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现代地质 ›› 2011, Vol. 25 ›› Issue (6): 1219-1222.

• 工程地质 • 上一篇    

膨润土的有机改性及其钻井液性能

胡继良1,2,陶士先2 ,付帆2,王成彪1   

  1. 1中国地质大学 工程技术学院,北京100083;2北京探矿工程研究所,北京100083
  • 收稿日期:2011-04-25 修回日期:2011-10-28 出版日期:2011-12-14 发布日期:2011-12-15
  • 作者简介:胡继良,男,博士研究生,教授级高级工程师,1965年出生,地质工程专业,主要从事钻井化学材料研究。 Email:bjhjl@cugb.edu.cn。
  • 基金资助:

    国土资源部地质调查项目(1212011120247)。

Organic Modification and Drilling Fluid Properties of Bentonite

 HU  Ji-Liang-1, 2 , DAO  Shi-Xian-2 , FU  Fan-2, WANG  Cheng-Biao-1   

  1. 1School of Engineering and Technology, China University of Geosciences, Beijing100083, China;
    2 Beijing Institute of Exploration Engineering, Beijing100083, China
  • Received:2011-04-25 Revised:2011-10-28 Online:2011-12-14 Published:2011-12-15

摘要:

以过硫酸钾为引发剂,通过水溶液聚合法制得了丙烯酸和丙烯酰胺的聚合物A。用聚合物A作为有机改性剂,采用混炼挤压法制备得到样品。用X射线衍射(XRD)、红外光谱(FT-IR)、扫描电子显微镜(SEM)等方法对其结构形貌进行研究。结果表明,其晶面间距由原来的1.269 nm增大到1.322 nm,有机基团进入层间,并且仍保持层状结构,成功制备出了有机改性膨润土。用有机改性膨润土配制钻井液,当其质量分数为4%时,浆液的粘度为5.5 mPa·s,滤失量为13 mL,润滑系数为0.13。与普通钠基膨润土钻井液相比,有机改性膨润土钻井液的滤失量和润滑系数均有较大幅度降低,并且改善了钻井液的流变性。

关键词: 膨润土, 有机改性, 钻井液性能

Abstract:

Polymer A was synthesized by aqueous solution polymerization used acrylic acid and acrylamide with potassium persulfate as initiator. Organic modified bentonite sample was prepared by mixing extrusion method with polymer A as an organic modifier.The structure and morphology of the sample were examined by Xray diffraction (XRD), Fourier transform infrared spectroscopy(FT-IR) and scanning electron microscopy (SEM).The results show that the crystal spacing of the organic modified bentonite changes from 1.269 to 1.322 nm, and the organic modified bentonite still maintains the layered structure with organic groups in the layer.The organic modified bentonite was successfully prepared.Drilling fluids were prepared by this organic modified bentonite to study the fluid loss property and other properties.When the mass fraction was 4%, the viscosity of the drilling fluid was 5.5 mPa·s, and the fluid loss and lubrication coefficient were 13 mL and 0.13, respectively. The results show that the fluid loss and lubrication coefficient of the drilling fluid of organic modified bentonite reduce greatly and the rheology improves, compared with drilling fluid of ordinary sodium bentonite.