钾长石分解反应热力学与过程评价

现代地质 ›› 2007, Vol. 21 ›› Issue (2): 426-434.

• 岩石物理化学 • 上一篇

钾长石分解反应热力学与过程评价

马鸿文，苏双青，王芳，徐锦明，谭丹君，刘浩

中国地质大学矿物材料国家专业实验室，北京100083

收稿日期:2007-02-07 修回日期:2007-03-20 出版日期:2007-02-20 发布日期:2007-02-20
作者简介:马鸿文，男，教授，博士生导师，1952年出生，岩石学、矿物学、材料学专业，主要从事矿物材料科学及制备技术、硅酸盐体系化学平衡与材料设计、结晶岩热力学与相平衡领域的教学与研究。Email:mahw@cugb.edu.cn。
基金资助:
“十一五”国家科技支撑计划项目（2006BAD10B04）；中国地质大学矿物材料国家专业实验室开放基金课题（04103）

Thermodynamic Analysis on Decomposition reactions of Potassium Feldspar and Evaluation of the Processes

MA Hong-wen, SU Shuang-qing, WANG Fang, XU Jin-ming, TAN Dan-jun, LIU Hao

National Laboratory of Mineral Materials, China University of Geosciences, Beijing100083, China

Received:2007-02-07 Revised:2007-03-20 Online:2007-02-20 Published:2007-02-20

摘要/Abstract

摘要：

综述了添加各种助剂分解钾长石的研究进展。对不同体系中钾长石分解反应的Gibbs自由能和能耗计算，综合考虑一次性资源、能源消耗量和烧结过程的环境相容性、产品方案等因素，结果表明:只有以石灰石、碳酸钠为配料的工艺路线具有实际工业应用价值；而唯有以碳酸钠为配料时，钾长石原料烧结过程才具有一次性资源消耗量最少、能耗最低、温室气体CO₂排放量最小、且可生产高附加值产品、实现完全清洁生产等优点。因此，选择以碳酸钠为配料分解钾长石的技术路线，具有良好的工业化应用前景。

关键词: 非水溶性钾矿, 烧结反应, 热力学, 清洁生产, 钾化合物

Abstract:

The advances of thermal decomposition of potassium feldspar with various additive agents are reviewed. Thermodynamic calculations of the thermal decomposition reactions of potassium feldspar are performed for both of the Gibbs free energy changes and energy consumptions during the sintering processes with various additives. Taking such factors into consideration as mineral resource consumption, energy consumption, environmental compatibility, and the terminal product schema for the sintering procedures of potassium feldspar powdery materials, it is deduced that both procedures with limestone and sodium carbonate as additives are of significance in industry; and further, it is only when sodium carbonate is taken as additive that the procedure could be the least consumptions of the mineral resources and energy, the least expellant of the greenhouse gas CO₂, and that the terminal products with high value could be manufactured. It is therefore feasible that the procedure suggested in this paper is hopeful industrialized both in economic benefits and environmental kindness.

Key words: insoluble potassium ore, sintering reaction, thermodynamics, clean processing, potassium compound

中图分类号:

TQ170.1

马鸿文，苏双青，王芳，徐锦明，谭丹君，刘浩. 钾长石分解反应热力学与过程评价[J]. 现代地质, 2007, 21(2): 426-434.

MA Hong-wen, SU Shuang-qing, WANG Fang, XU Jin-ming, TAN Dan-jun, LIU Hao. Thermodynamic Analysis on Decomposition reactions of Potassium Feldspar and Evaluation of the Processes[J]. Geoscience, 2007, 21(2): 426-434.

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钾长石分解反应热力学与过程评价

Thermodynamic Analysis on Decomposition reactions of Potassium Feldspar and Evaluation of the Processes

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