金刚烷化合物在深层油气地球化学研究中的应用

doi:10.19657/j.geoscience.1000-8527.2020.04.16

现代地质 ›› 2020, Vol. 34 ›› Issue (04): 812-820.DOI: 10.19657/j.geoscience.1000-8527.2020.04.16

金刚烷化合物在深层油气地球化学研究中的应用

晏继发¹^,²(), 马安来³(), 李贤庆¹^,², 从刚石¹^,², 和钰凯¹^,², 张亚超¹^,²

1.中国矿业大学(北京) 煤炭资源与安全开采国家重点实验室,北京 100083
2.中国矿业大学(北京) 地球科学与测绘工程学院,北京 100083
3.中国石油化工股份有限公司石油勘探开发研究院,北京 100083

收稿日期:2019-06-30 修回日期:2019-09-17 出版日期:2020-08-31 发布日期:2020-09-03
通讯作者: 马安来
作者简介:马安来,男,副教授,博士,1969年出生,有机地球化学专业,主要从事油气地球化学与成藏机理研究。Email: maal.syky@sinopec.com。
晏继发,男,硕士研究生,1995年出生,地质工程专业,主要从事油气地质和地球化学研究。Email: 1341627067@qq.com。
基金资助:
国家自然科学基金项目(41772153);国家科技重大专项(2016ZX05007-003);中国石油化工股份有限公司科技部项目(P17049-1);中国石油化工股份有限公司科技部项目(P19024)

Application of Diamondoids in Geochemical Research of Deep Oil and Gas

YAN Jifa¹^,²(), MA Anlai³(), LI Xianqing¹^,², CONG Gangshi¹^,², HE Yukai¹^,², ZHANG Yachao¹^,²

1. State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Beijing 100083, China
2. College of Geoscience and Surveying Engineering, China University of Mining and Technology, Beijing 100083, China
3. Exploration and Production Research Institute, SINOPEC, Beijing 100083, China

Received:2019-06-30 Revised:2019-09-17 Online:2020-08-31 Published:2020-09-03
Contact: MA Anlai

摘要/Abstract

摘要：

近年来我国油气勘探向深层拓展,油气成熟度及油藏保存成为研究焦点。金刚烷化合物由于其独特的笼型分子结构,具有较强的热稳定性和抗生物降解能力,在深层油气勘探具有广阔的应用前景。叙述了实验室检测金刚烷化合物的样品预处理及检测方法;总结了金刚烷化合物在地质体中的成因和演化过程;综述了金刚烷化合物在判识成熟度、原油裂解程度、生物降解作用、硫酸盐热化学还原作用和蒸发分馏作用等方面的研究进展。由于金刚烷化合物成因不明,制约了其在油气地球化学的应用。提出开展不同沉积环境、不同类型烃源岩及原油中金刚烷化合物演化过程的对比研究,研究不同沉积盆地原油的甲基双金刚烷基线,有利于补充和完善金刚烷化合物的实际应用,对了解深部油气成藏过程、指导深部油气勘探具有重要意义。

关键词: 金刚烷化合物, 成熟度, 原油裂解, 生物降解, 硫酸盐热化学作用, 蒸发分馏作用

Abstract:

In recent years, oil and gas exploration in China has expanded to ultra-deep formations, and oil and gas maturity and reservoir preservation have become the focus of research. Because of their unique cage molecular structure, strong thermal stability and biodegradability, diamondoids have broad application potential in deep oil and gas exploration. In this paper, laboratory sample pretreatment and detection methods of diamondoids are described, and their genesis and geological evolution are summarized. New advancement in maturity, oil-cracking, biodegradation, thermochemical sulfate reduction (TSR), evaporative fractionation, and other identification methods with diamondoids are reviewed. Applications of diamondoids in the petroleum geochemistry are limited due to its unknown origin. It is proposed that comparative studies on the evolution process of diamondoids in different sedimentary environments, different types of source rocks and crude oils should be performed, in order to study the methyl-diamantane baseline of crude oils in different sedimentary basins. This can supplement and improve the applications of diamondoids, and can greatly enhance our understanding in deep hydrocarbon accumulation processes and guide deep hydrocarbon exploration.

Key words: diamondoids, maturity, oil-cracking, biodegradation, thermochemical sulfate reduction (TSR), evaporative fractionation

中图分类号:

TE122

晏继发, 马安来, 李贤庆, 从刚石, 和钰凯, 张亚超. 金刚烷化合物在深层油气地球化学研究中的应用[J]. 现代地质, 2020, 34(04): 812-820.

YAN Jifa, MA Anlai, LI Xianqing, CONG Gangshi, HE Yukai, ZHANG Yachao. Application of Diamondoids in Geochemical Research of Deep Oil and Gas[J]. Geoscience, 2020, 34(04): 812-820.

图/表 8

参考文献 52

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学者	时间	样品	主要认识
Fang等^[18]	2012	原油	金刚烷在Easy R_o=1.0%~2.1%时生成,Easy R_o>2.1%时开始分解
Fang等^[19]	2013	原油	单金刚烷在Easy R_o=1.0%~2.3%时生成,Easy R_o>2.3%时开始分解;双金刚烷在Easy R_o=1.6%~2.7%时生成,Easy R_o>2.7%时开始分解
Fang等^[29]	2015	海相页岩	金刚烷在Easy R_o=0.8%~1.7%时生成,Easy R_o>1.7%时开始分解直至Easy R_o=3.0%时基本完全消失
房忱琛等^[30]	2015	煤系泥岩	金刚烷在Easy R_o=1.0%~1.5%时生成,Easy R_o>1.5%时开始分解
Li等^[31]	2015	干酪根	单金刚烷在Easy R_o=0.8%~1.8%时生成,Easy R_o>1.8%时开始分解;双金刚烷在Easy R_o=1.0%~2.2%时生成,Easy R_o>2.2%时开始分解
Jiang等^[32]	2018	干酪根	金刚烷在Easy R_o=0.6%~2.1%时生成,Easy R_o>2.1%时开始分解

学者	时间	样品	主要认识
Fang等^[18]	2012	原油	金刚烷在Easy R_o=1.0%~2.1%时生成,Easy R_o>2.1%时开始分解
Fang等^[19]	2013	原油	单金刚烷在Easy R_o=1.0%~2.3%时生成,Easy R_o>2.3%时开始分解;双金刚烷在Easy R_o=1.6%~2.7%时生成,Easy R_o>2.7%时开始分解
Fang等^[29]	2015	海相页岩	金刚烷在Easy R_o=0.8%~1.7%时生成,Easy R_o>1.7%时开始分解直至Easy R_o=3.0%时基本完全消失
房忱琛等^[30]	2015	煤系泥岩	金刚烷在Easy R_o=1.0%~1.5%时生成,Easy R_o>1.5%时开始分解
Li等^[31]	2015	干酪根	单金刚烷在Easy R_o=0.8%~1.8%时生成,Easy R_o>1.8%时开始分解;双金刚烷在Easy R_o=1.0%~2.2%时生成,Easy R_o>2.2%时开始分解
Jiang等^[32]	2018	干酪根	金刚烷在Easy R_o=0.6%~2.1%时生成,Easy R_o>2.1%时开始分解

	缩写	公式	资料来源
同系物指标	MAI	1-MA/(1-MA+2-MA)	Chen等^[10];Zhang等^[35]
	MDI	4-MD/(4-MD+1-MD+3-MD)	Chen等^[10];Zhang等^[35]
	DMAI-1	1,3-DMA/(1,3-DMA+1,2-DMA)	Wei等^[7];
	DMAI-2	1,3-DMA/(1,3-DMA+1,4-DMA)	Wei等^[7];
	EAI	1-EA/(1-EA+2-EA)	Schulz等^[23]
	TMAI-1	1,3,5-TMA/(1,3,5-TMA+1,3,4-TMA)	Wei等^[7];Fang等^[18]
	TMAI-2	1,3,5-TMA/(1,3,5-TMA+1,3,6-TMA)	Wei等^[7];Fang等^[18]
	DMDI-1	4,9-DMD/(4,9-DMD+3,4-DMD)	Chen等^[10];Zhang等^[35]
	DMDI-2	4,9-DMD/(4,9-DMD+4,8-DMD)	Chen等^[10];Zhang等^[35]
产率指标	A/D	单金刚烷/双金刚烷	Fang等^[18,19]
	MA/MD	甲基单金刚烷/甲基双金刚烷
	DMA/DMD	双甲基单金刚烷/双甲基双金刚烷
	TMA/DMD	三甲基单金刚烷/三甲基双金刚烷
	As/Ds	总单金刚烷/总双金刚烷

	缩写	公式	资料来源
同系物指标	MAI	1-MA/(1-MA+2-MA)	Chen等^[10];Zhang等^[35]
	MDI	4-MD/(4-MD+1-MD+3-MD)	Chen等^[10];Zhang等^[35]
	DMAI-1	1,3-DMA/(1,3-DMA+1,2-DMA)	Wei等^[7];
	DMAI-2	1,3-DMA/(1,3-DMA+1,4-DMA)	Wei等^[7];
	EAI	1-EA/(1-EA+2-EA)	Schulz等^[23]
	TMAI-1	1,3,5-TMA/(1,3,5-TMA+1,3,4-TMA)	Wei等^[7];Fang等^[18]
	TMAI-2	1,3,5-TMA/(1,3,5-TMA+1,3,6-TMA)	Wei等^[7];Fang等^[18]
	DMDI-1	4,9-DMD/(4,9-DMD+3,4-DMD)	Chen等^[10];Zhang等^[35]
	DMDI-2	4,9-DMD/(4,9-DMD+4,8-DMD)	Chen等^[10];Zhang等^[35]
产率指标	A/D	单金刚烷/双金刚烷	Fang等^[18,19]
	MA/MD	甲基单金刚烷/甲基双金刚烷
	DMA/DMD	双甲基单金刚烷/双甲基双金刚烷
	TMA/DMD	三甲基单金刚烷/三甲基双金刚烷
	As/Ds	总单金刚烷/总双金刚烷

金刚烷化合物在深层油气地球化学研究中的应用

Application of Diamondoids in Geochemical Research of Deep Oil and Gas

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