAHs (70%-100%); Fenton’s reagent has significant oxidation effects on most pollutants, among which the removal efficiency on short-chain petroleum hydrocarbons (C6-C9, 20%-40%), as well as benzene, toluene, ethylbenzene, o-and p-xylene (BTEX) (40%-90%) is higher than that of the other three oxidants. Our finding is useful to the application of chemical oxidation technology on similar contaminated sites.

    Paleogroundwater Dynamics of Xishanyao Formation in Kuosijiaer Uranium Ore District in Yili Basin
    QIU Yubo, CHEN Hong, YANG Junfeng, ZHANG Zhanfeng, JIANG Hong, DU Mo, LI Gang
    2019, 33(02):  431-439.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.18
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    This study investigated the paleogroundwater dynamic system of the Xishanyao Formation in Kuosijiaer area (Yili Basin), summarized its relationship with the uranium mineralization, and provided supports for the metallogenic regularities of sandstone-type uranium deposits and guide for future uranium prospecting in the area. By analyzing the thickness variation characteristics of the oxidized sand bodies, inverting the planar flow regime of interlayer oxidizing fluids, we reconstructed the paleogroundwater recharge-runoff-discharge characteristics of the Xishanyao Formation in the study area. Interlayer oxidized zone at Kuosijiaer was mainly developed in the Lower Xishanyao Formation and upper sub-member of the Upper Xishanyao Formation. The maximum thickness of the oxidized sand body of the Lower Xishanyao Formation occurs in the southwest, and appears as flower-shaped in the northeast and north. Maximum thickness of the oxidized sand body of the upper sub-member of the Upper Xishanyao Formation is in the southeast, and appears as strip-shaped in the northwest. Based on the distribution characteristics of the oxidized sand bodies, and considering the sand body thickness changes and the regional hydrogeological regime, two water-replenishment directions in the uranium mineralization can be determined at Kuosijiaer: (1) southwest, same in both the Lower and Upper Xishanyao Formations; (2) southeast, which was likely the main water-replenishment direction in the Upper Xishanyao Formation.

    Formation of Groundwater Based on Inverse Geochemical Modeling: A Case Study from the Sixian County, Anhui Province
    LIU Hai, KANG Bo, SHEN Junhui
    2019, 33(02):  440-450.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.19
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    Based on regional hydrogeological conditions, the hydrogeochemical characteristics, water type and spatial distribution of groundwater in Sixian County,Anhui Province were analysed and discussed. According to the characteristics of hydrodynamic field under groundwater exploitation, three paths were selected to simulate. The hydrogeochemical simulation was carried out using PHREEQC, and the formation and evolution of groundwater were quantitatively analysed. The results showed that the halite, gypsum and illite were dissolved; kaolinite, quartz, dolomite, calcite, fluorite were precipitated; calcic montmorillonite did not participate in the reaction; NaX desorption or CaX2 adsorption occurred in Path Ⅰ. Halite, gypsum, illite, quartz were dissolved; calcic montmorillonite and calcite were precipitated; NaX desorption and CaX2 adsorption occurred in Path Ⅱ. Reactions of Paths Ⅰ and Ⅲ are largely the same; the difference is the presence of dolomite dissolution in Path Ⅲ. The reason for this difference may be that dolomite dissolution is affected by precipitation CO2 and precipitation hysteresis in groundwater runoff. The results show that the groundwater composition is mainly influenced by dissolution of rock salt and gypsum, Ca-Na ionic exchange and calcic montmorillonite, calcite in groundwater mining conditions of Sixian County.

    Numerical Simulations of Groundwater Based on Three-dimensional Stochastic Hydrogeologic Structure Model: A Case Study from West Liaohe Plain
    SUN Qian, SHAO Jingli, CUI Yali, WANG Yulong, XUE Junhuan, MA Tao
    2019, 33(02):  451-460.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.20
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    To explore the uncertainty of the hydrogeological structure on the groundwater numerical simulation the West Liaohe Plain, the groundwater level was predicted using stochastic simulation. In this paper, lithologic distribution of porous media was simulated by the transition probability geostatistical method, and the relationship between lithology and hydrogeological parameters were determined by nonlinear programming. The many accurate stochastic hydrogeological parameters obtained were fed into MODFLOW, which generated the stochastic simulation. By comparing the fitting of the groundwater terminal flow field and the water level dynamic process of the stochastic and deterministic models, we found that the stochastic and deterministic models have similar trends, and are well-fitted to the measured data. The stochastic model can better reflect the real hydrogeological characteristics. According to the uncertainty analysis of the predicted groundwater level after 10 years, the average amplitude of the water level variation is ±5 m, and the average upper limit of the 95% confidence level is 0.146 m. This provides a scientific basis for decision makers.

    Spatial-temporal Characteristics of Vegetation Index and Its Impact Factors in the Golmud River Basin
    ZHANG Xucai, JIN Xiaomei, ZHU Xiaoqian, ZHANG Jing
    2019, 33(02):  461-468.  DOI: 10.19657/j.geoscience.1000-8527.2019.02.21
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    Located in the south-central part of Qaidam Basin in Qinghai Province, the Golmud River Basin is arid and its ecology is fragile. Vegetation dynamics are of great significance to ecological conservation in arid regions. Based on continuous record of MODIS NDVI data, the spatial-temporal characteristics of vegetation index in the Golmud River Basin were analyzed via remote sensing, and the influencing factors were discussed. The results show that the annual average NDVI value is generally small, but increased from 0.10 to 0.12 during 2001 to 2016. Areas of increasing NDVI trend are distributed to the east and west of Golmud City, while constant and decreasing trends of NDVI occur in the desert and the northern salt pond area, respectively. Both areas of low-density and high-density vegetation show an increasing rate, whereas the bare soil shows a decreasing trend in the vegetation coverage. Generally, the vegetation variation depends on various attributes such as climate change, soil moisture and groundwater depth. The correlation between NDVI and temperature is good (correlation coefficieis=0.822), and precipitation also has a certain impact on the growth of vegetation. There is a strong correlation between NDVI value and the apparent thermal inertia (correlation coefficieis=0.979). The corresponding range of groundwater depth to vegetation in the study area is from 0 to 12 m, and the vegetation growth is the best when the groundwater depth is about 6.5 m.