Geoscience ›› 2023, Vol. 37 ›› Issue (03): 801-812.DOI: 10.19657/j.geoscience.1000-8527.2022.087
• Experimental, Applied and Environmental Geochemistry • Previous Articles Next Articles
ZHANG Gaixia1(), SUN Jinjiajie2, GONG Qingjie2(
), JIANG Biao3, YAN Taotao4
Received:
2022-05-05
Revised:
2022-10-08
Online:
2023-06-10
Published:
2023-07-20
CLC Number:
ZHANG Gaixia, SUN Jinjiajie, GONG Qingjie, JIANG Biao, YAN Taotao. Geochemical Genes for the Weathering of Dolomite at the Shangmanggang Gold Deposit Area in Luxi, Yunnan, SW China[J]. Geoscience, 2023, 37(03): 801-812.
项目 | 检出限 | B1 | B2 | B3 | B4 | B5 | B6 | B7 | B8 | B9 |
---|---|---|---|---|---|---|---|---|---|---|
样品类型 | — | 土壤 | 土壤 | 土壤 | 土壤 | 土壤 | 土壤 | 土壤 | 风化碎屑 | 白云岩 |
采样深度(m) | — | 0.05 | 0.25 | 0.45 | 1.25 | 1.90 | 2.55 | 3.05 | 4.0 | 4.5 |
SiO2 | 0.10 | 60.7 | 57.1 | 52.8 | 52.7 | 55.1 | 53.1 | 52.5 | 3.5 | 0.96* |
Al2O3 | 0.05 | 17.54 | 20.38 | 22.80 | 23.08 | 21.65 | 22.46 | 22.62 | 2.09 | 0.08 |
Fe2O3 | 0.05 | 6.24 | 8.13 | 9.75 | 9.76 | 9.96 | 9.78 | 10.20 | 0.66 | 0.07 |
FeO | 0.10 | 1.20 | 0.78 | 0.43 | 0.47 | 0.31 | 0.30 | 0.16 | 0.11 | 0.11 |
K2O | 0.05 | 1.88 | 2.20 | 2.47 | 2.60 | 2.84 | 4.14 | 3.77 | 0.16 | 0.026* |
Na2O | 0.05 | 0.09 | 0.09 | 0.09 | 0.09 | 0.08 | 0.09 | 0.09 | 0.08 | 0.08 |
CaO | 0.05 | 0.10 | 0.06 | 0.07 | 0.08 | 0.05 | 0.17 | 0.21 | 29.14 | 30.76 |
MgO | 0.05 | 0.60 | 0.66 | 0.75 | 0.77 | 0.70 | 1.24 | 1.21 | 20.26 | 22.07 |
TiO2 | 0.05 | 1.14 | 1.13 | 1.04 | 1.04 | 1.04 | 0.93 | 0.84 | 0.10 | 0.004* |
P2O5 | 0.05 | 0.16 | 0.12 | 0.12 | 0.11 | 0.11 | 0.07 | 0.08 | 0.027* | 0.005* |
MnO | 0.05 | 0.18 | 0.17 | 0.12 | 0.10 | 0.06 | 0.07 | 0.14 | 0.010* | 0.005* |
烧失量 | 0.10 | 10.00 | 9.01 | 9.39 | 9.11 | 7.90 | 7.40 | 7.88 | 43.76 | 45.87 |
总量 | — | 99.79 | 99.85 | 99.83 | 99.92 | 99.85 | 99.79 | 99.68 | 99.87 | 100.03 |
TFe2O3 | 0.10 | 7.58 | 8.99 | 10.23 | 10.28 | 10.30 | 10.11 | 10.36 | 0.78 | 0.19 |
CIA | — | 88.9 | 89.0 | 89.0 | 88.6 | 87.1 | 82.5 | 83.8 | 82.7 | 22.2 |
WIG | — | 9.2 | 9.2 | 9.2 | 9.6 | 10.8 | 15.8 | 14.6 | 1958 | 26875 |
Table 1 Major element oxide contents of the samples from weathering profile B in Shangmanggang gold deposit area
项目 | 检出限 | B1 | B2 | B3 | B4 | B5 | B6 | B7 | B8 | B9 |
---|---|---|---|---|---|---|---|---|---|---|
样品类型 | — | 土壤 | 土壤 | 土壤 | 土壤 | 土壤 | 土壤 | 土壤 | 风化碎屑 | 白云岩 |
采样深度(m) | — | 0.05 | 0.25 | 0.45 | 1.25 | 1.90 | 2.55 | 3.05 | 4.0 | 4.5 |
SiO2 | 0.10 | 60.7 | 57.1 | 52.8 | 52.7 | 55.1 | 53.1 | 52.5 | 3.5 | 0.96* |
Al2O3 | 0.05 | 17.54 | 20.38 | 22.80 | 23.08 | 21.65 | 22.46 | 22.62 | 2.09 | 0.08 |
Fe2O3 | 0.05 | 6.24 | 8.13 | 9.75 | 9.76 | 9.96 | 9.78 | 10.20 | 0.66 | 0.07 |
FeO | 0.10 | 1.20 | 0.78 | 0.43 | 0.47 | 0.31 | 0.30 | 0.16 | 0.11 | 0.11 |
K2O | 0.05 | 1.88 | 2.20 | 2.47 | 2.60 | 2.84 | 4.14 | 3.77 | 0.16 | 0.026* |
Na2O | 0.05 | 0.09 | 0.09 | 0.09 | 0.09 | 0.08 | 0.09 | 0.09 | 0.08 | 0.08 |
CaO | 0.05 | 0.10 | 0.06 | 0.07 | 0.08 | 0.05 | 0.17 | 0.21 | 29.14 | 30.76 |
MgO | 0.05 | 0.60 | 0.66 | 0.75 | 0.77 | 0.70 | 1.24 | 1.21 | 20.26 | 22.07 |
TiO2 | 0.05 | 1.14 | 1.13 | 1.04 | 1.04 | 1.04 | 0.93 | 0.84 | 0.10 | 0.004* |
P2O5 | 0.05 | 0.16 | 0.12 | 0.12 | 0.11 | 0.11 | 0.07 | 0.08 | 0.027* | 0.005* |
MnO | 0.05 | 0.18 | 0.17 | 0.12 | 0.10 | 0.06 | 0.07 | 0.14 | 0.010* | 0.005* |
烧失量 | 0.10 | 10.00 | 9.01 | 9.39 | 9.11 | 7.90 | 7.40 | 7.88 | 43.76 | 45.87 |
总量 | — | 99.79 | 99.85 | 99.83 | 99.92 | 99.85 | 99.79 | 99.68 | 99.87 | 100.03 |
TFe2O3 | 0.10 | 7.58 | 8.99 | 10.23 | 10.28 | 10.30 | 10.11 | 10.36 | 0.78 | 0.19 |
CIA | — | 88.9 | 89.0 | 89.0 | 88.6 | 87.1 | 82.5 | 83.8 | 82.7 | 22.2 |
WIG | — | 9.2 | 9.2 | 9.2 | 9.6 | 10.8 | 15.8 | 14.6 | 1958 | 26875 |
元素 | 检出限 | B1 | B2 | B3 | B4 | B5 | B6 | B7 | B8 | B9 |
---|---|---|---|---|---|---|---|---|---|---|
W | 0.20 | 8.84 | 9.21 | 8.23 | 8.96 | 10.03 | 7.93 | 7.17 | 0.54 | 0.44 |
Sn | 1.00 | 4.57 | 5.21 | 5.38 | 4.80 | 4.96 | 6.25 | 6.19 | 0.50* | 1.80 |
Mo | 0.20 | 5.73 | 5.35 | 5.38 | 5.96 | 5.50 | 12.26 | 11.60 | 3.32 | 1.03 |
Bi | 0.05 | 0.76 | 0.68 | 0.69 | 0.71 | 0.61 | 0.66 | 0.88 | 0.06 | 0.03* |
Cu | 1.0 | 44.3 | 50.9 | 52.7 | 55.3 | 49.2 | 69.0 | 71.5 | 6.9 | 4.2 |
Pb | 2.0 | 36.8 | 36.2 | 36.7 | 39.0 | 35.9 | 54.1 | 63.1 | 5.1 | 0.99* |
Zn | 2.0 | 99.6 | 118.6 | 124.2 | 126.3 | 112.3 | 140.0 | 169.0 | 24.3 | 7.2 |
Cd | 30 | 258 | 155 | 146 | 157 | 296 | 362 | 441 | 298 | 211 |
Ag | 20 | 197 | 161 | 111 | 126 | 68 | 140 | 213 | 30 | 17.8* |
As | 1 | 302 | 313 | 357 | 397 | 531 | 340 | 318 | 24 | 1.7 |
Sb | 0.05 | 20.30 | 23.30 | 23.40 | 28.20 | 44.70 | 42.50 | 42.70 | 4.88 | 0.20 |
Au | 0.2 | 208.6 | 267.3 | 383.9 | 380.1 | 577.3 | 463.6 | 829.2 | 10.4 | 2.7 |
Hg | 2 | 2595 | 3600 | 3450 | 4450 | 6100 | 14000 | 17750 | 1040 | 209 |
V | 5 | 150 | 177 | 197 | 196 | 192 | 209 | 225 | 30 | 30 |
Cr | 5 | 156 | 119 | 120 | 125 | 123 | 114 | 113 | 21 | 77 |
Co | 1.0 | 24.0 | 31.9 | 27.9 | 27.1 | 18.3 | 48.5 | 59.5 | 3.3 | 0.39* |
Ni | 2.0 | 68.4 | 93.3 | 99.9 | 100.9 | 80.3 | 151.7 | 194.7 | 13.4 | 8.7 |
Zr | 5 | 280 | 277 | 255 | 240 | 241 | 184 | 169 | 26 | 10 |
Hf | 0.20 | 6.24 | 6.33 | 5.86 | 5.75 | 5.39 | 4.24 | 3.87 | 0.73 | 0.27 |
Nb | 2.0 | 21.6 | 23.2 | 20.0 | 20.9 | 21.3 | 20.4 | 17.5 | 1.98* | 0.30* |
Ta | 0.10 | 1.41 | 1.56 | 1.37 | 1.45 | 1.36 | 1.33 | 1.17 | 0.14 | 0.01* |
Th | 1.0 | 16.4 | 19.7 | 17.5 | 14.2 | 17.5 | 15.1 | 13.1 | 1.34 | 0.29* |
U | 0.20 | 6.32 | 7.45 | 7.03 | 7.16 | 7.63 | 13.15 | 12.37 | 4.54 | 1.13 |
Sc | 1.0 | 19.2 | 23.9 | 24.9 | 24.0 | 26.6 | 30.1 | 30.4 | 3.0 | 0.06* |
Y | 1.0 | 33.0 | 31.0 | 38.7 | 49.7 | 43.9 | 72.6 | 76.0 | 16.4 | 1.7 |
Li | 1.0 | 40.6 | 49.1 | 51.6 | 51.8 | 44.7 | 36.8 | 40.2 | 5.7 | 0.40* |
Be | 0.50 | 2.60 | 2.89 | 2.87 | 3.41 | 3.38 | 7.53 | 11.16 | 1.29 | 0.048* |
Sr | 5 | 94 | 93 | 87 | 91 | 126 | 81 | 81 | 59 | 36 |
Ba | 5 | 269 | 276 | 308 | 324 | 262 | 208 | 212 | 27 | 5.0 |
Rb | 5 | 121 | 142 | 159 | 153 | 147 | 159 | 157 | 7.4 | 2.6* |
La | 1.0 | 49.7 | 44.8 | 48.7 | 53.4 | 56.8 | 66.4 | 68.9 | 4.8 | 0.46* |
Ce | 1.0 | 110.3 | 97.4 | 107.6 | 104.0 | 100.3 | 105.6 | 119.9 | 8.1 | 0.72* |
Pr | 0.1 | 11.5 | 10.5 | 11.5 | 13.7 | 13.9 | 20.3 | 23.0 | 1.2 | 0.11 |
Nd | 0.1 | 43.9 | 40.3 | 44.1 | 54.7 | 54.2 | 86.6 | 101.1 | 5.1 | 0.4 |
Sm | 0.10 | 8.64 | 8.08 | 8.97 | 11.82 | 11.07 | 20.55 | 25.10 | 1.13 | 0.09* |
Eu | 0.10 | 1.88 | 1.72 | 1.98 | 2.73 | 2.53 | 4.89 | 6.14 | 0.30 | 0.03* |
Gd | 0.10 | 7.69 | 7.23 | 8.38 | 11.55 | 10.13 | 20.89 | 25.62 | 1.60 | 0.12 |
Tb | 0.10 | 1.28 | 1.22 | 1.42 | 1.91 | 1.67 | 3.38 | 4.20 | 0.34 | 0.019* |
Dy | 0.10 | 7.45 | 7.05 | 8.17 | 11.01 | 9.60 | 18.99 | 23.67 | 3.82 | 0.10 |
Ho | 0.10 | 1.43 | 1.33 | 1.58 | 2.09 | 1.78 | 3.50 | 4.28 | 0.96 | 0.026* |
Er | 0.10 | 3.73 | 3.46 | 4.28 | 5.36 | 4.69 | 8.91 | 10.59 | 2.21 | 0.074* |
Tm | 0.10 | 0.61 | 0.58 | 0.72 | 0.90 | 0.79 | 1.48 | 1.78 | 0.25 | 0.01* |
Yb | 0.10 | 3.67 | 3.43 | 4.10 | 5.10 | 4.67 | 8.50 | 10.54 | 1.24 | 0.055* |
Lu | 0.10 | 0.58 | 0.56 | 0.65 | 0.80 | 0.74 | 1.33 | 1.69 | 0.18 | 0.009* |
LG01_R酸 | — | 70 | 75 | 75 | 75 | 75 | 75 | 75 | 65 | 55 |
LG03_R酸 | — | 70 | 75 | 70 | 65 | 70 | 70 | 70 | 45 | 50 |
MGAu_R矿 | — | 45 | 40 | 40 | 40 | 40 | 45 | 55 | 55 | 80 |
MGW_R矿 | — | 30 | 30 | 30 | 30 | 30 | 35 | 40 | 30 | 80 |
Table 2 Trace element concentrations of the samples from weathering profile B in Shangmanggang gold deposit area
元素 | 检出限 | B1 | B2 | B3 | B4 | B5 | B6 | B7 | B8 | B9 |
---|---|---|---|---|---|---|---|---|---|---|
W | 0.20 | 8.84 | 9.21 | 8.23 | 8.96 | 10.03 | 7.93 | 7.17 | 0.54 | 0.44 |
Sn | 1.00 | 4.57 | 5.21 | 5.38 | 4.80 | 4.96 | 6.25 | 6.19 | 0.50* | 1.80 |
Mo | 0.20 | 5.73 | 5.35 | 5.38 | 5.96 | 5.50 | 12.26 | 11.60 | 3.32 | 1.03 |
Bi | 0.05 | 0.76 | 0.68 | 0.69 | 0.71 | 0.61 | 0.66 | 0.88 | 0.06 | 0.03* |
Cu | 1.0 | 44.3 | 50.9 | 52.7 | 55.3 | 49.2 | 69.0 | 71.5 | 6.9 | 4.2 |
Pb | 2.0 | 36.8 | 36.2 | 36.7 | 39.0 | 35.9 | 54.1 | 63.1 | 5.1 | 0.99* |
Zn | 2.0 | 99.6 | 118.6 | 124.2 | 126.3 | 112.3 | 140.0 | 169.0 | 24.3 | 7.2 |
Cd | 30 | 258 | 155 | 146 | 157 | 296 | 362 | 441 | 298 | 211 |
Ag | 20 | 197 | 161 | 111 | 126 | 68 | 140 | 213 | 30 | 17.8* |
As | 1 | 302 | 313 | 357 | 397 | 531 | 340 | 318 | 24 | 1.7 |
Sb | 0.05 | 20.30 | 23.30 | 23.40 | 28.20 | 44.70 | 42.50 | 42.70 | 4.88 | 0.20 |
Au | 0.2 | 208.6 | 267.3 | 383.9 | 380.1 | 577.3 | 463.6 | 829.2 | 10.4 | 2.7 |
Hg | 2 | 2595 | 3600 | 3450 | 4450 | 6100 | 14000 | 17750 | 1040 | 209 |
V | 5 | 150 | 177 | 197 | 196 | 192 | 209 | 225 | 30 | 30 |
Cr | 5 | 156 | 119 | 120 | 125 | 123 | 114 | 113 | 21 | 77 |
Co | 1.0 | 24.0 | 31.9 | 27.9 | 27.1 | 18.3 | 48.5 | 59.5 | 3.3 | 0.39* |
Ni | 2.0 | 68.4 | 93.3 | 99.9 | 100.9 | 80.3 | 151.7 | 194.7 | 13.4 | 8.7 |
Zr | 5 | 280 | 277 | 255 | 240 | 241 | 184 | 169 | 26 | 10 |
Hf | 0.20 | 6.24 | 6.33 | 5.86 | 5.75 | 5.39 | 4.24 | 3.87 | 0.73 | 0.27 |
Nb | 2.0 | 21.6 | 23.2 | 20.0 | 20.9 | 21.3 | 20.4 | 17.5 | 1.98* | 0.30* |
Ta | 0.10 | 1.41 | 1.56 | 1.37 | 1.45 | 1.36 | 1.33 | 1.17 | 0.14 | 0.01* |
Th | 1.0 | 16.4 | 19.7 | 17.5 | 14.2 | 17.5 | 15.1 | 13.1 | 1.34 | 0.29* |
U | 0.20 | 6.32 | 7.45 | 7.03 | 7.16 | 7.63 | 13.15 | 12.37 | 4.54 | 1.13 |
Sc | 1.0 | 19.2 | 23.9 | 24.9 | 24.0 | 26.6 | 30.1 | 30.4 | 3.0 | 0.06* |
Y | 1.0 | 33.0 | 31.0 | 38.7 | 49.7 | 43.9 | 72.6 | 76.0 | 16.4 | 1.7 |
Li | 1.0 | 40.6 | 49.1 | 51.6 | 51.8 | 44.7 | 36.8 | 40.2 | 5.7 | 0.40* |
Be | 0.50 | 2.60 | 2.89 | 2.87 | 3.41 | 3.38 | 7.53 | 11.16 | 1.29 | 0.048* |
Sr | 5 | 94 | 93 | 87 | 91 | 126 | 81 | 81 | 59 | 36 |
Ba | 5 | 269 | 276 | 308 | 324 | 262 | 208 | 212 | 27 | 5.0 |
Rb | 5 | 121 | 142 | 159 | 153 | 147 | 159 | 157 | 7.4 | 2.6* |
La | 1.0 | 49.7 | 44.8 | 48.7 | 53.4 | 56.8 | 66.4 | 68.9 | 4.8 | 0.46* |
Ce | 1.0 | 110.3 | 97.4 | 107.6 | 104.0 | 100.3 | 105.6 | 119.9 | 8.1 | 0.72* |
Pr | 0.1 | 11.5 | 10.5 | 11.5 | 13.7 | 13.9 | 20.3 | 23.0 | 1.2 | 0.11 |
Nd | 0.1 | 43.9 | 40.3 | 44.1 | 54.7 | 54.2 | 86.6 | 101.1 | 5.1 | 0.4 |
Sm | 0.10 | 8.64 | 8.08 | 8.97 | 11.82 | 11.07 | 20.55 | 25.10 | 1.13 | 0.09* |
Eu | 0.10 | 1.88 | 1.72 | 1.98 | 2.73 | 2.53 | 4.89 | 6.14 | 0.30 | 0.03* |
Gd | 0.10 | 7.69 | 7.23 | 8.38 | 11.55 | 10.13 | 20.89 | 25.62 | 1.60 | 0.12 |
Tb | 0.10 | 1.28 | 1.22 | 1.42 | 1.91 | 1.67 | 3.38 | 4.20 | 0.34 | 0.019* |
Dy | 0.10 | 7.45 | 7.05 | 8.17 | 11.01 | 9.60 | 18.99 | 23.67 | 3.82 | 0.10 |
Ho | 0.10 | 1.43 | 1.33 | 1.58 | 2.09 | 1.78 | 3.50 | 4.28 | 0.96 | 0.026* |
Er | 0.10 | 3.73 | 3.46 | 4.28 | 5.36 | 4.69 | 8.91 | 10.59 | 2.21 | 0.074* |
Tm | 0.10 | 0.61 | 0.58 | 0.72 | 0.90 | 0.79 | 1.48 | 1.78 | 0.25 | 0.01* |
Yb | 0.10 | 3.67 | 3.43 | 4.10 | 5.10 | 4.67 | 8.50 | 10.54 | 1.24 | 0.055* |
Lu | 0.10 | 0.58 | 0.56 | 0.65 | 0.80 | 0.74 | 1.33 | 1.69 | 0.18 | 0.009* |
LG01_R酸 | — | 70 | 75 | 75 | 75 | 75 | 75 | 75 | 65 | 55 |
LG03_R酸 | — | 70 | 75 | 70 | 65 | 70 | 70 | 70 | 45 | 50 |
MGAu_R矿 | — | 45 | 40 | 40 | 40 | 40 | 45 | 55 | 55 | 80 |
MGW_R矿 | — | 30 | 30 | 30 | 30 | 30 | 35 | 40 | 30 | 80 |
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